Paradox of Peroxy Defects and Positive Holes in Rocks Part II: Outflow of Electric Currents from Stressed Rocks

Understanding the electrical properties of rocks is of fundamental interest. We report on currents generated when stresses are applied. Loading the center of gabbro tiles, 30x30x0.9 cm$^3$, across a 5 cm diameter piston, leads to positive currents flowing from the center to the unstressed edges. Changing the constant rate of loading over 5 orders of magnitude from 0.2 kPa/s to 20 MPa/s produces positive currents, which start to flow already at low stress levels, <5 MPa. The currents increase as long as stresses increase. At constant load they flow for hours, days, even weeks and months, slowly decreasing with time. When stresses are removed, they rapidly disappear but can be made to reappear upon reloading. These currents are consistent with the stress-activation of peroxy defects, such as O$_3$Si-OO-SiO$_3$, in the matrix of rock-forming minerals. The peroxy break-up leads to positive holes h$^{\bullet}$, i.e. electronic states associated with O$^-$ in a matrix of O$^{2-}$, plus electrons, e'. Propagating along the upper edge of the valence band, the holes are able to flow from stressed to unstressed rock, traveling fast and far by way of a phonon-assisted electron hopping mechanism using energy levels at the upper edge of the valence band. Impacting the tile center leads to h$^{\bullet}$ pulses, 4-6 ms long, flowing outward at ~100 m/sec at a current equivalent to 1-2 x 10$^9$ A/km$^3$. Electrons, trapped in the broken peroxy bonds, are also mobile, but only within the stressed volume.Comment: 33 pages, 19 figure

Analysis of minerals containing dissolved traces of the fluid phase components water and carbon dioxide

Substantial progress has been made towards a better understanding of the dissolution of common gas/fluid phase components, notably H2O and CO2, in minerals. It has been shown that the dissolution mechanisms are significantly more complex than currently believed. By judiciously combining various solid state analytical techniques, convincing evidence was obtained that traces of dissolved gas/fluid phase components undergo, at least in part, a redox conversion by which they split into reduced H2 and and reduced C on one hand and oxidized oxygen, O(-), on the other. Analysis for 2 and C as well as for any organic molecules which may form during the process of co-segregation are still impeded by the omnipresent danger of extraneous contamination. However, the presence of O(-), an unusual oxidized form of oxygen, has been proven beyond a reasonable doubt. The presence of O(-) testifies to the fact that a redox reaction must have taken place in the solid state involving the dissolved traces of gas/fluid phase components. Detailed information on the techniques used and the results obtained are given

Electrical Conductivity of Rocks and Dominant Charge Carriers

The prevailing view in the geophysics community is that the electrical conductivity structure of the Earth's continental crust over the 5-35 km depth range can best be understood by assuming the presence of intergranular fluids and/or of intragranular carbon films. Based on single crystal studies of melt-grown MgO, magma-derived sanidine and anorthosite feldspars and upper mantle olivine, we present evidence for the presence of electronic charge carriers, which derive from peroxy defects that are introduced during cooling, under non-equilibrium conditions, through a redox conversion of pairs of solute hydroxyl arising from dissolution of H2O.The peroxy defects become thermally activated in a 2-step process, leading to the release of defect electrons in the oxygen anion sublattice. Known as positive holes and symbolized by h(dot), these electronic charge carriers are highly mobile. Chemically equivalent to O(-) in a matrix of O(2-) they are highly oxidizing. Being metastable they can exist in the matrix of minerals, which crystallized in highly reduced environments. The h(dot) are highly mobile. They appear to control the electrical conductivity of crustal rocks in much of the 5-35 km depth range

Electromagnetic Basis of Metabolism and Heredity

Living organisms control their cellular biological clocks to maintain functional oscillation of the redox cycle, also called the "metabolic cycle" or "respiratory cycle". Organization of cellular processes requires parallel processing on a synchronized time-base. These clocks coordinate the timing of all biochemical processes in the cell, including energy production, DNA replication, and RNA transcription. When this universal time keeping function is perturbed by exogenous induction of reactive oxygen species (ROS), the rate of metabolism changes. This causes oxidative stress, aging and mutations. Therefore, good temporal coordination of the redox cycle not only actively prevents chemical conflict between the reductive and oxidative partial reactions; it also maintains genome integrity and lifespan. Moreover, this universal biochemical rhythm can be disrupted by ROS induction in vivo. This in turn can be achieved by blocking the electron transport chain either endogenously or exogenously by various metabolites, e.g. hydrogen sulfide (H2S), highly diffusible drugs, and carbon monoxide (CO). Alternatively, the electron transport in vivo can be attenuated via a coherent or interfering transfer of energy from exogenous ultralow frequency (ULF) and extremely low frequency (ELF) electromagnetic (EM) fields, suggesting that-on Earth-such ambient fields are an omnipresent (and probably crucially important) factor for the time-setting basis of universal biochemical reactions in living cells. Our work demonstrated previously un-described evidence for quantum effects in biology by electromagnetic coupling below thermal noise at the universal electron transport chain (ETC) in vivo

