Electrooptical behavior of twisted-wedge nematic structures

A new type of domain in twisted-wedge negative nematics is reported. The wedge shape allows the separation of ordinary and extraordinary beams that can be studied separately. In these conditions, at least five different regions can be detected, depending on applied voltages and frequencies. Both rays are shown to yield different diffraction patterns. The relative light intensity of several spots of these paterns is also studied

Controlling the Photonic Properties of Cholesteric Cellulose Nanocrystal Films with Magnets

The self-assembly of cellulose nanocrystals is a powerful method for the fabrication of biosourced photonic films with a chiral optical response. While various techniques have been exploited to tune the optical properties of such systems, the presence of external fields has yet to be reported to significantly modify their optical properties. In this work, by using small commercial magnets (≈ 0.5-1.2 T) the orientation of the cholesteric domains is enabled to tune in suspension as they assemble into films. A detailed analysis of these films shows an unprecedented control of their angular response. This simple and yet powerful technique unlocks new possibilities in designing the visual appearance of such iridescent films, ranging from metallic to pixelated or matt textures, paving the way for the development of truly sustainable photonic pigments in coatings, cosmetics, and security labeling.This work was supported by a BBSRC David Phillips fellowship [BB/K014617/1], the EPSRC [1525292] and the European Research Council [ERC-2014-STG H2020 639088]

Magnetic properties of liquid crystals

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