9,394 research outputs found

    Van der Waals spin valves

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    We propose spin valves where a 2D non-magnetic conductor is intercalated between two ferromagnetic insulating layers. In this setup, the relative orientation of the magnetizations of the insulating layers can have a strong impact on the in-plane conductivity of the 2D conductor. We first show this for a graphene bilayer, described with a tight-binding model, placed between two ferromagnetic insulators. In the anti-parallel configuration, a band gap opens at the Dirac point, whereas in the parallel configuration, the graphene bilayer remains conducting. We then compute the electronic structure of graphene bilayer placed between two monolayers of the ferromagnetic insulator CrI3_3, using density functional theory. Consistent with the model, we find that a gap opens at the Dirac point only in the antiparallel configuration.Comment: 5 pages, 4 figure

    An error-controlled methodology for approximate hierarchical symbolic analysis

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    Limitations of existing approaches for symbolic analysis of large analog circuits are discussed. To address their solution, a new methodology for hierarchical symbolic analysis is introduced. The combination of a hierarchical modeling technique and approximation strategies, comprising circuit reduction, graph-based symbolic solution of circuit equations and matrix-based error control, provides optimum results in terms of speech and quality of results.European Commission ESPRIT 21812Comisión Interministerial de Ciencia y Tecnología TIC97-058

    Error control in simplification before generation algorithms for symbolic analysis of large analogue circuits

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    Circuit reduction is a fundamental first step in addressing the symbolic analysis of large analogue circuits. A new algorithm for simplification before generation is presented which is very efficient in terms of speed and the amount of circuit reduction, and solves the accuracy problems of previously reported approaches

    Extended WKB method, resonances and supersymmetric radial barriers

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    Semiclassical approximations are implemented in the calculation of position and width of low energy resonances for radial barriers. The numerical integrations are delimited by t/T<<8, with t the period of a classical particle in the barrier trap and T the resonance lifetime. These energies are used in the construction of `haired' short range potentials as the supersymmetric partners of a given radial barrier. The new potentials could be useful in the study of the transient phenomena which give rise to the Moshinsky's diffraction in time.Comment: 12 pages, 4 figures, 3 table

    Compressed k2-Triples for Full-In-Memory RDF Engines

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    Current "data deluge" has flooded the Web of Data with very large RDF datasets. They are hosted and queried through SPARQL endpoints which act as nodes of a semantic net built on the principles of the Linked Data project. Although this is a realistic philosophy for global data publishing, its query performance is diminished when the RDF engines (behind the endpoints) manage these huge datasets. Their indexes cannot be fully loaded in main memory, hence these systems need to perform slow disk accesses to solve SPARQL queries. This paper addresses this problem by a compact indexed RDF structure (called k2-triples) applying compact k2-tree structures to the well-known vertical-partitioning technique. It obtains an ultra-compressed representation of large RDF graphs and allows SPARQL queries to be full-in-memory performed without decompression. We show that k2-triples clearly outperforms state-of-the-art compressibility and traditional vertical-partitioning query resolution, remaining very competitive with multi-index solutions.Comment: In Proc. of AMCIS'201

    El concepto de diversidad vegetal desde la etnia mapuche a la enseñanza formal en Chile

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    El estudio de la terminología botánica en la lengua mapuche revela la gran importancia que la diversidad vegetal ha tenido para sus tradiciones y usos. Un colectivo de estudiantes de enseñanza media de origen mapuche conserva entre sus conocimientos de biología vegetal un rico aporte de esta información etnobotánica; sin embargo estudiantes que inician estudios universitarios de ingeniería forestal y agronomía muestran un nivel de conocimiento muy inferior. La enseñanza formal chilena puede aprovechar este potencial cultural para incorporarlo en una educación científica intercultural que favorezca la protección y respeto de los ecosistemas del Chile Central gravemente amenazados por los intereses de las grandes multinacionales que explotan sus recursos naturales

