Ab-initio calculation of all-optical time-resolved calorimetry of nanosized systems: Evidence of nanosecond-decoupling of electron and phonon temperatures

The thermal dynamics induced by ultrashort laser pulses in nanoscale systems, i.e. all-optical time-resolved nanocalorimetry is theoretically investigated from 300 to 1.5 K. We report ab-initio calculations describing the temperature dependence of the electron-phonon interactions for Cu nanodisks supported on Si. The electrons and phonons temperatures are found to decouple on the ns time scale at 10 K, which is two orders of magnitude in excess with respect to that found for standard low-temperature transport experiments. By accounting for the physics behind our results we suggest an alternative route for overhauling the present knowledge of the electron-phonon decoupling mechanism in nanoscale systems by replacing the mK temperature requirements of conventional experiments with experiments in the time-domain.Comment: 5 pages, 3 figures. Accepted on Physical Review B

System thermal-hydraulic modelling of the phénix dissymmetric test benchmark

Phénix is a French pool-type sodium-cooled prototype reactor; before the definitive shutdown, occurred in 2009, a final set of experimental tests are carried out in order to increase the knowledge on the operation and the safety aspect of the pool-type liquid metal-cooled reactors. One of the experiments was the Dissymmetric End-of-Life Test which was selected for the validation benchmark activity in the frame of SESAME project. The computer code validation plays a key role in the safety assessment of the innovative nuclear reactors and the Phénix dissymmetric test provides useful experimental data to verify the computer codes capability in the asymmetric thermal-hydraulic behaviour into a pool-type liquid metal-cooled reactor. This paper shows the comparison of the outcomes obtained with six different System Thermal-Hydraulic (STH) codes: RELAP5-3D©, SPECTRA, ATHLET, SAS4A/SASSYS-1, ASTEC-Na and CATHARE. The nodalization scheme of the reactor was individually achieved by the participants; during the development of the thermal-hydraulic model, the pool nodalization methodology had a special attention in order to investigate the capability of the STH codes to reproduce the dissymmetric effects which occur in each loop and into pools, caused by the azimuthal asymmetry of the boundary conditions. The modelling methodology of the participants is discussed and the main results are compared in this paper to obtain useful guide lines for the future modelling of innovative liquid metal pool-type reactors

A timeline for massive star-forming regions via combined observation of o-H2_2D+^+ and N2_2D+^+

Context: In cold and dense gas prior to the formation of young stellar objects, heavy molecular species (including CO) are accreted onto dust grains. Under these conditions H$_3^+$ and its deuterated isotopologues become more abundant, enhancing the deuterium fraction of molecules such as N$_2$H$^+$ that are formed via ion-neutral reactions. Because this process is extremely temperature sensitive, the abundance of these species is likely linked to the evolutionary stage of the source. Aims: We investigate how the abundances of o-H$_2$D$^+$ and N$_2$D$^+$ vary with evolution in high-mass clumps. Methods: We observed with APEX the ground-state transitions of o-H$_2$D$^+$ near 372 GHz, and N$_2$D$^+$(3-2) near 231 GHz for three massive clumps in different evolutionary stages. The sources were selected within the G351.77-0.51 complex to minimise the variation of initial chemical conditions, and to remove distance effects. We modelled their dust continuum emission to estimate their physical properties, and also modelled their spectra under the assumption of local thermodynamic equilibrium to calculate beam-averaged abundances. Results: We find an anticorrelation between the abundance of o-H$_2$D$^+$ and that of N$_2$D$^+$, with the former decreasing and the latter increasing with evolution. With the new observations we are also able to provide a qualitative upper limit to the age of the youngest clump of about 10$^5$ yr, comparable to its current free-fall time. Conclusions: We can explain the evolution of the two tracers with simple considerations on the chemical formation paths, depletion of heavy elements, and evaporation from the grains. We therefore propose that the joint observation and the relative abundance of o-H$_2$D$^+$ and N$_2$D$^+$ can act as an efficient tracer of the evolutionary stages of the star-formation process

Cleaner production for achieving the sustainable development goals

Cleaner production is a lively concept in which new procedures and technologies constantly emerge introducing methods and practices to prevent damages to the environment. A broad range of cleaner production initiatives contribute to sustainable development not only through the efficient management of resources and energy, but also through the development of new and smart technologies, new ways of assisting policies development, and organizing supply chains, sectors and individual companies. The authors of this Virtual Special Issue sought to introduce first-hand knowledge and discussions identifying and highlighting the ways cleaner production can contribute to reach the United Nations sustainable development targets. The intent of the Virtual Special Issue is to provide an overview of the recent trends that cleaner production practitioners/researchers are following in the chase of the sustainable development goals, and in this context, this editorial was designed to summarize and underscore the link between cleaner production concepts and practices and the sustainable development goals. An adequate response to this challenge required scientific knowledge and reassessment of the papers ensuring that the science is responsive to the evolving needs of sustainable development. This Virtual Special Issue of the Journal of Cleaner Production is mainly dedicated to the 7th International Workshop on Advances in Cleaner Production, held at Universidad de La Costa, Barranquilla, Colombia on 21–22 June 2018. Based upon the examination of the papers of this Virtual Special Issue, the authors were able to establish that there is an pressing need for research on the assessment on which/when cleaner production interventions are more effective; inter and multidisciplinary cooperation among social and technical scientists to distinguish and address the cleaner production/sustainable development goals interactions and connect cleaner production solutions and large-scale sustainability approaches

