559 research outputs found
Classical Aspects of Quantum Walls in One Dimension
We investigate the system of a particle moving on a half line x >= 0 under
the general walls at x = 0 that are permitted quantum mechanically. These
quantum walls, characterized by a parameter L, are shown to be realized as a
limit of regularized potentials. We then study the classical aspects of the
quantum walls, by seeking a classical counterpart which admits the same time
delay in scattering with the quantum wall, and also by examining the
WKB-exactness of the transition kernel based on the regularized potentials. It
is shown that no classical counterpart exists for walls with L < 0, and that
the WKB-exactness can hold only for L = 0 and L = infinity.Comment: TeX, 21 pages, 4 figures. v2: some parts of the text improved, new
and improved figure
Electronic States of Graphene Grain Boundaries
We introduce a model for amorphous grain boundaries in graphene, and find
that stable structures can exist along the boundary that are responsible for
local density of states enhancements both at zero and finite (~0.5 eV)
energies. Such zero energy peaks in particular were identified in STS
measurements [J. \v{C}ervenka, M. I. Katsnelson, and C. F. J. Flipse, Nature
Physics 5, 840 (2009)], but are not present in the simplest pentagon-heptagon
dislocation array model [O. V. Yazyev and S. G. Louie, Physical Review B 81,
195420 (2010)]. We consider the low energy continuum theory of arrays of
dislocations in graphene and show that it predicts localized zero energy
states. Since the continuum theory is based on an idealized lattice scale
physics it is a priori not literally applicable. However, we identify stable
dislocation cores, different from the pentagon-heptagon pairs, that do carry
zero energy states. These might be responsible for the enhanced magnetism seen
experimentally at graphite grain boundaries.Comment: 10 pages, 4 figures, submitted to Physical Review
Duality and Anholonomy in Quantum Mechanics of 1D Contact Interactions
We study systems with parity invariant contact interactions in one dimension.
The model analyzed is the simplest nontrivial one --- a quantum wire with a
point defect --- and yet is shown to exhibit exotic phenomena, such as strong
vs weak coupling duality and spiral anholonomy in the spectral flow. The
structure underlying these phenomena is SU(2), which arises as accidental
symmetry for a particular class of interactions.Comment: 4 pages ReVTeX with 4 epsf figures. KEK preprint 2000-3. Correction
in Eq.(14
Magnetic field tuning and quantum interference in a Cooper pair splitter
Cooper pair splitting (CPS) is a process in which the electrons of naturally
occurring spin-singlet pairs in a superconductor are spatially separated using
two quantum dots. Here we investigate the evolution of the conductance
correlations in an InAs CPS device in the presence of an external magnetic
field. In our experiments the gate dependence of the signal that depends on
both quantum dots continuously evolves from a slightly asymmetric Lorentzian to
a strongly asymmetric Fano-type resonance with increasing field. These
experiments can be understood in a simple three - site model, which shows that
the nonlocal CPS leads to symmetric line shapes, while the local transport
processes can exhibit an asymmetric shape due to quantum interference. These
findings demonstrate that the electrons from a Cooper pair splitter can
propagate coherently after their emission from the superconductor and how a
magnetic field can be used to optimize the performance of a CPS device. In
addition, the model calculations suggest that the estimate of the CPS
efficiency in the experiments is a lower bound for the actual efficiency.Comment: 5 pages + 4 pages supplementary informatio
Structural and functional characterisation of multi-copper oxidase CueO from lignin-degrading bacterium Ochrobactrum sp. reveal its activity towards lignin model compounds and lignosulfonate
The identification of enzymes responsible for oxidation of lignin in ligninâdegrading bacteria is of interest for biotechnological valorization of lignin to renewable chemical products. The genome sequences of two ligninâdegrading bacteria, Ochrobactrum sp., and Paenibacillus sp., contain no Bâtype DyP peroxidases implicated in lignin degradation in other bacteria, but contain putative multicopper oxidase genes. Multiâcopper oxidase CueO from Ochrobactrum sp. was expressed and reconstituted as a recombinant laccaseâlike enzyme, and kinetically characterized. Ochrobactrum CueO shows activity for oxidation of ÎČâaryl ether and biphenyl lignin dimer model compounds, generating oxidized dimeric products, and shows activity for oxidation of Caâlignosulfonate, generating vanillic acid as a low molecular weight product. The crystal structure of Ochrobactrum CueO (OcCueO) has been determined at 1.1 Ă
