Color fixation strategies on sustainable poly-butylene succinate using biobased itaconic acid

Biopo-lybutylene succinate (bioPBS) is gaining attention in the biodegradable polymer market due to its promising properties, such as high biodegradability and processing versatility, representing a potential sustainable replacement for fossil-based commodities. However, there is still a need to enhance its properties for certain applications, with aesthetical and mechanical properties being a challenge. The aim of the present work is to improve these properties by adding selected additives that will confer bioPBS with comparable properties to that of current counterparts such as polypropylene (PP) for specific applications in the automotive and household appliances sectors. A total of thirteen materials have been studied and compared, being twelve biocomposites containing combinations of three different additives: a commercial red colorant, itaconic acid (IA) to enhance color fixation and zirconia (ZrO2) nanoparticles to maintain at least native PBS mechanical properties. The results show that the combination of IA and the coloring agent tends to slightly yellowish the blend due to the absorbance spectra of IA and also to modify the gloss due to the formation of IA nanocrystals that affects light scattering. In addition, for low amounts of IA (4 wt %), Young’s Modulus seems to be kept while elongation at break is even raised. Unexpectedly, a strong aging affect was found after four weeks. IA increases the hydrophilic behavior of the samples and thus seems to accelerate the hydrolization of the matrix, which is accompanied by an accused disaggregation of phases and an overall softening and rigidization effect. The addition of low amounts of ZrO2 (2 wt %) seems to provide the desired effect for hardening the surface while almost not affecting the other properties; however, higher amounts tends to form aggregates saturating the compounds. As a conclusion, IA might be a good candidate for color fixing in biobased polymers

Short range order of CCl4: RMC and MD methods

The main objective of this paper is to present a method to fully determine the six degrees of freedom regarding position and orientation of a neighboring molecule around a central one, i.e. the g(rCM,¿) distribution function. This is accomplished by completely determining the short range structure of liquid carbon tetrachloride, while employing results from two different methods, Molecular Dynamics (MD) [1] and Reverse Monte Carlo (RMC) [2]. Exclusively, the structural ordering of the first four molecules will be detailed.Postprint (published version

Elaboration of Essential Oil From the Oregano for Medicinal Use Sheet

The extraction and industrialization of the oregano oil in Ecuador can represent an important source of work, from the harvest to the transformation of the raw material into finished product. The oregano is a plant known from many years back and has always been used for medicinal purposes and is currently being used in many fields such as perfumery, gastronomy, toiletries; But its main use is in medicine. The work proposes a methodology that allows extracting the essential oil of the plant for different medical uses such as: anti - inflammatory, analgesic, antioxidant and antibiotic, being of social benefit representing an economic impact in its industrializatio

Detection of the Opening of the Bundle Crossing in KcsA with Fluorescence Lifetime Spectroscopy Reveals the Existence of Two Gates for Ion Conduction

The closed KcsA channel structure revealed a crossing of the cytosolic ends of the transmembrane helices blocking the permeation pathway. It is generally agreed that during channel opening this helical bundle crossing has to widen in order to enable access to the inner cavity. Here, we address the question of whether the opening of the inner gate is sufficient for ion conduction, or if a second gate, located elsewhere, may interrupt the ion flow. We used fluorescence lifetime measurements on KcsA channels labeled with tetramethylrhodamine at residues in the C-terminal end of TM2 to report on the opening of the lower pore region

¿Ayudan los libros de texto a comprender la realidad fluvial de la ciudad?

Se analiza el tratamiento de la idea de río y sus relaciones con la ciudad en los libros de texto de Educación Secundaria, con el fin de valorar su influencia en la comprensión de los fenómenos fluviales en entornos urbanos por los escolares. Se han revisado textos de ciencias naturales y ciencias sociales de uso frecuente en España y se han sometido a análisis de contenido mediante selección y tratamiento de unidades de información, siguiendo un sistema de categorías relacionadas con el concepto de río y su interacción con la ciudad. Se concluye que la relación ciudad-río tiene escasa presencia en los libros de texto, está marcada por el valor económico del agua, el río como amenaza y en el ahorro doméstico como único compromiso. Esta visión mercantilista, antropocéntrica y superficial no facilita el aprendizaje crítico de la realidad ni ayuda al cambio necesario en las relaciones de las ciudades con sus ríos. Palabras clave: ríos educativos, libros de texto, aprendizaje, geografía, educación ambiental, ciudad fluvial