    Passivity Breakdown of Titanium in LiBr solutions

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    The passive behavior of titanium and its susceptibility to undergo localized attack in different LiBr solutions at 25 degrees C have been investigated using different electrochemical techniques: potentiodynamic polarization curves, potentiostatic passivation tests, EIS measurements and Mott-Schottky analysis. In low and moderately concentrated LiBr solutions, the breakdown potential E-b decreased with increasing bromide concentrations, while in highly concentrated LiBr solutions, E-b increased with increasing LiBr concentration. In the most concentrated LiBr solution (11.42M) Ti did not undergo passivity breakdown even at 9 V-Ag/AgCl. This observation can be explained by a a decrease in the activity of water in highly concentrated LiBr solutions. (C) 2013 The Electrochemical Society.We wish express our gratitude to the Ministerio de Ciencia e Innovacion (Project CTQ2009-07518), and to Dr. M. Asuncion Jaime. for her translation assistance.Fernández Domene, RM.; Blasco-Tamarit, E.; García-García, D.; García Antón, J. (2014). Passivity Breakdown of Titanium in LiBr solutions. Journal of The Electrochemical Society. 161(1):25-35. https://doi.org/10.1149/2.035401jesS25351611Been J. Grauman J. S. , in: Uhlig's Corrosion Handbook, 2nd ed., Winston Revie R. (ed.), 863-885, Wiley Interscience, New York (2000).Blasco-Tamarit, E., Igual-Muñoz, A., García Antón, J., & García-García, D. (2007). Corrosion behaviour and galvanic coupling of titanium and welded titanium in LiBr solutions. Corrosion Science, 49(3), 1000-1026. doi:10.1016/j.corsci.2006.07.007Huang, Y. Z., & Blackwood, D. J. (2005). Characterisation of titanium oxide film grown in 0.9% NaCl at different sweep rates. Electrochimica Acta, 51(6), 1099-1107. doi:10.1016/j.electacta.2005.05.051Pan, J., Thierry, D., & Leygraf, C. (1996). Electrochemical impedance spectroscopy study of the passive oxide film on titanium for implant application. Electrochimica Acta, 41(7-8), 1143-1153. doi:10.1016/0013-4686(95)00465-3Assis, S. L. de, Wolynec, S., & Costa, I. (2006). Corrosion characterization of titanium alloys by electrochemical techniques. Electrochimica Acta, 51(8-9), 1815-1819. doi:10.1016/j.electacta.2005.02.121Birch, J. R., & Burleigh, T. D. (2000). Oxides Formed on Titanium by Polishing, Etching, Anodizing, or Thermal Oxidizing. CORROSION, 56(12), 1233-1241. doi:10.5006/1.3280511Peláez-Abellán, E., Rocha-Sousa, L., Müller, W.-D., & Guastaldi, A. C. (2007). Electrochemical stability of anodic titanium oxide films grown at potentials higher than 3V in a simulated physiological solution. Corrosion Science, 49(3), 1645-1655. doi:10.1016/j.corsci.2006.08.010Azumi, K., & Seo, M. (2001). Changes in electrochemical properties of the anodic oxide film formed on titanium during potential sweep. Corrosion Science, 43(3), 533-546. doi:10.1016/s0010-938x(00)00105-0Alves, V. A., Reis, R. Q., Santos, I. C. B., Souza, D. G., de F. Gonçalves, T., Pereira-da-Silva, M. A., … da Silva, L. A. (2009). In situ impedance spectroscopy study of the electrochemical corrosion of Ti and Ti–6Al–4V in simulated body fluid at 25°C and 37°C. Corrosion Science, 51(10), 2473-2482. doi:10.1016/j.corsci.2009.06.035Schmidt, A. M., Azambuja, D. S., & Martini, E. M. A. (2006). Semiconductive properties of titanium anodic oxide films in McIlvaine buffer solution. Corrosion Science, 48(10), 2901-2912. doi:10.1016/j.corsci.2005.10.013Sellers, M. C. K., & Seebauer, E. G. (2011). Measurement method for carrier concentration in TiO2 via the Mott–Schottky approach. Thin Solid Films, 519(7), 2103-2110. doi:10.1016/j.tsf.2010.10.071Jiang, Z., Dai, X., & Middleton, H. (2011). Investigation on passivity of titanium under steady-state conditions in acidic solutions. Materials Chemistry and Physics, 126(3), 859-865. doi:10.1016/j.matchemphys.2010.12.028Kong, D.