Magnetic properties of the double perovskites LaPbMSbO6 (M = Mn, Co and Ni)

New double perovskites LaPbMSbO6, where M2+ = Mn2+, Co2+, and Ni2+, were synthesized as polycrystals by an aqueous synthetic route at temperatures below 1000 oC. All samples are monoclinic, space group P21/n, as obtained from Rietveld analysis of X-ray powder diffraction patterns. The distribution of M2+ and Sb5+ among the two octahedral sites have 3% of disorder for M2+ = Ni2+, whereas for M2+ = Mn2+ and Co2+ less disorder is found. The three samples have an antiferromagnetic transition, due to the antiferromagnetic coupling between M2+ through super-superexchange paths M2+ - O2- - Sb5+ - O2- - M2+. Transition temperatures are low: 8, 10 and 17 K for Mn2+, Co2+, and Ni2+ respectively, as a consequence of the relatively long distances between the magnetic ions M2+. Besides, for LaPbMnSbO6 a small transition at 45 K was found, with ferrimagnetic characteristics, possibly as a consequence of a small disorder between Mn2+ and Sb5+. This disorder would give additional and shorter interaction paths: superexchange Mn2+ - O2- - Mn2+.Comment: 4 pages, 4 figures included. Manuscript submitted to IEEE Transactions on Magnetics, proceedings of the LAW3M 2013 conferenc

Positive solutions of nonlinear fourth-order boundary-value problems with local and non-local boundary conditions

We establish new existence results for multiple positive solutions of fourth-order nonlinear equations which model deflections of an elastic beam. We consider the widely studied boundary conditions corresponding to clamped and hinged ends and many non-local boundary conditions, with a unified approach. Our method is to show that each boundary-value problem can be written as the same type of perturbed integral equation, in the space $C[0,1]$, involving a linear functional $\alpha[u]$ but, although we seek positive solutions, the functional is not assumed to be positive for all positive $u$. The results are new even for the classic boundary conditions of clamped or hinged ends when $\alpha[u]=0$, because we obtain sharp results for the existence of one positive solution; for multiple solutions we seek optimal values of some of the constants that occur in the theory, which allows us to impose weaker assumptions on the nonlinear term than in previous works. Our non-local boundary conditions contain multi-point problems as special cases and, for the first time in fourth-order problems, we allow coefficients of both signs

Tailoring the ground state of the ferrimagnet La2Ni(Ni1/3Sb2/3)O6

We report on the magnetic and structural properties of La2Ni(Ni1/3Sb2/3)O6 in polycrystal, single crystal and thin film samples. We found that this material is a ferrimagnet (Tc ~ 100 K) which possesses a very distinctive and uncommon feature in its virgin curve of the hysteresis loops. We observe that bellow 20 K it lies outside the hysteresis cycle, and this feature was found to be an indication of a microscopically irreversible process possibly involving the interplay of competing antiferromagnetic interactions that hinder the initial movement of domain walls. This initial magnetic state is overcome by applying a temperature dependent characteristic field. Above this field, an isothermal magnetic demagnetization of the samples yield a ground state different from the initial thermally demagnetized one.Comment: 21 pages, 8 figures, submitted to JMM

Positronium signature in organic liquid scintillators for neutrino experiments

Electron anti-neutrinos are commonly detected in liquid scintillator experiments via inverse beta decay, by looking at the coincidence between the reaction products, neutron and positron. Prior to positron annihilation, an electron-positron pair may form an orthopositronium (o-Ps) state, with a mean life of a few ns. Even if the o-Ps decay is speeded up by spin flip or pick off effects, it may introduce distortions in the photon emission time distribution, crucial for position reconstruction and pulse shape discrimination algorithms in anti-neutrino experiments. Reversing the problem, the o-Ps induced time distortion represents a new signature for tagging anti-neutrinos in liquid scintillator. In this paper, we report the results of measurements of the o-Ps formation probability and lifetime, for the most used solvents for organic liquid scintillators in neutrino physics (pseudocumene, linear alkyl benzene, phenylxylylethane, and dodecane). We characterize also a mixture of pseudocumene +1.5 g/l of 2,5-diphenyloxazole, a fluor acting as wavelength shifter. In the second part of the paper, we demonstrate that the o-Ps induced distortion of the scintillation photon emission time distributions represent an optimal signature for tagging positrons on an event by event basis, potentially enhancing the anti-neutrino detection.Comment: 6 pages, 9 figure

