Influence of the microstructure on the magnetism of Co-doped ZnO thin films

The prediction of ferromagnetism at room temperature in Co-ZnO thin films has generated a large interest in the community due to the possible applications. However, the results are controversial, going from ferromagnetism to non-ferromagnetism, leading to a large debate about its origin (secondary phase, Co clusters or not). By carefully studying the micro-structure of various Co-ZnO films, we show that the Co2+ partly substitutes the ZnO wurtzite matrix without forming Co clusters. Surprisingly, the ferromagnetism nature of the films disappears as the Co content increases. In addition, our results suggest that the observed ferromagnetism is likely associated to a large amount of defects- close to the interface and strongly depending on the growth temperature- which may explained the spreading of the results.Comment: 4 pages, 4 figures, to be published in Journal of Applied Physics (2006

Investigation of laser ablated ZnO thin films grown with Zn metal target: a structural study

High quality ZnO thin films were gown using the pulsed laser deposition technique on (0001) Al$_2$O$_3$ substrates in an oxidizing atmosphere, using a Zn metallic target. We varied the growth conditions such as the deposition temperature and the oxygen pressure. First, using a battery of techniques such as x-rays diffraction, Rutherford Backscattering spectroscopy and atomic force microscopy, we evaluated the structural quality, the stress and the degree of epitaxy of the films. Second, the relations between the deposition conditions and the structural properties, that are directly related to the nature of the thin films, are discussed qualitatively. Finally, a number of issues on how to get good-quality ZnO films are addressed.Comment: To be published in Jour. Appl. Phys. (15 August 2004

Structural and magnetic properties of a series of low doped Zn1−x_{1-x}Cox_xO thin films deposited from Zn and Co metal targets on (0001) Al2_2O3_3 substrates

We report on the synthesis of low doping Zn$_{1-x}$Co$_x$O ($0<x<0.1$) thin films on (0001)-Al$_2$O$_3$ substrates. The films were prepared in an oxidizing atmosphere, using the pulsed laser deposition technique starting from Zn and Co metallic targets. We first studied the influence of the strains of ZnO and their stuctural properties. Second, we have investigated the structural and the magnetic properties of the Zn$_{1-x}$Co$_x$O films. We show that at low doping, the lattice parameters and the magnetization of the Zn$_{1-x}$Co$_x$O films depend strongly on the Co concentration.Comment: to be published in Journal Applied Physics (June 2004) as a proceeding of the MMM/Intermag Conferenc

Gap Formation in the Dust Layer of 3D Protoplanetary Disks

We numerically model the evolution of dust in a protoplanetary disk using a two-phase (gas+dust) Smoothed Particle Hydrodynamics (SPH) code, which is non-self-gravitating and locally isothermal. The code follows the three dimensional distribution of dust in a protoplanetary disk as it interacts with the gas via aerodynamic drag. In this work, we present the evolution of a disk comprising 1% dust by mass in the presence of an embedded planet for two different disk configurations: a small, minimum mass solar nebular (MMSN) disk and a larger, more massive Classical T Tauri star (CTTS) disk. We then vary the grain size and planetary mass to see how they effect the resulting disk structure. We find that gap formation is much more rapid and striking in the dust layer than in the gaseous disk and that a system with a given stellar, disk and planetary mass will have a different appearance depending on the grain size and that such differences will be detectable in the millimetre domain with ALMA. For low mass planets in our MMSN models, a gap can open in the dust disk while not in the gas disk. We also note that dust accumulates at the external edge of the planetary gap and speculate that the presence of a planet in the disk may facilitate the growth of planetesimals in this high density region.Comment: 5 page, 4 figures. Accepted for publication in Astrophysics & Space Scienc

The CH4_4 abundance in Jupiter's upper atmosphere

Hydrocarbon species, and in particular CH$_4$, play a key role in the stratosphere--thermosphere boundary of Jupiter, which occurs around the $\mu$-bar pressure level. Previous analyses of solar occultation, He and Ly-$\alpha$ airglow, and ISO/SWS measurements of the radiance around 3.3 $\mu$m have inferred significantly different methane concentrations. Here we aim to accurately model the CH$_4$ radiance at 3.3 $\mu$m measured by ISO/SWS by using a comprehensive non-local thermodynamic equilibrium model and the most recent collisional rates measured in the laboratory for CH$_4$ to shed new light onto the methane concentration in the upper atmosphere of Jupiter. These emission bands have been shown to present a peak contribution precisely at the $\mu$-bar level, hence directly probing the region of interest. We find that a high CH$_4$ concentration is necessary to explain the data, in contrast with the most recent analyses, and that the observations favour the lower limit of the latest laboratory measurements of the CH$_4$ collisional relaxation rates. Our results provide precise constraints on the composition and dynamics of the lower atmosphere of Jupiter.Comment: 15 pages; accepted for publication in A&

