3,358 research outputs found
Towards a quantitative phase-field model of two-phase solidification
We construct a diffuse-interface model of two-phase solidification that
quantitatively reproduces the classic free boundary problem on solid-liquid
interfaces in the thin-interface limit. Convergence tests and comparisons with
boundary integral simulations of eutectic growth show good accuracy for
steady-state lamellae, but the results for limit cycles depend on the interface
thickness through the trijunction behavior. This raises the fundamental issue
of diffuse multiple-junction dynamics.Comment: 4 pages, 2 figures. Better final discussion. 1 reference adde
Phase-field model for Hele-Shaw flows with arbitrary viscosity contrast. II. Numerical study
We implement a phase-field simulation of the dynamics of two fluids with
arbitrary viscosity contrast in a rectangular Hele-Shaw cell. We demonstrate
the use of this technique in different situations including the linear regime,
the stationary Saffman-Taylor fingers and the multifinger competition dynamics,
for different viscosity contrasts. The method is quantitatively tested against
analytical predictions and other numerical results. A detailed analysis of
convergence to the sharp interface limit is performed for the linear dispersion
results. We show that the method may be a useful alternative to more
traditional methods.Comment: 13 pages in revtex, 5 PostScript figures. changes: 1 reference added,
figs. 4 and 5 rearrange
Phase-field model for Hele-Shaw flows with arbitrary viscosity contrast. I. Theoretical approach
We present a phase-field model for the dynamics of the interface between two
inmiscible fluids with arbitrary viscosity contrast in a rectangular Hele-Shaw
cell. With asymptotic matching techniques we check the model to yield the right
Hele-Shaw equations in the sharp-interface limit and compute the corrections to
these equations to first order in the interface thickness. We also compute the
effect of such corrections on the linear dispersion relation of the planar
interface. We discuss in detail the conditions on the interface thickness to
control the accuracy and convergence of the phase-field model to the limiting
Hele-Shaw dynamics. In particular, the convergence appears to be slower for
high viscosity contrasts.Comment: 17 pages in revtex. changes: 1 reference adde
Engineering DNA-grafted quatsomes as stable nucleic acid-responsive fluorescent nanovesicles
The development of artificial vesicles into responsive architectures capable of sensing the biological environment and simultaneously signaling the presence of a specific target molecule is a key challenge in a range of biomedical applications from drug delivery to diagnostic tools. Herein, the rational design of biomimetic DNA-grafted quatsome (QS) nanovesicles capable of translating the binding of a target molecule to amphiphilic DNA probes into an optical output is presented. QSs are synthetic lipid-based nanovesicles able to confine multiple organic dyes at the nanoscale, resulting in ultra-bright soft materials with attractiveness for sensing applications. Dye-loaded QS nanovesicles of different composition and surface charge are grafted with fluorescent amphiphilic nucleic acid-based probes to produce programmable FRET-active nanovesicles that operate as highly sensitive signal transducers. The photophysical properties of the DNA-grafted nanovesicles are characterized and the highly selective, ratiometric detection of clinically relevant microRNAs with sensitivity in the low nanomolar range are demonstrated. The potential applications of responsive QS nanovesicles for biosensing applications but also as functional nanodevices for targeted biomedical applications is envisaged
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Evaluating the structure and magnitude of the ash plume during the initial phase of the 2010 Eyjafjallajökull eruption using lidar observations and NAME simulations
The Eyjafjallajökull volcano in Iceland erupted explosively on 14 April 2010, emitting a plume of ash into the atmosphere. The ash was transported from Iceland toward Europe where mostly cloud-free skies allowed ground-based lidars at Chilbolton in England and Leipzig in Germany to estimate the mass concentration in the ash cloud as it passed overhead. The UK Met Office's Numerical Atmospheric-dispersion Modeling Environment (NAME) has been used to simulate the evolution of the ash cloud from the Eyjafjallajökull volcano during the initial phase of the ash emissions, 14–16 April 2010. NAME captures the timing and sloped structure of the ash layer observed over Leipzig, close to the central axis of the ash cloud. Relatively small errors in the ash cloud position, probably caused by the cumulative effect of errors in the driving meteorology en route, result in a timing error at distances far from the central axis of the ash cloud. Taking the timing error into account, NAME is able to capture the sloped ash layer over the UK. Comparison of the lidar observations and NAME simulations has allowed an estimation of the plume height time series to be made. It is necessary to include in the model input the large variations in plume height in order to accurately predict the ash cloud structure at long range. Quantitative comparison with the mass concentrations at Leipzig and Chilbolton suggest that around 3% of the total emitted mass is transported as far as these sites by small (<100 μm diameter) ash particles
In-beam internal conversion electron spectroscopy with the SPICE detector
The SPectrometer for Internal Conversion Electrons (SPICE) has been
commissioned for use in conjunction with the TIGRESS -ray spectrometer
at TRIUMF's ISAC-II facility. SPICE features a permanent rare-earth magnetic
lens to collect and direct internal conversion electrons emitted from nuclear
reactions to a thick, highly segmented, lithium-drifted silicon detector. This
arrangement, combined with TIGRESS, enables in-beam -ray and internal
conversion electron spectroscopy to be performed with stable and radioactive
ion beams. Technical aspects of the device, capabilities, and initial
performance are presented
Viscous fingering in liquid crystals: Anisotropy and morphological transitions
We show that a minimal model for viscous fingering with a nematic liquid
crystal in which anisotropy is considered to enter through two different
viscosities in two perpendicular directions can be mapped to a two-fold
anisotropy in the surface tension. We numerically integrate the dynamics of the
resulting problem with the phase-field approach to find and characterize a
transition between tip-splitting and side-branching as a function of both
anisotropy and dimensionless surface tension. This anisotropy dependence could
explain the experimentally observed (reentrant) transition as temperature and
applied pressure are varied. Our observations are also consistent with previous
experimental evidence in viscous fingering within an etched cell and
simulations of solidification.Comment: 12 pages, 3 figures. Submitted to PR
Kinematic reduction of reaction-diffusion fronts with multiplicative noise: Derivation of stochastic sharp-interface equations
We study the dynamics of generic reaction-diffusion fronts, including pulses
and chemical waves, in the presence of multiplicative noise. We discuss the
connection between the reaction-diffusion Langevin-like field equations and the
kinematic (eikonal) description in terms of a stochastic moving-boundary or
sharp-interface approximation. We find that the effective noise is additive and
we relate its strength to the noise parameters in the original field equations,
to first order in noise strength, but including a partial resummation to all
orders which captures the singular dependence on the microscopic cutoff
associated to the spatial correlation of the noise. This dependence is
essential for a quantitative and qualitative understanding of fluctuating
fronts, affecting both scaling properties and nonuniversal quantities. Our
results predict phenomena such as the shift of the transition point between the
pushed and pulled regimes of front propagation, in terms of the noise
parameters, and the corresponding transition to a non-KPZ universality class.
We assess the quantitative validity of the results in several examples
including equilibrium fluctuations, kinetic roughening, and the noise-induced
pushed-pulled transition, which is predicted and observed for the first time.
The analytical predictions are successfully tested against rigorous results and
show excellent agreement with numerical simulations of reaction-diffusion field
equations with multiplicative noise.Comment: 17 pages, 6 figure
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