Reactive Oxygen Species on the Early Earth and Survival of Bacteria

An oxygen-rich atmosphere appears to have been a prerequisite for complex, multicellular life to evolve on Earth and possibly elsewhere in the Universe. However it remains unclear how free oxygen first became available on the early Earth. A potentially important, and as yet poorly constrained pathway, is the production of oxygen through the weathering of rocks and release into the near-surface environment. Reactive Oxygen Species (ROS), as precursors to molecular oxygen, are a key step in this process, and may have had a decisive impact on the evolution of life, present and past. ROS are generated from minerals in igneous rocks during hydrolysis of peroxy defects, which consist of pairs of oxygen anions oxidized to the valence state -1 and during (bio) transformations of iron sulphide minerals. ROS are produced and consumed by intracellular and extracellular reactions of Fe, Mn, C, N, and S species. We propose that, despite an overall reducing or neutral oxidation state of the macroenvironment and the absence of free O2 in the atmosphere, organisms on the early Earth had to cope with ROS in their microenvironments. They were thus under evolutionary pressure to develop enzymatic and other defences against the potentially dangerous, even lethal effects of oxygen and its derived ROS. Conversely it appears that microorganisms learned to take advantage of the enormous reactive potential and energy gain provided by nascent oxygen. We investigate how oxygen might be released through weathering. We test microorganisms in contact with rock surfaces and iron sulphides. We model bacteria such as Deionococcus radiodurans and Desulfotomaculum, Moorella and Bacillus species for their ability to grow or survive in the presence of ROS. We examine how early Life might have adapted to oxygen

Precise Chemical Analyses of Planetary Surfaces

We identify the chemical elements and element ratios that should be analyzed to address many of the issues identified by the Committee on Planetary and Lunar Exploration (COMPLEX). We determined that most of these issues require two sensitive instruments to analyze the necessary complement of elements. In addition, it is useful in many cases to use one instrument to analyze the outermost planetary surface (e.g. to determine weathering effects), while a second is used to analyze a subsurface volume of material (e.g., to determine the composition of unaltered planetary surface material). This dual approach to chemical analyses will also facilitate the calibration of orbital and/or Earth-based spectral observations of the planetary body. We determined that in many cases the scientific issues defined by COMPLEX can only be fully addressed with combined packages of instruments that would supplement the chemical data with mineralogic or visual information

Ground Water Chemistry Changes before Major Earthquakes and Possible Effects on Animals

Prior to major earthquakes many changes in the environment have been documented. Though often subtle and fleeting, these changes are noticeable at the land surface, in water, in the air, and in the ionosphere. Key to understanding these diverse pre-earthquake phenomena has been the discovery that, when tectonic stresses build up in the Earth’s crust, highly mobile electronic charge carriers are activated. These charge carriers are defect electrons on the oxygen anion sublattice of silicate minerals, known as positive holes, chemically equivalent to O− in a matrix of O2−. They are remarkable inasmuch as they can flow out of the stressed rock volume and spread into the surrounding unstressed rocks. Travelling fast and far the positive holes cause a range of follow-on reactions when they arrive at the Earth’s surface, where they cause air ionization, injecting massive amounts of primarily positive air ions into the lower atmosphere. When they arrive at the rock-water interface, they act as •O radicals, oxidizing water to hydrogen peroxide. Other reactions at the rock-water interface include the oxidation or partial oxidation of dissolved organic compounds, leading to changes of their fluorescence spectra. Some compounds thus formed may be irritants or toxins to certain species of animals. Common toads, Bufo bufo, were observed to exhibit a highly unusual behavior prior to a M6.3 earthquake that hit L’Aquila, Italy, on April 06, 2009: a few days before the seismic event the toads suddenly disappeared from their breeding site in a small lake about 75 km from the epicenter and did not return until after the aftershock series. In this paper we discuss potential changes in groundwater chemistry prior to seismic events and their possible effects on animals

Exploration of Charge Carriers in Obsidian

This research effort is part of an ongoing investigation into stress-activated positive hole charge carriers in common igneous and high-grade metamorphic rocks. The findings have already revealed potential early earthquake detection mechanisms and caused a re-think on the processes that could conceivably contribute to the formation of and evolution of life. Positive holes are defect electrons in the oxygen anion sub-lattice of silicate minerals that have demonstrated some intriguing capabilities: flowing out of a stressed rock volume; causing oxidation reactions at the rock-water interface and ionization at the rock-air interface; and traveling great distances. This research seeks to determine if obsidian (volcanic glass) is also capable of yielding stress- or temperature-activated charge carriers. In this study, a measurable change in current and voltage when obsidian samples are put under mechanical stress would suggest that charge carriers are available. The motivation for this research, among other reasons, is that it will add breadth to positive hole phenomena; provide additional evidence for stress- or temperature-activated positive hole formation; and create possibilities for monitoring volcano activity

Radar Reflectivity Experiment: Infrared Measurements

Before large earthquakes and volcanic eruptions, the increased stress and temperature activates electronic charge carriers within the Earth’s crust. The charge carriers can diffuse out of the stressed rock and travel for kilometers throughout the surround rocks. Once at the Earth’s surface, the charge carriers can react in a variety of processes – which can be detected remotely. One process involves the charge carriers releasing energy as infrared emissions – which are detected in satellites as “thermal infrared anomalies.” Our experiment involves stressing large blocks of basic rocks with expanding cement and detecting the infrared emissions. We will focus on how the thermal infrared band is distributed spatially over the rock and how the emission changes as a function of time during build-up of stress until the rock breaks