Atmospheric methanol measurement using selective catalytic methanol to formaldehyde conversion

International audienceA novel atmospheric methanol measurement technique, employing selective gas-phase catalytic conversion of methanol to formaldehyde followed by detection of the formaldehyde product, has been developed and tested. The effects of temperature, gas flow rate, gas composition, reactor-bed length, and reactor-bed composition on the methanol conversion efficiency of a molybdenum-rich, iron-molybdate catalyst [Mo-Fe-O] were studied. Best results were achieved using a 1:4 mixture (w/w) of the catalyst in quartz sand. Optimal methanol to formaldehyde conversion (>95% efficiency) occurred at a catalyst housing temperature of 345°C and an estimated sample-air/catalyst contact time of <0.2 seconds. Potential interferences arising from conversion of methane and a number of common volatile organic compounds (VOC) to formaldehyde were found to be negligible under most atmospheric conditions and catalyst housing temperatures. Using the new technique, atmospheric measurements of methanol were made at the University of Bremen campus from 1 to 15 July 2004. Methanol mixing ratios ranged from 1 to 5 ppb with distinct maxima at night. Formaldehyde mixing ratios, obtained in conjunction with methanol by periodically bypassing the catalytic converter, ranged from 0.2 to 1.6 ppb with maxima during midday. These results suggest that selective, catalytic methanol to formaldehyde conversion, coupled with existing formaldehyde measurement instrumentation, is an inexpensive and effective means for monitoring atmospheric methanol

Paper Session II-C - Pegasus and Taurus Launch Vehicles

The Pegasus Air-Launched Space Booster is an innovative new space launch vehicle now in full scale development and initial production. Pegasus, developed by a privately-funded joint venture of Orbital Sciences Corporation (OSC) and Hercules Aerospace Company, is a three-stage, solid-propellant, inertially-guided, winged vehicle that is launched from a carrier aircraft at 40,000 ft and Mach .8. This 50 ft long, 41,000 Ib vehicle can deliver a payload of 900 Ib into a low inclination, 150 nmi Earth orbit. The first two Pegasus flights are sponsored by the Defense Advanced Research Projects Agency (DARPA), with additional missions currently reserved by the U.S. Air Force and commercial customers. Pegasus was conceived to provide a more flexible and more efficient launch system for small space payloads by taking advantage of the many benefits inherent in the airborne launch approach. The Pegasus system achieves a substantial improvement in payload performance relative to comparable ground-based launch vehicle designs, while also providing numerous advantages in operational flexibility and cost effectiveness. The flight vehicle, shown in Figure 1, consists of three solid-propellant rocket motors, a fixed highmounted composite delta wing, an aft skirt assembly including three composite fins, an avionics section atop the third stage, and a two-piece composite payload fairing

Discovery of a New Quadruple Lens HST 1411+5211

Gravitational lensing is an important tool for probing the mass distribution of galaxies. In this letter we report the discovery of a new quadruple lens HST 1411+5211 found in archived WFPC2 images of the galaxy cluster CL140933+5226. If the galaxy is a cluster member then its redshift is $z=0.46$. The images of the source appear unresolved in the WFC implying that the source is a quasar. We have modeled the lens as both a single galaxy and a galaxy plus a cluster. The latter model yields excellent fits to the image positions along with reasonable parameters for the galaxy and cluster making HST 1411+5211 a likely gravitational lens. Determination of the source redshift and confirmation of the lens redshift would allow us to put strong constraints on the mass distribution of the lensing galaxy.Comment: 11 pages including 1 postscript figure, aastex. Accepted to the ApJL. Also available from: http://www.astro.lsa.umich.edu:80/users/philf/www/papers/list.htm

INTERACTION BETWEEN THE POLE AND THE HUMAN BODY AND ITS EFFECT ON THE POLE VAULTING PERFORMANCE

The purposes of this study were: (a) to examine the utilization of pole elasticity by the athletes through muscular work and to develope performance criteria throughout the pole vault and (b) to examine the reproducibility and the athlete's specificity of the developed criteria. In the study, 6 athletes performed from 4 to 11 trials each, at 90% of their respective personal best performance. All trials were recorded using four synchronized, genlocked video cameras operating at 50 Hz. The ground reaction forces exerted on the bottom of the pole were measured using a planting box fixed on a kistler force plate (1000 Hz). The interaction between athlete and pole may be split into two parts. During the first part of the interaction, energy is transferred into the pole and the total energy of the athlete decreases. The difference between the energy decrease of the athlete and the pole energy indicates if the athletes are producing additional energy by means of muscular work (criterion 1). In the second part of the interaction, energy is transferred back to the athlete and the total energy of the athlete increases. The difference between the returned pole energy and the amount of energy increase of the athlete defines criterion 2. The criteria are reproducible, specific to each athlete, capable of identifying deficits or strengths of the athlete's performance during his interaction with the pole; they can therefore estimate the quality of the technique during each of the phases of the interaction athlete-pole

Catalog of Galaxy Morphology in Four Rich Clusters: Luminosity Evolution of Disk Galaxies at 0.33<z<0.83