Detection of CO and HCN in Pluto's atmosphere with ALMA

Observations of the Pluto-Charon system, acquired with the ALMA interferometer on June 12-13, 2015, have yielded a detection of the CO(3-2) and HCN(4-3) rotational transitions from Pluto, providing a strong confirmation of the presence of CO, and the first observation of HCN, in Pluto's atmosphere. The CO and HCN lines probe Pluto's atmosphere up to ~450 km and ~900 km altitude, respectively. The CO detection yields (i) a much improved determination of the CO mole fraction, as 515+/-40 ppm for a 12 ubar surface pressure (ii) clear evidence for a well-marked temperature decrease (i.e., mesosphere) above the 30-50 km stratopause and a best-determined temperature of 70+/-2 K at 300 km, in agreement with recent inferences from New Horizons / Alice solar occultation data. The HCN line shape implies a high abundance of this species in the upper atmosphere, with a mole fraction >1.5x10-5 above 450 km and a value of 4x10-5 near 800 km. The large HCN abundance and the cold upper atmosphere imply supersaturation of HCN to a degree (7-8 orders of magnitude) hitherto unseen in planetary atmospheres, probably due to the slow kinetics of condensation at the low pressure and temperature conditions of Pluto's upper atmosphere. HCN is also present in the bottom ~100 km of the atmosphere, with a 10-8 - 10-7 mole fraction; this implies either HCN saturation or undersaturation there, depending on the precise stratopause temperature. The HCN column is (1.6+/-0.4)x10^14 cm-2, suggesting a surface-referred net production rate of ~2x10^7 cm-2s-1. Although HCN rotational line cooling affects Pluto's atmosphere heat budget, the amounts determined in this study are insufficient to explain the well-marked mesosphere and upper atmosphere's ~70 K temperature. We finally report an upper limit on the HC3N column density (< 2x10^13 cm-2) and on the HC15N / HC14N ratio (< 1/125).Comment: Revised version. Icarus, in press, Oct. 11, 2016. 57 pages, including 13 figures and 4 table

Non-epileptic seizures: delayed diagnosis in patients presenting with electroencephalographic (EEG) or clinical signs of epileptic seizures

AbstractThe clinical differentiation between epileptic seizures (ES) and non-epileptic seizures (NES) is often difficult and mostly based on the presence or absence of widely recognized features of ES such as tongue biting, falling, incontinence or concomitant epileptic abnormalities in the electroencephalogram (EEG). We retrospectively analysed the records of all patients referred to our Epilepsy Centre for refractory epilepsy and finally diagnosed with NES between 1980 and 1999 ( n= 103), half of them also exhibiting ES. The mean time-lapse between first attack and NES diagnosis was 8.7 ± 1.3 years and 16.5 ± 1.4 years for the NES and NES + ES groups respectively. At least one of the usual signs associated with generalized tonic–clonic seizures (tongue biting, falling or incontinence) was reported by 66% and 60% of patients with NES or NES + ES respectively. Interictal EEG abnormalities were recorded in 16% of NES patients vs. 80% of NES + ES patients. In the NES group, delay before establishing the correct diagnosis was significantly longer when the patients exhibited ≥1 symptom(s) of generalized seizures, or when patients exhibited interictal EEG abnormalities. Upon admission, 72% of NES patients and all NES + ES patients were being treated with antiepileptic drugs (AEDs).We conclude that EEG or clinical abnormalities suggestive of epileptic seizures are common in undiagnosed NES patients. Such diagnostic pitfalls, besides considerably delaying NES diagnosis, also considerably delay appropriate treatment implementation

Hubbard band or oxygen vacancy states in the correlated electron metal SrVO3_3?

We study the effect of oxygen vacancies on the electronic structure of the model strongly correlated metal SrVO$_3$. By means of angle-resolved photoemission (ARPES) synchrotron experiments, we investigate the systematic effect of the UV dose on the measured spectra. We observe the onset of a spurious dose-dependent prominent peak at an energy range were the lower Hubbard band has been previously reported in this compound, raising questions on its previous interpretation. By a careful analysis of the dose dependent effects we succeed in disentangling the contributions coming from the oxygen vacancy states and from the lower Hubbard band. We obtain the intrinsic ARPES spectrum for the zero-vacancy limit, where a clear signal of a lower Hubbard band remains. We support our study by means of state-of-the-art ab initio calculations that include correlation effects and the presence of oxygen vacancies. Our results underscore the relevance of potential spurious states affecting ARPES experiments in correlated metals, which are associated to the ubiquitous oxygen vacancies as extensively reported in the context of a two-dimensional electron gas (2DEG) at the surface of insulating $d^0$ transition metal oxides.Comment: Manuscript + Supplemental Material, 12 pages, 9 figure

The Exomars Climate Sounder (EMCS) Investigation

The ExoMars Climate Sounder (EMCS) investigation is developed at the Jet Propulsion Laboratory (Principal Investigator J. T. Schofield) in collaboration with an international scientific team from France, the United Kingdom and the USA. EMCS plans to map daily, global, pole-to-pole profiles of temperature, dust, water and CO2 ices, and water vapor from the proposed 2016 ExoMars Trace Gas Orbiter (EMTGO). These profiles are to be assimilated into Mars General Circulation Models (MGCMs) to generate global, interpolated fields of measured and derived parameters such as wind