Modelling of chemical shrinkage evolution with curing degree of a filled epoxy adhesive

An epoxy adhesive system, commonly used in wind turbine blade manufacturing, is experimentally investigated with respect to its chemical shrinkage behavior to show the shrinkage evolution within rotor blade production related process conditions. Therefore, a new test configuration is set up to record the resulting chemical shrinkage of the adhesive at cross-linking temperatures ranging from 20 C to 90 C. The respective conversion evolution is simulated under several temperature conditions through a curing kinetics model. This is generated with state of the art formulations, implementing test results from a differential scanning calorimeter (DSC). Moreover, the transformation of the curing degree to the corresponding glass transition temperature (Tg ) is performed through an experimentally based Di-Benedetto curve-fitting. By the combination of curing kinetics and chemical shrinkage test data, a model for the temperature and conversion dependant chemical shrinkage evolution during cure is developed. This is applied to a realistic curing cycle for adhesive materials in rotor blade production

Effects of higher dietary protein and fiber intakes at breakfast on postprandial glucose, insulin, and 24-H interstitial glucose in overweight adults

Dietary protein and fiber independently influence insulin-mediated glucose control. However, potential additive effects are not well-known. Men and women (n = 20; age: 26 ± 5 years; body mass index: 26.1 ± 0.2 kg/m²; mean ± standard deviation) consumed normal protein and fiber (NPNF; NP = 12.5 g, NF = 2 g), normal protein and high fiber (NPHF; NP = 12.5 g, HF = 8 g), high protein and normal fiber (HPNF; HP = 25 g, NF = 2 g), or high protein and fiber (HPHF; HP = 25 g, HF = 8 g) breakfast treatments during four 2-week interventions in a randomized crossover fashion. On the last day of each intervention, meal tolerance tests were completed to assess postprandial (every 60 min for 240 min) serum glucose and insulin concentrations. Continuous glucose monitoring was used to measure 24-h interstitial glucose during five days of the second week of each intervention. Repeated-measures ANOVA was applied for data analyses. The HPHF treatment did not affect postprandial glucose and insulin responses or 24-h glucose total area under the curve (AUC). Higher fiber intake reduced 240-min insulin AUC. Doubling the amount of protein from 12.5 g to 25 g/meal and quadrupling fiber from 2 to 8 g/meal at breakfast was not an effective strategy for modulating insulin-mediated glucose responses in these young, overweight adults.T32 HL116276 - NHLBI NIH HHS; UL1 TR001108 - NCATS NIH HH

Can digging make you happy? Archaeological excavations, happiness and heritage

Current government agendas for investigating the “Gross National Happiness” have spurred private and commercial organizations to consider whether their work has the potential to influence peoples' happiness and sense of well-being. The role of archaeological projects has yet to be considered, despite the body of research pertaining to their wider social values. Methods: By combining quantitative methodological well-being measures offered by positive and negative affect schedule and modified visual analogue scale (MVAS), this research evaluates if it is possible to identify the role archaeological projects play in enhancing well-being. Results: The analysis of the quantitative data is used to assess whether it is possible to quantitatively identify and link changes in cultural values to involvements in heritage projects. Conclusions: This paper sets out a methodological framework for analysing heritage well-being, providing guidelines for future evaluations of the cultural value of heritage

Reviews

The following publications have been reviewed by the mentioned authors;The Art of Print Making by Erich Rhein, reviewed by John LancasterDevelopments in Art Teaching by Terence Wooff, reviewed by John LancasterResources by Jack Bainbridge, reviewed by Michael SayerPower by Jack Bainbridge, reviewed by Michael SayerThe Potter's Complete Book of Clay and Glazes by James Chappell, reviewed by Michael PaffardWriting and Illuminating Lettering by Edward Johnston, reviewed by John LancasterBasic Mathematics for Technicians by C. W. Schofield, reviewed by F. R. WatsonDesign and Technology - Plastics by R. Millett, reviewed by Michael SayerObjective and Completion Tests in CSE Woodwork Theory by Ernest Clarke, reviewed by Denis TabernerObjectice and Completion Tests in CSE Metalwork Theory by Ernest Clarke, reviewed by Denis Taberne

The limits of process: On (re)reading Henri Bergson

This article offers a reading of the work of Henri Bergson as it pertains to organizations through the lens of ideas drawn from critical realism. It suggests an alternative to interpretations based on a stark division between process and realist perspectives. Much of the existing literature presents a rather partial view of Bergson’s work. A review suggests some interesting parallels with themes in critical realism, notably the emergence of mind. Critical realism has a focus on process at its heart, but is also concerned with how the products of such processes become stabilized and form the conditions for action. This suggests that attention might usefully be paid to the relationship between organizational action and the sedimented practices grouped under the heading of ‘routines’. More attention to Bergson’s account of the relationship between instinct, intuition and intelligence provides a link to the social character of thought, something which can be mapped on to Archer’s work on reflexivity and the ‘internal conversation’. This suggests that our analyses need to pay attention to both memory and history, to building and dwelling, rather than the one-sided focus found in some process theory accounts

Learning from local perceptions for strategic road development in Cambodia's protected forests

