1,117 research outputs found
NO adsorption and thermal behavior on Pd surfaces. A detailed comparative study
The adsorption and thermal behavior of NO on `flat¿ Pd(111) and `stepped¿ Pd(112) surfaces has been investigated by temperature programmed desorption (TPD), high resolution electron energy loss spectroscopy (HREELS), and electron stimulated desorption ion angular distribution (ESDIAD) techniques. NO is shown to molecularly adsorb on both Pd(111) and Pd(112) in the temperature range 100¿373 K. NO thermally desorbs predominantly molecularly from Pd(111) near 500 K with an activation energy and pre-exponential factor of desorption which strongly depend on the initial NO surface coverage. In contrast, NO decomposes substantially on Pd(112) upon heating, with relatively large amounts of N2 and N2O desorbing near 500 K, in addition to NO. The fractional amount of NO dissociation on Pd(112) during heating is observed to be a strong function of the initial NO surface coverage. HREELS results indicate that the thermal dissociation of NO on both Pd(111) and Pd(112) occurs upon annealing to 490 K, forming surface-bound O on both surfaces. Evidence for the formation of sub-surface O via NO thermal dissociation is found only on Pd(112), and is verified by dissociative O2 adsorption experiments. Both surface-bound O and sub-surface O dissolve into the Pd bulk upon annealing of both surfaces to 550 K. HREELS and ESDIAD data consistently indicate that NO preferentially adsorbs on the (111) terrace sites of Pd(112) at low coverages, filling the (001) step sites only at high coverage. This result was verified for adsorption temperatures in the range 100¿373 K. In addition, the thermal dissociation of NO on Pd(112) is most prevalent at low coverages, where only terrace sites are occupied by NO. Thus, by direct comparison to NO/Pd(111), this study shows that the presence of steps on the Pd(112) surface enhances the thermal dissociation of NO, but that adsorption at the step sites is not the criterion for this decomposition
W=0 Pairing in Carbon Nanotubes away from Half Filling
We use the Hubbard Hamiltonian on the honeycomb lattice to represent the
valence bands of carbon single-wall nanotubes. A detailed symmetry
analysis shows that the model allows W=0 pairs which we define as two-body
singlet eigenstates of with vanishing on-site repulsion. By means of a
non-perturbative canonical transformation we calculate the effective
interaction between the electrons of a W=0 pair added to the interacting ground
state. We show that the dressed W=0 pair is a bound state for resonable
parameter values away from half filling. Exact diagonalization results for the
(1,1) nanotube confirm the expectations. For nanotubes of length ,
the binding energy of the pair depends strongly on the filling and decreases
towards a small but nonzero value as . We observe the existence
of an optimal doping when the number of electrons per C atom is in the range
1.21.3, and the binding energy is of the order of 0.1 1 meV.Comment: 16 pages, 6 figure
Recent Developments of NEMO: Detection of Solar Eruptions Characteristics
The recent developments in space instrumentation for solar observations and
telemetry have caused the necessity of advanced pattern recognition tools for
the different classes of solar events. The Extreme ultraviolet Imaging
Telescope (EIT) of solar corona on-board SOHO spacecraft has uncovered a new
class of eruptive events which are often identified as signatures of Coronal
Mass Ejection (CME) initiations on solar disk. It is evident that a crucial
task is the development of an automatic detection tool of CMEs precursors. The
Novel EIT wave Machine Observing (NEMO) (http://sidc.be/nemo) code is an
operational tool that detects automatically solar eruptions using EIT image
sequences. NEMO applies techniques based on the general statistical properties
of the underlying physical mechanisms of eruptive events on the solar disc. In
this work, the most recent updates of NEMO code - that have resulted to the
increase of the recognition efficiency of solar eruptions linked to CMEs - are
presented. These updates provide calculations of the surface of the dimming
region, implement novel clustering technique for the dimmings and set new
criteria to flag the eruptive dimmings based on their complex characteristics.
The efficiency of NEMO has been increased significantly resulting to the
extraction of dimmings observed near the solar limb and to the detection of
small-scale events as well. As a consequence, the detection efficiency of CMEs
precursors and the forecasts of CMEs have been drastically improved.
