Thiyl radicals are co-products of dinitrosyl iron complex (DNIC) formation.

Thiyl radicals are detected by EPR as co-products of dinitrosyl iron complex (DNIC) formation. In demonstrating that DNIC formation generates RS˙ in a NO rich environment, these results provide a novel route for S-nitroso thiol formation

Surface fitting three-dimensional bodies

The geometry of general three-dimensional bodies was generated from coordinates of points in several cross sections. Since these points may not be on smooth curves, they are divided into groups forming segments and general conic sections are curve fit in a least-squares sense to each segment of a cross section. The conic sections are then blended in the longitudinal direction through longitudinal curves. Both the cross-sectional and longitudinal curves may be modified by specifying particular segments as straight lines or specifying slopes at selected points. This method was used to surface fit a 70 deg slab delta wing and the HL-10 Lifting Body. The results for the delta wing were very close to the exact geometry. Although there is no exact solution for the lifting body, the surface fit generated a smooth surface with cross-sectional planes very close to prescribed coordinate points

AGRICULTURAL POLICY DEVELOPMENTS IN THE UNITED STATES: 1991-93

Agricultural and Food Policy,

TRENDS AND DEVELOPMENTS IN UNITED STATES AGRICULTURAL POLICY: 1993-1995

A number of factors including budget pressures, emphasis on environmentally sensitive agriculture, emphasis on finding agricultural export markets, and anti-agricultural program sentiment have fueled a climate for change in United States agricultural policy. Whether significant changes will occur depends on the political strength of agricultural interest groups and on the compromises which can be reached between them. Several notable achievements have been accomplished in recent domestic agricultural policy legislation. The 1995 farm bill will define the commodity and conservation programs for the next five years. In addition to domestic developments, there have been history-setting accomplishments in reducing barriers to international agricultural trade. The tri-partite North American Free Trade Agreement became effective January 1, 1994. The Uruguay Round Agreement of the General Agreement on Tariffs and Trade was completed in late 1994 and will become effective in 1995.Agricultural and Food Policy,

Inelastic scattering calculations with projected Hartree-Fock wave functions: Coupled channel treatment

Microscopic coupled-channel analysis of proton inelastic scattering from neon and magnesium ion

Deformed Brueckner-Hartree-Fock calculations

The renormalized Brueckner-Hartree-Fock (RBHF) theory for many-body nuclear systems is generalized to permit calculations for intrinsic states having permanent deformation. Both Hartree-Fock and Brueckner self-consistencies are satisfied, and details of the numerical techniques are discussed. The Hamada-Johnston interaction is used in a study of deformations, binding, size, and separation energies for several nuclei. Electromagnetic transition rates, moments, and electron scattering form factors are calculated using nuclear wave functions obtained by angular momentum projection. Comparison is made to experiment as well as to predictions of ordinary and density-dependent Hartree-Fock Theory

Short-range correlations in carbon-12, oxygen-16, and neon-20: Intrinsic properties

The Brueckner-Hartree-Fock (BHF) method has been applied to nuclei whose intrinsic structure is nonspherical. Reaction matrix elements were calculated as functions of starting energy for the Hamada-Johnston interaction using the Pauli operator appropriate to O-16 and a shifted oscillator spectrum for virtual excited states. Binding energies, single particle energies, radii, and shape deformations of the intrinsic state, in ordinary as well as renormalized BHF, are discussed and compared with previous HF studies and with experiment when possible. Results are presented for C-12, 0-16 and Ne-20. It is found that the binding energies and radii are too small, but that separation energies are well reproduced when the renormalized theory is used

Gravitons and Lightcone Fluctuations II: Correlation Functions

A model of a fluctuating lightcone due to a bath of gravitons is further investigated. The flight times of photons between a source and a detector may be either longer or shorter than the light propagation time in the background classical spacetime, and will form a Gaussian distribution centered around the classical flight time. However, a pair of photons emitted in rapid succession will tend to have correlated flight times. We derive and discuss a correlation function which describes this effect. This enables us to understand more fully the operational significance of a fluctuating lightcone. Our results may be combined with observational data on pulsar timing to place some constraints on the quantum state of cosmological gravitons.Comment: 16 pages and two figures, uses eps

Dynamics of Dinitrosyl Iron Complex (DNIC) Formation with Low Molecular Weight Thiols.

Dinitrosyl iron complexes (DNICs) are ubiquitous in mammalian cells and tissues producing nitric oxide (NO) and have been argued to play key physiological and pathological roles. Nonetheless, the mechanism and dynamics of DNIC formation in aqueous media remain only partially understood. Here, we report a stopped-flow kinetics and density functional theory (DFT) investigation of the reaction of NO with ferrous ions and the low molecular weight thiols glutathione (GSH) and cysteine (CysSH) as well as the peptides WCGPC and WCGPY to produce DNICs in pH 7.4 aqueous media. With each thiol, a two-stage reaction pattern is observed. The first stage involves several rapidly established pre-equilibria leading to a ferrous intermediate concluded to have the composition FeII(NO)(RS)2(H2O)x (C). In the second stage, C undergoes rate-limiting, unimolecular autoreduction to give thiyl radical (RS•) plus the mononitrosyl Fe(I) complex FeI(NO)(RS)(H2O)x following the reactivity order of CysSH > WCGPC > WCGPY > GSH. Time course simulations using the experimentally determined kinetics parameters demonstrate that, at a NO flux characteristic of inflammation, DNICs will be rapidly formed from intracellular levels of ferrous iron and thiols. Furthermore, the proposed mechanism offers a novel pathway for S-nitroso thiol (RSNO) formation in a biological environment

A study of the Hartree-Fock model space for light deformed nuclei

Effects of altering truncated basis space used in Hartree Fock model for light deformed nucle