35 research outputs found
Interfacial Profile and Propagation of Frontal Photopolymerization Waves
We investigate the frontal photopolymerization
of a thiol–ene
system with a combination of experiments and modeling, focusing on
the interfacial conversion profile and its planar wave propagation.
We spatially resolve the solid-to-liquid front by FT-IR and AFM mechanical
measurements, supplemented by differential scanning calorimetry. A
simple coarse-grained model is found to describe remarkably well the
frontal kinetics and the sigmoidal interface, capturing the effects
of UV light exposure time (or dose) and temperature, as well as the
front position and resulting patterned dimensions after development.
Analytical solutions for the conversion profile enable the description
of all conditions with a single master curve in the moving frame of
the front position. Building on this understanding, we demonstrate
the design and fabrication of gradient polymer materials, with tunable
properties <i>along</i> the direction of illumination, which
can be coupled with lateral patterning by modulated illumination or
grayscale lithography
Lower bound for the spatial extent of localized modes in photonic-crystal waveguides with small random imperfections
Light localization due to random imperfections in periodic media is paramount in photonics research. The group index is known to be a key parameter for localization near photonic band edges, since small group velocities reinforce light interaction with imperfections. Here, we show that the size of the smallest localized mode that is formed at the band edge of a one-dimensional periodic medium is driven instead by the effective photon mass, i.e. the flatness of the dispersion curve. Our theoretical prediction is supported by numerical simulations, which reveal that photonic-crystal waveguides can exhibit surprisingly small localized modes, much smaller than those observed in Bragg stacks thanks to their larger effective photon mass. This possibility is demonstrated experimentally with a photonic-crystal waveguide fabricated without any intentional disorder, for which near-field measurements allow us to distinctly observe a wavelength-scale localized mode despite the smallness (∼1/1000 of a wavelength) of the fabrication imperfections
Light confinement in photonic-crystal microcavities : A Fabry-Perot point of view
The physical mechanisms that can be used as general recipes for designing high-quality factor (Q) photonic crystal cavities with small mode volumes are described within a Fabry-Perot-like approach. ©2007 IEEE
Kinetic Study of Photoinitiated Frontal Polymerization. Influence of UV Light Intensity Variations on the Conversion Profiles
A novel high-efficiency single-mode single photon source
We present a novel single-mode single photon source
exploiting the emission of a semiconductor quantum dot (QD) located inside a
photonic wire. We first show theoretically that for optimized designs, more
than 95% of the QD spontaneous emission (SE) can be injected into the
fundamental guided mode of the photonic wire. A single photon collection
efficiency of 17% is measured in a preliminary experiment performed on a
single InAs QD located within a 250Â nm diameter cylinder of GaAs. Because
this photon collection strategy does not exploit the Purcell effect, it
could also be efficiently applied to broadband single photon emitters such
as F-centers in diamond
Estimating diffusion-controlled reaction parameters in photoinitiated polymerization of dimethacrylate macromonomers
Simulation of conversion profiles inside a thick dental material photopolymerized in the presence of nanofillers
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