Furthermore, the catalogues of solar eruptive events that can be constructed by
NEMO may include larger number of physical parameters associated to the dimming
regions.Comment: 12 Pages, 5 figures, submitted to Solar Physic
Engineering a C-Phase quantum gate: optical design and experimental realization
A two qubit quantum gate, namely the C-Phase, has been realized by exploiting
the longitudinal momentum (i.e. the optical path) degree of freedom of a single
photon. The experimental setup used to engineer this quantum gate represents an
advanced version of the high stability closed-loop interferometric setup
adopted to generate and characterize 2-photon 4-qubit Phased Dicke states. Some
experimental results, dealing with the characterization of multipartite
entanglement of the Phased Dicke states are also discussed in detail.Comment: accepted for publication on EPJ
Measurement of single electron emission in two-phase xenon
We present the first measurements of the electroluminescence response to the
emission of single electrons in a two-phase noble gas detector. Single
ionization electrons generated in liquid xenon are detected in a thin gas layer
during the 31-day background run of the ZEPLIN-II experiment, a two-phase xenon
detector for WIMP dark matter searches. Both the pressure dependence and
magnitude of the single-electron response are in agreement with previous
measurements of electroluminescence yield in xenon. We discuss different
photoionization processes as possible cause for the sample of single electrons
studied in this work. This observation may have implications for the design and
operation of future large-scale two-phase systems.Comment: 11 pages, 6 figure
The UNC/UMN Baby Connectome Project (BCP): An overview of the study design and protocol development
The human brain undergoes extensive and dynamic growth during the first years of life. The UNC/UMN Baby Connectome Project (BCP), one of the Lifespan Connectome Projects funded by NIH, is an ongoing study jointly conducted by investigators at the University of North Carolina at Chapel Hill and the University of Minnesota. The primary objective of the BCP is to characterize brain and behavioral development in typically developing infants across the first 5 years of life. The ultimate goals are to chart emerging patterns of structural and functional connectivity during this period, map brain-behavior associations, and establish a foundation from which to further explore trajectories of health and disease. To accomplish these goals, we are combining state of the art MRI acquisition and analysis techniques, including high-resolution structural MRI (T1-and T2-weighted images), diffusion imaging (dMRI), and resting state functional connectivity MRI (rfMRI). While the overall design of the BCP largely is built on the protocol developed by the Lifespan Human Connectome Project (HCP), given the unique age range of the BCP cohort, additional optimization of imaging parameters and consideration of an age appropriate battery of behavioral assessments were needed. Here we provide the overall study protocol, including approaches for subject recruitment, strategies for imaging typically developing children 0–5 years of age without sedation, imaging protocol and optimization, a description of the battery of behavioral assessments, and QA/QC procedures. Combining HCP inspired neuroimaging data with well-established behavioral assessments during this time period will yield an invaluable resource for the scientific community
A Statistical Study on Photospheric Magnetic Nonpotentiality of Active Regions and Its Relationship with Flares during Solar Cycles 22-23
A statistical study is carried out on the photospheric magnetic
nonpotentiality in solar active regions and its relationship with associated
flares. We select 2173 photospheric vector magnetograms from 1106 active
regions observed by the Solar Magnetic Field Telescope at Huairou Solar
Observing Station, National Astronomical Observatories of China, in the period
of 1988-2008, which covers most of the 22nd and 23rd solar cycles. We have
computed the mean planar magnetic shear angle (\bar{\Delta\phi}), mean shear
angle of the vector magnetic field (\bar{\Delta\psi}), mean absolute vertical
current density (\bar{|J_{z}|}), mean absolute current helicity density
(\bar{|h_{c}|}), absolute twist parameter (|\alpha_{av}|), mean free magnetic
energy density (\bar{\rho_{free}}), effective distance of the longitudinal
magnetic field (d_{E}), and modified effective distance (d_{Em}) of each
photospheric vector magnetogram. Parameters \bar{|h_{c}|}, \bar{\rho_{free}},
and d_{Em} show higher correlation with the evolution of the solar cycle. The
Pearson linear correlation coefficients between these three parameters and the
yearly mean sunspot number are all larger than 0.59. Parameters
\bar{\Delta\phi}, \bar{\Delta\psi}, \bar{|J_{z}|}, |\alpha_{av}|, and d_{E}
show only weak correlations with the solar cycle, though the nonpotentiality
and the complexity of active regions are greater in the activity maximum
periods than in the minimum periods. All of the eight parameters show positive
correlations with the flare productivity of active regions, and the combination
of different nonpotentiality parameters may be effective in predicting the
flaring probability of active regions.Comment: 20 pages, 5 figures, 4 tables, accepted for publication in Solar
Physic
Partial Wave Analysis of
BES data on are presented. The
contribution peaks strongly near threshold. It is fitted with a
broad resonance with mass MeV, width MeV. A broad resonance peaking at 2020 MeV is also required
with width MeV. There is further evidence for a component
peaking at 2.55 GeV. The non- contribution is close to phase
space; it peaks at 2.6 GeV and is very different from .Comment: 15 pages, 6 figures, 1 table, Submitted to PL
Walking, Gross Motor Development, and Brain Functional Connectivity in Infants and Toddlers
Infant gross motor development is vital to adaptive function and predictive of both cognitive outcomes and neurodevelopmental disorders. However, little is known about neural systems underlying the emergence of walking and general gross motor abilities. Using resting state fcMRI, we identified functional brain networks associated with walking and gross motor scores in a mixed cross-sectional and longitudinal cohort of infants at high and low risk for autism spectrum disorder, who represent a dimensionally distributed range of motor function. At age 12 months, functional connectivity of motor and default mode networks was correlated with walking, whereas dorsal attention and posterior cingulo-opercular networks were implicated at age 24 months. Analyses of general gross motor function also revealed involvement of motor and default mode networks at 12 and 24 months, with dorsal attention, cingulo-opercular, frontoparietal, and subcortical networks additionally implicated at 24 months. These findings suggest that changes in network-level brain-behavior relationships underlie the emergence and consolidation of walking and gross motor abilities in the toddler period. This initial description of network substrates of early gross motor development may inform hypotheses regarding neural systems contributing to typical and atypical motor outcomes, as well as neurodevelopmental disorders associated with motor dysfunction
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