Mechanistic Study Of Plasma Damage Of Low k Dielectric Surfaces

Plasma damage to low k dielectric materials was investigated from a mechanistic point of view. Low k dielectric films were treated by plasma Ar, O-2, N-2/H-2, N-2 and H-2 in a standard RIE chamber and the damage was characterized by Angle Resolved X-ray Photoelectron Spectroscopy (ARXPS), X-Ray Reflectivity (XRR), Fourier Transform Infrared Spectroscopy (FTIR) and Contact Angle measurements. Both carbon depletion and surface densification were observed on the top surface of damaged low k materials while the bulk remained largely unaffected. Plasma damage was found to be a complicated phenomenon involving both chemical and physical effects, depending on chemical reactivity and the energy and mass of the plasma species. A downstream hybrid plasma source with separate ions and atomic radicals was employed to study their respective roles in the plasma damage process. Ions were found to play a more important role in the plasma damage process. The dielectric constant of low k materials can increase up to 20% due to plasma damage and we attributed this to the removal of the methyl group making the low k surface hydrophilic. Annealing was generally effective in mitigating moisture uptake to restore the k value but the recovery was less complete for higher energy plasmas. Quantum chemistry calculation confirmed that physisorbed water in low k materials induces the largest increase of dipole moments in comparison with changes of surface bonding configurations, and is primarily responsible for the dielectric constant increase.Microelectronics Research Cente

Simulation and analysis of in vitro DNA evolution

We study theoretically the in vitro evolution of a DNA sequence by binding to a transcription factor. Using a simple model of protein-DNA binding and available binding constants for the Mnt protein, we perform large-scale, realistic simulations of evolution starting from a single DNA sequence. We identify different parameter regimes characterized by distinct evolutionary behaviors. For each regime we find analytical estimates which agree well with simulation results. For small population sizes, the DNA evolutional path is a random walk on a smooth landscape. While for large population sizes, the evolution dynamics can be well described by a mean-field theory. We also study how the details of the DNA-protein interaction affect the evolution.Comment: 11 pages, 11 figures. Submitted to PNA

Dime como educas y te diré como es tu ambiente

La crisis ambiental es un problema de conocimiento, por ello involucra a la educación, siendo el desafío de ella el de pasar de una cultura economicista, que refuerza y que es reforzada por la globalización, a una cultura de pertenencia, de compromiso, de resistencia, de solidaridad. Debemos focalizar los esfuerzos por construir desde la complejidad ambiental una ciencia para la sustentabilidad que hunda sus raíces en la justicia ambiental y que destierre las ideas simplificadoras y reduccionistas de la sociedad y comience a fundar el nuevo paradigma basado en la interdisciplinaridad y la transdisciplinariedad. Este proyecto didáctico se elabora para aplicar en dos cursos "paralelos" de diferentes escuelas de la ciudad de Rafaela, provincia de Santa Fe. Se formarán equipos de trabajo que interactuarán en esta propuesta: docentes (biología, historia, derecho, lengua, geografía, economía), directivos y los alumnos, con las adaptaciones a sus problemáticas, su universo y territorialidad, implementando ILS-indicadores locales de sustentabilidad.Trabajos del área Ciencias NaturalesDepartamento de Ciencias Exactas y Naturale

The role of aerosol in altering North Atlantic atmospheric circulation in winter and its impact on air quality

Numerical model scenarios of future climate depict a global increase in temperatures and changing precipitation patterns, primarily driven by increasing greenhouse gas (GHG) concentrations. Aerosol particles also play an important role by altering the Earth's radiation budget and consequently surface temperature. Here, we use the general circulation aerosol model ECHAM5-HAM, coupled to a mixed layer ocean model, to investigate the impacts of future air pollution mitigation strategies in Europe on winter atmospheric circulation over the North Atlantic. We analyse the extreme case of a maximum feasible end-of-pipe reduction of aerosols in the near future (2030), in combination with increasing GHG concentrations. Our results show a more positive North Atlantic Oscillation (NAO) mean state by 2030, together with a significant eastward shift of the southern centre of action of sea-level pressure (SLP). Moreover, we show a significantly increased blocking frequency over the western Mediterranean. By separating the impacts of aerosols and GHGs, our study suggests that future aerosol abatement may be the primary driver of both the eastward shift in the southern SLP centre of action and the increased blocking frequency over the western Mediterranean. These concomitant modifications of the atmospheric circulation over the Euro-Atlantic sector lead to more stagnant weather conditions that favour air pollutant accumulation, especially in the western Mediterranean sector. Changes in atmospheric circulation should therefore be included in future air pollution mitigation assessments. The indicator-based evaluation of atmospheric circulation changes presented in this work will allow an objective first-order assessment of the role of changes in wintertime circulation on future air quality in other climate model simulations