Fractal Fidelity as a signature of Quantum Chaos

We analyze the fidelity of a quantum simulation and we show that it displays fractal fluctuations iff the simulated dynamics is chaotic. This analysis allows us to investigate a given simulated dynamics without any prior knowledge. In the case of integrable dynamics, the appearance of fidelity fractal fluctuations is a signal of a highly corrupted simulation. We conjecture that fidelity fractal fluctuations are a signature of the appearance of quantum chaos. Our analysis can be realized already by a few qubit quantum processor.Comment: 5 pages, 5 figure

A new anti-neutrino detection technique based on positronium tagging with plastic scintillators

The main signature for anti-neutrino detection in reactor and geo-neutrino experiments based on scintillators is provided by the space-time coincidence of positron and neutron produced in the Inverse Beta Decay reaction. Such a signature strongly suppresses backgrounds and allows for measurements performed underground with a relatively high signal-to-background ratio. In an aboveground environment, however, the twofold coincidence technique is not sufficient to efficiently reject the high background rate induced by cosmogenic events. Enhancing the positron-neutron twofold coincidence efficiency has the potential to pave the way future aboveground detectors for reactor monitoring. We propose a new detection scheme based on a threefold coincidence, between the positron ionization, the ortho-positronium (o-Ps) decay, and the neutron capture, in a sandwich detector with alternated layers of plastic scintillator and aerogel powder. We present the results of a set of dedicated measurements on the achievable light yield and on the o-Ps formation and lifetime. The efficiencies for signal detection and background rejection of a preliminary detector design are also discussed.Comment: 18 pages, 10 figure

An SU(5)⊗\otimesZ_{13} Grand Unification Model

We propose an SU(5) grand unified model with an invisible axion and the unification of the three coupling constants which is in agreement with the values, at $M_Z$, of $\alpha$, $\alpha_s$, and $\sin^2\theta_W$. A discrete, anomalous, $Z_{13}$ symmetry implies that the Peccei-Quinn symmetry is an automatic symmetry of the classical Lagrangian protecting, at the same time, the invisible axion against possible semi-classical gravity effects. Although the unification scale is of the order of the Peccei-Quinn scale the proton is stabilized by the fact that in this model the standard model fields form the SU(5) multiplets completed by new exotic fields and, also, because it is protected by the $Z_{13}$ symmetry.Comment: 14 pages, more typos correcte

Submillimeter H2O masers in water-fountain nebulae

We report the first detection of submillimeter water maser emission toward water-fountain nebulae, which are post-AGB stars that exhibit high-velocity water masers. Using APEX we found emission in the ortho-H2O (10_29-9_36) transition at 321.226 GHz toward three sources: IRAS 15445-5449, IRAS 18043-2116 and IRAS 18286-0959. Similarly to the 22 GHz masers, the submillimeter water masers are expanding with a velocity larger than that of the OH masers, suggesting that these masers also originate in fast bipolar outflows. In IRAS 18043-2116 and IRAS 18286-0959, which figure among the sources with the fastest water masers, the velocity range of the 321 GHz masers coincides with that of the 22 GHz masers, indicating that they likely coexist. Towards IRAS 15445-5449 the submillimeter masers appear in a different velocity range, indicating that they are tracing different regions. The intensity of the submillimeter masers is comparable to that of the 22 GHz masers, implying that the kinetic temperature of the region where the masers originate should be Tk > 1000 K. We propose that the passage of two shocks through the same gas can create the conditions necessary to explain the presence of strong high-velocity 321 GHz masers coexisting with the 22 GHz masers in the same region.Comment: 4 pages, 1 figure. Accepted for publication in A&A Letter