-S., Lu, W.-H., Feng, Y.-Y., Yu, Z.-Y., Wu, J.-X., Fan, W.-J., & Liu, H.-Y. (2009). Studying on the Point-Defect-Conductive Property of the Semiconducting Anodic Oxide Films on Titanium. Journal of The Electrochemical Society, 156(1), C39. doi:10.1149/1.3021008Roh, B., & Macdonald, D. D. (2007). Effect of oxygen vacancies in anodic titanium oxide films on the kinetics of the oxygen electrode reaction. Russian Journal of Electrochemistry, 43(2), 125-135. doi:10.1134/s1023193507020012Sazou, D., Saltidou, K., & Pagitsas, M. (2012). Understanding the effect of bromides on the stability of titanium oxide films based on a point defect model. Electrochimica Acta, 76, 48-61. doi:10.1016/j.electacta.2012.04.158Roberge P. R. , Handbook of Corrosion Engineering, p. 756, McGraw-Hill, New York (2000).Basame, S. B., & White, H. S. (1995). Scanning electrochemical microscopy of native titanium oxide films. Mapping the potential dependence of spatially-localized electrochemical reactions. The Journal of Physical Chemistry, 99(44), 16430-16435. doi:10.1021/j100044a034Basame, S. B., & White, H. S. (2000). Pitting Corrosion of Titanium The Relationship Between Pitting Potential and Competitive Anion Adsorption at the Oxide Film/Electrolyte Interface. Journal of The Electrochemical Society, 147(4), 1376. doi:10.1149/1.1393364Dugdale, I., & Cotton, J. B. (1964). The anodic polarization of titanium in halide solutions. Corrosion Science, 4(1-4), 397-411. doi:10.1016/0010-938x(64)90041-1Virtanen, S., & Curty, C. (2004). Metastable and Stable Pitting Corrosion of Titanium in Halide Solutions. CORROSION, 60(7), 643-649. doi:10.5006/1.3287839Trompette, J. L., Massot, L., Arurault, L., & Fontorbes, S. (2011). Influence of the anion specificity on the anodic polarization of titanium. Corrosion Science, 53(4), 1262-1268. doi:10.1016/j.corsci.2010.12.021Casillas, N. (1994). Pitting Corrosion of Titanium. Journal of The Electrochemical Society, 141(3), 636. doi:10.1149/1.2054783Beck, T. R. (1973). Pitting of Titanium. Journal of The Electrochemical Society, 120(10), 1310. doi:10.1149/1.2403253Huo, S., & Meng, X. (1990). The states of bromide on titanium surface prior to pit initiation. Corrosion Science, 31, 281-286. doi:10.1016/0010-938x(90)90120-tFernández-Domene, R. M., Blasco-Tamarit, E., García-García, D. M., & García-Antón, J. (2011). Cavitation corrosion and repassivation kinetics of titanium in a heavy brine LiBr solution evaluated by using electrochemical techniques and Confocal Laser Scanning Microscopy. Electrochimica Acta, 58, 264-275. doi:10.1016/j.electacta.2011.09.034Srikhirin, P., Aphornratana, S., & Chungpaibulpatana, S. (2001). A review of absorption refrigeration technologies. Renewable and Sustainable Energy Reviews, 5(4), 343-372. doi:10.1016/s1364-0321(01)00003-xLee R. J. DiGuilio R. M. Jeter S. M. Teja A. 