resolution (PDB: 6EVG), showing a fourâcoordinate mononuclear type I copper center with ligands His495, His434 and Cys490 with Met500 as an axial ligand, similar to that of Escherichia coli CueO and bacterial azurin proteins, whereas fungal laccase enzymes contain a threeâcoordinate type I copper metal center. A trinuclear type 2/3 copper cluster was modeled into the active site, showing similar structure to E. coli CueO and fungal laccases, and three solvent channels leading to the active site. Siteâdirected mutagenesis was carried out on amino acid residues found in the solvent channels, indicating the importance for residues Asp102, Gly103, Arg221, Arg223, and Asp462 for catalytic activity. The work identifies a new bacterial multicopper enzyme with activity for lignin oxidation, and implicates a role for bacterial laccaseâlike multicopper oxidases in some ligninâdegrading bacteria
Role of Microbes in the Development of Alzheimer\u27s Disease: State of the Art - An International Symposium Presented at the 2017 IAGG Congress in San Francisco.
This article reviews research results and ideas presented at a special symposium at the International Association of Gerontology and Geriatrics (IAGG) Congress held in July 2017 in San Francisco. Five researchers presented their results related to infection and Alzheimer\u27s disease (AD). Prof. Itzhaki presented her work on the role of viruses, specifically HSV-1, in the pathogenesis of AD. She maintains that although it is true that most people harbor HSV-1 infection, either latent or active, nonetheless aspects of herpes infection can play a role in the pathogenesis of AD, based on extensive experimental evidence from AD brains and infected cell cultures. Dr. Miklossy presented research on the high prevalence of bacterial infections that correlate with AD, specifically spirochete infections, which have been known for a century to be a significant cause of dementia (e.g., in syphilis). She demonstrated how spirochetes drive senile plaque formation, which are in fact biofilms. Prof. Balin then described the involvement of brain tissue infection by th
Inter-layer spin diffusion and electric conductivity in the organic conductors {\kappa}-ET2-Cl and {\kappa}-ET2-Br
A high frequency (111.2-420 GHz) electron spin resonance study of the
inter-layer (perpendicular) spin diffusion as a function of pressure and
temperature is presented in the conducting phases of the layered organic
compounds, {\kappa}-(BEDT-TTF)2-Cu[N(CN)2]X ({\kappa}-ET2-X), X=Cl or Br. The
resolved ESR lines of adjacent layers at high temperatures and high frequencies
allows for the determination of the inter-layer cross spin relaxation time, Tx
and the intrinsic spin relaxation time, T2 of single layers. In the bad metal
phase spin diffusion is two-dimensional, i.e. spins are not hopping to adjacent
layers within T2. Tx is proportional to the perpendicular resistivity at least
approximately, as predicted in models where spin and charge excitations are
tied together. In {\kappa}-ET2-Cl, at zero pressure Tx increases as the bad
metal-insulator transition is approached. On the other hand, Tx decreases as
the normal metal and superconducting phases are approached with increasing
pressure and/or decreasing temperature.Comment: 18 pages, 11 figure
Low temperature fullerene encapsulation in single wall carbon nanotubes: synthesis of N@C@SWCNT
High filling of single wall carbon nanotubes (SWCNT) with C and
C fullerenes in solvent is reported at temperatures as low as 69
C. A 2 hour long refluxing in n-hexane of the mixture of the fullerene
and SWCNT results in a high yield of C,C@SWCNT, fullerene peapod,
material. The peapod filling is characterized by TEM, Raman and electron energy
loss spectroscopy and X-ray scattering. We applied the method to synthesize the
temperature sensitive (N@C:C)@SWCNT as proved by electron spin
resonance spectroscopy. The solvent prepared peapod samples can be transformed
to double walled nanotubes enabling a high yield and industrially scalable
production of DWCNT
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