Burst avalanches in solvable models of fibrous materials

We review limiting models for fracture in bundles of fibers, with statistically distributed thresholds for breakdown of individual fibers. During the breakdown process, avalanches consisting of simultaneous rupture of several fibers occur, and the distribution $D(\Delta)$ of the magnitude $\Delta$ of such avalanches is the central characteristics in our analysis. For a bundle of parallel fibers two limiting models of load sharing are studied and contrasted: the global model in which the load carried by a bursting fiber is equally distributed among the surviving members, and the local model in which the nearest surviving neighbors take up the load. For the global model we investigate in particular the conditions on the threshold distribution which would lead to anomalous behavior, i.e. deviations from the asymptotics $D(\Delta) \sim \Delta^{-5/2}$, known to be the generic behavior. For the local model no universal power-law asymptotics exists, but we show for a particular threshold distribution how the avalanche distribution can nevertheless be explicitly calculated in the large-bundle limit.Comment: 28 pages, RevTeX, 3 Postscript figure

Scaling in the time-dependent failure of a fiber bundle with local load sharing

We study the scaling behaviors of a time-dependent fiber-bundle model with local load sharing. Upon approaching the complete failure of the bundle, the breaking rate of fibers diverges according to $r(t)\propto (T_f-t)^{-\xi}$, where $T_f$ is the lifetime of the bundle, and $\xi \approx 1.0$ is a quite universal scaling exponent. The average lifetime of the bundle $$ scales with the system size as $N^{-\delta}$, where $\delta$ depends on the distribution of individual fiber as well as the breakdown rule.Comment: 5 pages, 4 eps figures; to appear in Phys. Rev.

Gravastar Solutions with Continuous Pressures and Equation of State

We study the gravitational vacuum star (gravastar) configuration as proposed by other authors in a model where the interior de Sitter spacetime segment is continuously extended to the exterior Schwarzschild spacetime. The multilayered structure in previous papers is replaced by a continuous stress-energy tensor at the price of introducing anisotropy in the (fluid) model of the gravastar. Either with an ansatz for the equation of state connecting the radial $p_r$ and tangential $p_t$ pressure or with a calculated equation of state with non-homogeneous energy/fluid density, solutions are obtained which in all aspects satisfy the conditions expected for an anisotropic gravastar. Certain energy conditions have been shown to be obeyed and a polytropic equation of state has been derived. Stability of the solution with respect to possible axial perturbation is shown to hold.Comment: 19 pages, 9 figures. Latest version contains new and updated references along with some clarifying remarks in the stability analysi

Fracture of disordered solids in compression as a critical phenomenon: I. Statistical mechanics formalism

This is the first of a series of three articles that treats fracture localization as a critical phenomenon. This first article establishes a statistical mechanics based on ensemble averages when fluctuations through time play no role in defining the ensemble. Ensembles are obtained by dividing a huge rock sample into many mesoscopic volumes. Because rocks are a disordered collection of grains in cohesive contact, we expect that once shear strain is applied and cracks begin to arrive in the system, the mesoscopic volumes will have a wide distribution of different crack states. These mesoscopic volumes are the members of our ensembles. We determine the probability of observing a mesoscopic volume to be in a given crack state by maximizing Shannon's measure of the emergent crack disorder subject to constraints coming from the energy-balance of brittle fracture. The laws of thermodynamics, the partition function, and the quantification of temperature are obtained for such cracking systems.Comment: 11 pages, 2 figure