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G. , Molecular Thermodynamics of Fluid-Phase Equilibria, p. 517, Prentice Hall, Upper Saddle River, NJ (1999).Blandamer, M. J., Engberts, J. B. F. N., Gleeson, P. T., & Reis, J. C. R. (2005). Activity of water in aqueous systems; A frequently neglected property. Chemical Society Reviews, 34(5), 440. doi:10.1039/b400473fSelcuk, H., Sene, J. J., Zanoni, M. V. B., Sarikaya, H. Z., & Anderson, M. A. (2004). Behavior of bromide in the photoelectrocatalytic process and bromine generation using nanoporous titanium dioxide thin-film electrodes. Chemosphere, 54(7), 969-974. doi:10.1016/j.chemosphere.2003.09.016Muñoz, A. I., Antón, J. G., Guiñón, J. L., & Herranz, V. P. (2003). Corrosion Behavior and Galvanic Coupling of Stainless Steels, Titanium, and Alloy 33 in Lithium Bromide Solutions. CORROSION, 59(7), 606-615. doi:10.5006/1.3277591Muñoz-Portero, M. J., García-Antón, J., Guiñón, J. L., & Leiva-García, R. (2011). Pourbaix diagrams for titanium in concentrated aqueous lithium bromide solutions at 25°C. Corrosion Science, 53(4), 1440-1450. doi:10.1016/j.corsci.2011.01.013Davydov, A. . (2001). Breakdown of valve metal passivity induced by aggressive anions. Electrochimica Acta, 46(24-25), 3777-3781. doi:10.1016/s0013-4686(01)00664-8Lin, L. F. (1981). A Point Defect Model for Anodic Passive Films. Journal of The Electrochemical Society, 128(6), 1194. doi:10.1149/1.2127592Haruna, T. (1997). Theoretical Prediction of the Scan Rate Dependencies of the Pitting Potential and the Probability Distribution in the Induction Time. Journal of The Electrochemical Society, 144(5), 1574. doi:10.1149/1.1837643Macdonald, D. D. (1992). The Point Defect Model for the Passive State. Journal of The Electrochemical Society, 139(12), 3434. doi:10.1149/1.2069096Macdonald, D. D. (1999). Passivity–the key to our metals-based civilization. Pure and Applied Chemistry, 71(6), 951-978. doi:10.1351/pac199971060951Macdonald, D. 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Impedance spectroscopy at semiconductor electrodes: Review and recent developments. Electrochimica Acta, 41(7-8), 967-973. doi:10.1016/0013-4686(95)00427-0Da Cunha Belo, M., Hakiki, N. ., & Ferreira, M. G. . (1999). Semiconducting properties of passive films formed on nickel–base alloys type Alloy 600: influence of the alloying elements. Electrochimica Acta, 44(14), 2473-2481. doi:10.1016/s0013-4686(98)00372-7Hakiki, N. B., Boudin, S., Rondot, B., & Da Cunha Belo, M. (1995). The electronic structure of passive films formed on stainless steels. Corrosion Science, 37(11), 1809-1822. doi:10.1016/0010-938x(95)00084-wHamadou, L., Kadri, A., & Benbrahim, N. (2005). Characterisation of passive films formed on low carbon steel in borate buffer solution (pH 9.2) by electrochemical impedance spectroscopy. Applied Surface Science, 252(5), 1510-1519. doi:10.1016/j.apsusc.2005.02.135Wijesinghe, T. L. S. L., & Blackwood, D. J. (2008). 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    Assessment of fissionable material behaviour in fission chambers

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    A comprehensive study is performed in order to assess the pertinence of fission chambers coated with different fissile materials for high neutron flux detection. Three neutron scenarios are proposed to study the fast component of a high neutron flux: (i) high neutron flux with a significant thermal contribution such as BR2, (ii) DEMO magnetic fusion reactor, and (iii) IFMIF high flux test module. In this study, the inventory code ACAB is used to analyze the following questions: (i) impact of different deposits in fission chambers; (ii) effect of the irradiation time/burn-up on the concentration; (iii) impact of activation cross-section uncertainties on the composition of the deposit for all the range of burn-up/irradiation neutron fluences of interest. The complete set of nuclear data (decay, fission yield, activation cross-sections, and uncertainties) provided in the EAF2007 data library are used for this evaluation
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