Hubble Space Telescope (HST) imaging of four rich, X-ray luminous, galaxy clusters (0.33<z<0.83) is used to produce quantitative morphological measurements for galaxies in their fields. Catalogs of these measurements are presented for 1642 galaxies brighter than F814W(AB)=23.0 . Galaxy luminosity profiles are fitted with three models: exponential disk, de Vaucouleurs bulge, and a disk-plus-bulge hybrid model. The best fit is selected and produces a quantitative assessment of the morphology of each galaxy: the principal parameters derived being B/T, the ratio of bulge to total luminosity, the scale lengths and half-light radii, axial ratios, position angles and surface brightnesses of each component. Cluster membership is determined using a statistical correction for field galaxy contamination, and a mass normalization factor (mass within boundaries of the observed fields) is derived for each cluster. In the present paper, this catalog of measurements is used to investigate the luminosity evolution of disk galaxies in the rich-cluster environment. Examination of the relations between disk scale-length and central surface brightness suggests, under the assumption that these clusters represent a family who share a common evolutionary history and are simply observed at different ages, that there is a dramatic change in the properties of the small disks (h < 2 kpc). This change is best characterized as a change in surface brightness by about 1.5 magnitude between z=0.3 and z=0.8 with brighter disks at higher redshifts.Comment: 53 pages, including 13 figures and 7 tables. Accepted for publication in the Astrophysical Journal Supplement Serie

Observation of charge-density-wave excitations in manganites

In the optical conductivity of four different manganites with commensurate charge order (CO), strong peaks appear in the meV range below the ordering temperature T_{CO}. They are similar to those reported for one-dimensional charge density waves (CDW) and are assigned to pinned phasons. The peaks and their overtones allow one to obtain, for La{1-n/8}Ca{n/8}$MnO{3} with n = 5, 6, the electron-phonon coupling, the effective mass of the CO system, and its contribution to the dielectric constant. These results support a description of the CO in La-Ca manganites in terms of moderately weak-coupling and of the CDW theory.Comment: To be published on Phys. Rev. Let

Quantifying alkane emissions in the Eagle Ford Shale using boundary layer enhancement

The Eagle Ford Shale in southern Texas is home to a booming unconventional oil and gas industry, the climate and air quality impacts of which remain poorly quantified due to uncertain emission estimates. We used the atmospheric enhancement of alkanes from Texas Commission on Environmental Quality volatile organic compound monitors across the shale, in combination with back trajectory and dispersion modeling, to quantify C2–C4 alkane emissions for a region in southern Texas, including the core of the Eagle Ford, for a set of 68 days from July 2013 to December 2015. Emissions were partitioned into raw natural gas and liquid storage tank sources using gas and headspace composition data, respectively, and observed enhancement ratios. We also estimate methane emissions based on typical ethane-to-methane ratios in gaseous emissions. The median emission rate from raw natural gas sources in the shale, calculated as a percentage of the total produced natural gas in the upwind region, was 0.7 % with an interquartile range (IQR) of 0.5–1.3 %, below the US Environmental Protection Agency's (EPA) current estimates. However, storage tanks contributed 17 % of methane emissions, 55 % of ethane, 82 % percent of propane, 90 % of n-butane, and 83 % of isobutane emissions. The inclusion of liquid storage tank emissions results in a median emission rate of 1.0 % (IQR of 0.7–1.6 %) relative to produced natural gas, overlapping the current EPA estimate of roughly 1.6 %. We conclude that emissions from liquid storage tanks are likely a major source for the observed non-methane hydrocarbon enhancements in the Northern Hemisphere

Semantic analysis of citizen sensing, crowdsourcing and VGI

This paper describes a semantic analysis of terms used to describe citizen sensing and crowdsourced data use in scientific analyses. It applies a latency analysis to journal abstracts downloaded from Scopus that matched one of number of terms related to crowd sourced data and citizen science. The latency analysis shows how the terms associated with crowdsourcing are related and how they have evolved over time.JRC.H.6-Digital Earth and Reference Dat

A comparison of new measurements of total monoterpene flux with improved measurements of speciated monoterpene flux

International audienceMany monoterpenes have been identified in forest emissions using gas chromatography (GC). Until now, it has been impossible to determine whether all monoterpenes are appropriately measured using GC techniques. We used a proton transfer reaction mass spectrometer (PTR-MS) coupled with the eddy covariance (EC) technique to measure mixing ratios and fluxes of total monoterpenes above a ponderosa pine plantation. We compared PTR-MS-EC results with simultaneous measurements of eight speciated monoterpenes, ?-pinene, ?-pinene, 3-carene, d-limonene, ?-phellandrene, ?-terpinene, camphene, and terpinolene, made with an automated, in situ gas chromatograph with flame ionization detectors (GC-FID), coupled to a relaxed eddy accumulation system (REA). Monoterpene mixing ratios and fluxes measured by PTR-MS averaged 30±2.3% and 31±9.2% larger than by GC-FID, with larger mixing ratio discrepancies between the two techniques at night than during the day. Two unidentified peaks that correlated with ?-pinene were resolved in the chromatograms and completely accounted for the daytime difference and reduced the nighttime mixing ratio difference to 20±2.9%. Measurements of total monoterpenes by PTR-MS-EC indicated that GC-FID-REA measured the common, longer-lived monoterpenes well, but that additional terpenes were emitted from the ecosystem that represented an important contribution to the total mixing ratio above the forest at night