Magnetic behavior of lamellar mnps3 and cdps3 composites with a paramagnetic manganese(iii) macrocyclic guest

Indexación: ScieloSix new composites derived from the intercalation of the MPS3 phases (M = MnII, CdIII) with the macrocyclic manganese(III) complex [MnL(H2O)2].NO3(H2O) (LH2 = Schiff base macrocyclic ligand derived from the condensation of 2-hydroxy-5-methy1-1,3-benzene-dicarbaldehyde and 1,2-diamine-benzene) were obtained by two different synthetic procedures: a conventional and a microwave assisted method. The composites [MnL]0.25K0.15Mn0.80 PS3(H2O)~1.0 (1), and [MnL]0.25K0.15Cd 0. 80PS3(H2O)~0.5 (2) were obtained by the conventional method, after stirring a suspension of the corresponding potassium precursor and the macrocyclic complex for two weeks, while [MnL]0.35K0.15Mn0.80 PS3(H2O)~1.0 (3) and [MnL]0.25K0.15Cd 0. 80PS3(H2O)~0.5 (4) after stirring for four weeks at room temperature. Using a microwave assisted reaction permitted to obtain in a shorter period of time as compared with the conventional method, composites [MnL]0.20K0.15Mn0.80 PS3(H2O)~1.0 (5) and [MnL]0.15K0.15Cd 0. 80PS3(H2O)~0.5 (6). All the M = MnII, MnIII composites show a bulk antiferromagnetic behavior. However, the spontaneous magnetization present at low temperature in the potassium precursor K0.40Mn0.80 PS3(H2O)~1.0 is observable in composite [MnL]0.20K0.15Mn0.80 PS3(H2O)~1.0 (5), while it is completely absent in composites [MnL]0.25K0.15Mn0.80 PS3(H2O)~1.0 (1) and [MnL]0.35K0.15Mn0.80 PS3(H2O)~1.0 (3). Keywords: Intercalation; MPS3 phases; MnIII macrocyclic complex; microwave assisted synthesis; magnetic properties

A solution of the Gaussian optimizer conjecture

The long-standing conjectures of the optimality of Gaussian inputs for Gaussian channel and Gaussian additivity are solved for a broad class of covariant or contravariant Bosonic Gaussian channels (which includes in particular thermal, additive classical noise, and amplifier channels) restricting to the class of states with finite second moments. We show that the vacuum is the input state which minimizes the entropy at the output of such channels. This allows us to show also that the classical capacity of these channels (under the input energy constraint) is additive and is achieved by Gaussian encodings.Comment: 24 pages, no figures (minor typos corrected

The 1991 southern hemisphere complex of activity

We have investigated the development of a complex of activity which took place in the southern hemisphere of the Sun between July 1991 and April 1992. The whole process culminated with the successive formation of two large active regions with sunspot groups NOAA 6850 (September/October) and NOAA 6891 (October/November 1991), both having complicated magnetic fields, but the former without heavy flare activity. We observed the appearance of the individual active regions as the consequence of the development stage of large-scale magnetic fields in the given area of the solar surface, in connection with their longitudinal and latitudinal distribution. We have studied the dynamics of this development on magnetic synoptic charts, as well as on spectroheliograms taken in the K-line of ionized calcium. Our new observations confirm the regularities found earlier and connection of global and local developments with convection. We think that they could become a tool for solar activity prediction and that they could be used for comparative studies of stellar complexes of activity

Line-of-sight velocity distributions of elliptical galaxies from collisionless mergers

We analyse the skewness of the line-of-sight velocity distributions in model elliptical galaxies built through collisionless galaxy mergers. We build the models using large N-body simulations of mergers between either two spiral or two elliptical galaxies. Our aim is to investigate whether the observed ranges of skewness coefficient (h3) and the rotational support (V/sigma), as well as the anticorrelation between h3 and V, may be reproduced through collisionless mergers. Previous attempts using N-body simulations failed to reach V/sigma ~ 1-2 and corresponding high h3 values, which suggested that gas dynamics and ensuing star formation might be needed in order to explain the skewness properties of ellipticals through mergers. Here we show that high V/sigma and high h3 are reproduced in collisionless spiral-spiral mergers whenever a central bulge allows the discs to retain some of their original angular momentum during the merger. We also show that elliptical-elliptical mergers, unless merging from a high-angular momentum orbit, reproduce the strong skewness observed in non-rotating, giant, boxy ellipticals. The behaviour of the h3 coefficient therefore associates rapidly-rotating disky ellipticals to disc-disc mergers, and associates boxy, slowly-rotating giant ellipticals to elliptical-elliptical mergers, a framework generally consistent with the expectations of hierarchical galaxy formation.Comment: 5 pages, 4 figures, MNRAS Letters, in pres