Road development in tropical forest landscapes is contentious. Local preferences are often subordinated to global economic and environmental concerns. Opportunities to seek solutions based on local context are rare. We examined local perspectives on road development within Cambodia's Keo Seima Wildlife Sanctuary to explore opportunities for optimizing conservation and development outcomes. We conducted household surveys to document the perceived benefits and risks of road development. We found that in the sanctuary, road rehabilitation may accelerate transitions to intensified agriculture and diversified, off-farm incomes. All households prefer good roads and poorer households prioritize road development over other village infrastructure. Households perceive the most prominent benefit of roads to be access to hospital. Local government authorities are responsible for controlling land use and conversion within village boundaries and are therefore highly influential in determining the social and environmental outcomes of roads. Strategies to mitigate environmental risks of roads without constraining development benefits must focus on improving local capacity for decision-making and transparency. Local institutions in tropical forest landscapes must have greater control over development benefits if they are to reinvest assets to achieve conservation success

Effects of dietary protein and fiber at breakfast on appetite, ad libitum energy intake at lunch, and neural responses to visual food stimuli in overweight adults

Increasing either protein or fiber at mealtimes has relatively modest effects on ingestive behavior. Whether protein and fiber have additive or interactive effects on ingestive behavior is not known. Fifteen overweight adults (5 female, 10 male; BMI: 27.1 ± 0.2 kg/m²; aged 26 ± 1 year) consumed four breakfast meals in a randomized crossover manner (normal protein (12 g) + normal fiber (2 g), normal protein (12 g) + high fiber (8 g), high protein (25 g) + normal fiber (2 g), high protein (25 g) + high fiber (8 g)). The amount of protein and fiber consumed at breakfast did not influence postprandial appetite or ad libitum energy intake at lunch. In the fasting-state, visual food stimuli elicited significant responses in the bilateral insula and amygdala and left orbitofrontal cortex. Contrary to our hypotheses, postprandial right insula responses were lower after consuming normal protein vs. high protein breakfasts. Postprandial responses in other a priori brain regions were not significantly influenced by protein or fiber intake at breakfast. In conclusion, these data do not support increasing dietary protein and fiber at breakfast as effective strategies for modulating neural reward processing and acute ingestive behavior in overweight adults.R01 MH102224 - NIMH NIH HHS; UL1 TR001108 - NCATS NIH HHS; UL1TR001108 - NCATS NIH HH

Cellulose nanocarriers via miniemulsion allow Pathogen-Specific agrochemical delivery

The current spraying of agrochemicals is unselective and ineffective, consuming a high amount of fungicides, which endangers the environment and human health. Cellulose-based nanocarriers (NCs) are a promising tool in sustainable agriculture and suitable vehicles for stimuli-responsive release of agrochemicals to target cellulase-segregating fungi, which cause severe plant diseases such as Apple Canker. Herein, cellulose was modified with undec-10-enoic acid to a hydrophobic and cross-linkable derivative, from which NCs were prepared via thiol-ene addition in miniemulsion. During the crosslinking reaction, the NCs were loaded in situ with hydrophobic fungicides, Captan and Pyraclostrobin. NCs with average sizes ranging from 200 to 300 nm and an agrochemical-load of 20 wt% were obtained. Cellulose-degrading fungi, e.g. Neonectria. ditissima which is responsible for Apple Canker, lead to the release of fungicides from the aqueous NC dispersions suppressing fungal growth. In contrast, the non-cellulase segregating fungi, e.g. Cylindrocladium buxicola, do not degrade the agrochemical-loaded NCs. This selective action against Apple Canker fungi, N. ditissima, proves the efficacy of NC-mediated drug delivery triggered by degradation in the exclusive presence of cellulolytic fungi. Cellulose NCs represent a sustainable alternative to the current unselective spraying of agrochemicals that treats many crop diseases ineffectively

Aeronet-based Microphysical and Optical Properties of Smoke-dominated Aerosol near Source Regions and Transported over Oceans, and Implications for Satellite Retrievals of Aerosol Optical Depth

Smoke aerosols from biomass burning are an important component of the global aerosol cycle. Analysis of Aerosol Robotic Network (AERONET) retrievals of size distribution and refractive index reveals variety between biomass burning aerosols in different global source regions, in terms of aerosol particle size and single scatter albedo (SSA). Case studies of smoke transported to coastal/island AERONET sites also mostly lie within the range of variability at near-source sites. Two broad families of aerosol properties are found, corresponding to sites dominated by boreal forest burning (larger, broader fine mode, with midvisible SSA 0.95), and those influenced by grass, shrub, or crop burning with additional forest contributions (smaller, narrower particles with SSA 0.88-0.9 in the midvisible). The strongest absorption is seen in southern African savanna at Mongu (Zambia), with average SSA 0.85 in the midvisible. These can serve as candidate sets of aerosol microphysicaloptical properties for use in satellite aerosol optical depth (AOD) retrieval algorithms. The models presently adopted by these algorithms over ocean are often insufficiently absorbing to represent these biomass burning aerosols. A corollary of this is an underestimate of AOD in smoke outflow regions, which has important consequences for applications of these satellite datasets