Thermo-mechanical behavior of surface acoustic waves in ordered arrays of nanodisks studied by near infrared pump-probe diffraction experiments

The ultrafast thermal and mechanical dynamics of a two-dimensional lattice of metallic nano-disks has been studied by near infrared pump-probe diffraction measurements, over a temporal range spanning from 100 fs to several nanoseconds. The experiments demonstrate that, in these systems, a two-dimensional surface acoustic wave (2DSAW), with a wavevector given by the reciprocal periodicity of the array, can be excited by ~120 fs Ti:sapphire laser pulses. In order to clarify the interaction between the nanodisks and the substrate, numerical calculations of the elastic eigenmodes and simulations of the thermodynamics of the system are developed through finite-element analysis. At this light, we unambiguously show that the observed 2DSAW velocity shift originates from the mechanical interaction between the 2DSAWs and the nano-disks, while the correlated 2DSAW damping is due to the energy radiation into the substrate.Comment: 13 pages, 10 figure

The new hyperspectral satellite prisma: Imagery for forest types discrimination

Different forest types based on different tree species composition may have similar spectral signatures if observed with traditional multispectral satellite sensors. Hyperspectral imagery, with a more continuous representation of their spectral behavior may instead be used for their classification. The new hyperspectral Precursore IperSpettrale della Missione Applicativa (PRISMA) sensor, developed by the Italian Space Agency, is able to capture images in a continuum of 240 spectral bands ranging between 400 and 2500 nm, with a spectral resolution smaller than 12 nm. The new sensor can be employed for a large number of remote sensing applications, including forest types discrimination. In this study, we compared the capabilities of the new PRISMA sensor against the well-known Sentinel-2 Multi-Spectral Instrument (MSI) in recognition of different forest types through a pairwise separability analysis carried out in two study areas in Italy, using two different nomenclature systems and four separability metrics. The PRISMA hyperspectral sensor, compared to Sentinel-2 MSI, allowed for a better discrimination in all forest types, increasing the performance when the complexity of the nomenclature system also increased. PRISMA achieved an average improvement of 40% for the discrimination between two forest categories (coniferous vs. broadleaves) and of 102% in the discrimination between five forest types based on main tree species groups

Overcoming the myths of mainstream economics to enable a newwellbeing economy

Increasingly, empirical evidence refutes many of the theoretical pillars of mainstream economics. These theories have persisted despite the fact that they support unsustainable and undesirable environmental, social, and economic outcomes. Continuing to embrace them puts at risk the possibility of achieving the Sustainable Development Goals and overcoming other global challenges. We discuss a selection of paradoxes and delusions surrounding mainstream economic theories related to: (1) efficiency and resource use, (2) wealth and wellbeing, (3) economic growth, and (4) the distribution of wealth within and between rich and poor nations. We describe a wellbeing economy as an alternative for guiding policy development. In 2018, a network of Wellbeing Economy Governments (WEGo), (supported by, but distinct from, the larger Wellbeing Economy Alliance-WEAll) promoting new forms of governance that diverge from the ones on which the G7 and G20 are based, has been launched and is now a living project. Members of WEGo aim at advancing the three key principles of a wellbeing economy: Live within planetary ecological boundaries, ensure equitable distribution of wealth and opportunity, and efficiently allocate resources (including environmental and social public goods), bringing wellbeing to the heart of policymaking, and in particular economic policymaking. This network has potential to fundamentally re-shape current global leadership still anchored to old economic paradigms that give primacy to economic growth over environmental and social wealth and wellbeing

Emergence of pseudogap from short-range spin-correlations in electron doped cuprates

Electron interactions are pivotal for defining the electronic structure of quantum materials. In particular, the strong electron Coulomb repulsion is considered the keystone for describing the emergence of exotic and/or ordered phases of quantum matter as disparate as high-temperature superconductivity and charge- or magnetic-order. However, a comprehensive understanding of fundamental electronic properties of quantum materials is often complicated by the appearance of an enigmatic partial suppression of low-energy electronic states, known as the pseudogap. Here we take advantage of ultrafast angle-resolved photoemission spectroscopy to unveil the temperature evolution of the low-energy density of states in the electron-doped cuprate Nd$_{\text{2-x}}$Ce$_{\text{x}}$CuO$_{\text{4}}$, an emblematic system where the pseudogap intertwines with magnetic degrees of freedom. By photoexciting the electronic system across the pseudogap onset temperature T*, we report the direct relation between the momentum-resolved pseudogap spectral features and the spin-correlation length with an unprecedented sensitivity. This transient approach, corroborated by mean field model calculations, allows us to establish the pseudogap in electron-doped cuprates as a precursor to the incipient antiferromagnetic order even when long-range antiferromagnetic correlations are not established, as in the case of optimal doping.Comment: 17 pages, 3 figure

Evidence of vectorial photoelectric effect on Copper

Quantum Efficiency (QE) measurements of single photon photoemission from a Cu(111) single crystal and a Cu polycrystal photocathodes, irradiated by 150 fs-6.28 eV laser pulses, are reported over a broad range of incidence angle, both in s and p polarizations. The maximum QE (\simeq 4\times10^{-4}) for polycrystalline Cu is obtained in p polarization at an angle of incidence {\theta} = 65deg. We observe a QE enhancement in p polarization which can not be explained in terms of optical absorption, a phenomenon known as vectorial photoelectric effect. Issues concerning surface roughness and symmetry considerations are addressed. An explanation in terms of non local conductivity tensor is proposed.Comment: 3 pages, 3 figure