Degradation of LaMnO{3-y} surface layer in LaMnO{3-y}/ metal interface

We report electrical measurements showing the degradation processes of LaMnO$_{3-y}$ (LaMnO) in LaMnO/normal metal interface in both point contact and planar-type junctions. Immediately after the preparation of the interface, the degradation process was followed by measuring the evolution of the junction resistance versus time. This process is characterized by the appearance of a second maximum in the resistance vs. temperature (R-T) dependence at temperatures lower than the Curie temperature T$_c$, at which the metal-insulator transition occurs in the bulk. These effects are explained in terms of the formation of a depleted interface layer in LaMnO caused by an out-diffusion of oxygen from the manganite surface to the normal metal. This assumption is confirmed by XPS measurement. Similar results on LaSrMnO$_{3-y}$ interfaces are also obtained.Comment: 4 pages, 3 figures, accepted for publication in Appl. Phys. Lett.(2002

Mitigating potentially hazardous asteroid impacts revisited

Context: Potentially hazardous asteroids (PHA) in Earth-crossing orbits pose a constant threat to life on Earth. Several mitigation methods have been proposed, and the most feasible technique appears to be the disintegration of the impactor and the generation of a fragment cloud by explosive penetrators at interception. Mitigation analyses, however neglect the effect of orbital dynamics on fragments trajectory. Aims: We aim at studying the effect of orbital dynamics of the impactor's cloud on the number of fragments that hit the Earth assuming different interception dates. The effect of self-gravitational cohesion and the axial rotation of the impactor are also investigated. Methods: The orbits of 10^5 fragments are computed with a high-precision direct N-body integrator of the 8th order, running on GPUs. We consider orbital perturbations from all large bodies in the Solar System and the self-gravity of the cloud fragments. Results: Using a series of numerical experiments, we show that orbital shear causes the fragment cloud to adopt the shape of a triaxial ellipsoid. The shape and alignment of the triaxial ellipsoid are strongly modulated by the cloud's orbital trajectory, and hence the impact cross-section of the cloud with respect to the Earth. Therefore, the number of fragments hitting the Earth is strongly influenced by the orbit of the impactor and the time of interception. A minimum number of impacts occurs for a well-defined orientation of the impactor rotational axis, depending on the date of interception. Conclusions: To minimise the lethal consequences of an PHA's impact, a well-constrained interception timing is necessary. Too early interception may not be ideal for PHAs in the Apollo or Aten groups. The best time to intercept PHA is when it is at the pericentre of its orbit.Comment: Accepted for publication in A&A Letter

The detection of subsurface stream channels in carbonate rocks by geoelectrical methods

Student supported: 1 Student AssistantThe distinction of partially dissolved from compact carbonate rocks and from the alluvial overburden is a major problem in geological engineering and water resources. Geoelectrical depth soundings after Schlumberger were applied over karst terraines in three locations of the Ozarks in Missouri. The zone of dissolved carbonate rock shows intermediate resistivities between low values for the overburden and extremely high values for the compact rock. The main part of the investigation was directed towards solving the underground flow and disappearance of Logan Creek near Ellington, Missouri. Combined geoelectrical and gravity surveys under consideration of some near surface seismic refractions indicate zones of increased depth and degree of dissolution at the Ellington Fault. A detailed gravity profile across the fault shows a negative anomaly with a minimum of -2.0 mgal, which extends over approximately 3 miles with large lateral gradients. A theoretical model can explain the anomaly if the depth of the cavernous limestone has a maximum of 350 feet and if the bulk volume of fissures and stream channels amounts to 15 percent. The coincidence between the fault and the negative anomaly suggests that ruptures along fault planes weakened the rock so that chemical dissolution from surface waters had a greater penetration.Project # A-065-MO Agreement # 14-31-0001-382

Field Measurements of Penetrator Seismic Coupling in Sediments and Volcanic Rocks

Field experiments were conducted to determine how well a seismometer installed using a penetrator would be coupled to the ground. A dry-lake bed and a lava bed were chosen as test sites to represent geological environments of two widely different material properties. At each site, two half-scale penetrators were fired into the ground, a three-component geophone assembly was mounted to the aft end of each penetrator, and dummy penetrators were at various distances to generate seismic signals. These signals were detected by the penetrator-mounted geophone assembly and by a reference geophone assembly buried or anchored to surface rock and 1-m from the penetrator. The recorded signals were digitized, and cross-spectral analyses were performed to compare the observed signals in terms of power spectral density ratio, coherence, and phase difference. The analyses indicate that seismometers deployed by penetrators will be as well coupled to the ground as are seismometers installed by conventional methods for the frequency range of interest in earthquake seismology

Holidaying with the family pet: No dogs allowed!

This paper assesses the extent to which dog owners located in Brisbane, Australia, wish to holiday with their pets, and whether there is a gap between this desire and reality. The paper also examines the extent to which this demand is being catered for by the tourism accommodation sector. The need for this study reflects the increasingly significant role dogs are playing in the lives of humans, and the scale of the dog-owning population. The results suggest that, although there is a strong desire among dog owners to take holidays with their pets, the actualisation of this desire is comparatively low. A significant obstacle to the realisation of this desire appears to be a dearth of pet-friendly accommodation. This has implications for the ability of the tourism industry to benefit from this potentially lucrative market, that is, the dog-owning population

Coherent phenomena in mesoscopic systems

A mesoscopic system of cylindrical geometry made of a metal or a semiconductor is shown to exhibit features of a quantum coherent state. It is shown that magnetostatic interaction can play an important role in mesoscopic systems leading to an ordered ground state. The temperature $T^{*}$ below the system exhibits long-range order is determined. The self-consistent mean field approximation of the magnetostatic interaction is performed giving the effective Hamiltonian from which the self-sustaining currents can be obtained. The relation of quantum coherent state in mesoscopic cylinders to other coherent systems like superconductors is discussed.Comment: REVTeX, 4 figures, in print in Supercond. Sci. Techno

The effects of incisional bupivacaine infusions on postoperative opioid consumption and pain scores after total abdominal hysterectomy

Background: The aim of this study was to determine opioid requirements and pain intensity scores in patients after a total abdominal hysterectomy (TAH) administered with a bupivacaine infusion for a 30-hour period, and then to compare the data with that of a control group. Method: This was a prospective, parallel, single-blinded randomised trial which took place at the Rahima Moosa Mother and Child Hospital, Johannesburg. Thirty-six consenting patients, who underwent a TAH, were randomised to either having a 0.39% bupivacaine infusion in the incisional site or not. Morphine was administered via a patient-controlled analgesia pump (PCA) for rescue analgesia. Dynamic, static and worst pain scores were assessed one, six and 30 hours after surgery by using a visual analogue scale (VAS). Morphine consumption was recorded at set intervals. Results: There were statistically significant differences between the two groups’ dynamic VAS scores in the first hour and at 24 hours and 30 hours; in the static VAS score in the first hour; and in the VAS scores for the worst pain experienced since the patients were last seen in the first hour and six hours after the operation. There was no statistical difference between the two groups’ opioid consumption at all set observation points. Conclusion: The opioid requirements of the two groups were comparable, although participants who had the bupivacaine infusion experienced reduced pain intensity which lasted until six hours postoperatively, and also had reduced pain intensity when moving around 30 hours after the operation.Keywords: incisional bupivacaine infusions, total abdominal hysterectomy, postoperative pain contro

Microbiology and atmospheric processes: Biological, physical and chemical characterization of aerosol particles

The interest in bioaerosols has traditionally been linked to health hazards for humans, animals and plants. However, several components of bioaerosols exhibit physical properties of great significance for cloud processes, such as ice nucleation and cloud condensation. To gain a better understanding of their influence on climate, it is therefore important to determine the composition, concentration, seasonal fluctuation, regional diversity and evolution of bioaerosols. In this paper, we will review briefly the existing techniques for detection, quantification, physical and chemical analysis of biological particles, attempting to bridge physical, chemical and biological methods for analysis of biological particles and integrate them with aerosol sampling techniques. We will also explore some emerging spectroscopy techniques for bulk and single-particle analysis that have potential for in-situ physical and chemical analysis. Lastly, we will outline open questions and further desired capabilities (e. g., in-situ, sensitive, both broad and selective, on-line, time-resolved, rapid, versatile, cost-effective techniques) required prior to comprehensive understanding of chemical and physical characterization of bioaerosols