115 research outputs found
«Más allá de una teorÃa del impacto de la interacción interpersonal en la cooperación no verbal».
S Erie BERNE fait ici son derniér discours publique, une critique trés humonstique des eaeurs eL problémes tipiques do monde académique de la Psicothérapie. Ses eommentaires néamnoins touchent la profondeur de sa théorie des jeux et du scénario psichologiques, et sont évidemment aplicables á tous les terrains de l'activité humaine. Nous ramassons aussi quelques fragmenis de sa théorie del homeur. Erie Br.RNE pronuncia ji suo ultimo discurso publico, nel quale, con un grande senso del'Umore, crÃtica alcuni degÃl errori e delle mancanze pIÚ comuni nel mondo academico della Psicoterapia. 1 sui conunenti, nonostante, possono applicarsi anche a qualsiasi campo umano, dato ché hanno diretta relazione con le suc teorie del giocchi psicologici. Anche si presentano qualque fragmenti della sua Leona sul' umore. PALABRA CLAVE: Psicoterapia, perdedores, juego, ganadores, mundo academico
PAH emission in the proplyd HST10: what is the mechanism behind photoevaporation?
Proplyds are photodissociation region (PDR)-like cometary cocoons around
young stars which are thought to originate through photo-evaporation of the
central protoplanetary disk by external UV radiation from the nearby OB stars.
This letter presents spatially resolved mid-infrared imaging and spectroscopy
of the proplyd HST10 obtained with the VLT/VISIR instrument. These observations
allow us to detect Polycyclic Aromatic Hydrocarbons (PAH) emission in the
proplyd photodissociation region and to study the general properties of PAHs in
proplyds for the first time. We find that PAHs in HST10 are mostly neutral and
at least 50 times less abundant than typical values found for the diffuse ISM
or the nearby Orion Bar. With such a low PAH abundance, photoelectric heating
is significantly reduced. If this low abundance pertains also to the original
disk material, gas heating rates could be too low to efficiently drive
photoevaporation unless other processes can be identified. Alternatively, the
model behind the formation of proplyds as evaporating disks may have to be
revised.Comment: 5 pages, 3 figures, 1 tabl
Corrosion Behavior of α,β'-Brass in NaNO3 Solutions
The corrosion behavior of an α,β'-brass CuZn40Pb2 (CW617N) was studied in solutions with basic pHs and various nitrate ion concentrations. Corrosion at the open circuit potential was observed to proceed by the galvanic coupling of α and β' phases, leading to a surface dezincification of the β' phase and the evolution of the passive layer. When the alloy was polarized in the anodic domain, a pseudo-passive or a passive stage followed by a passive breakdown was observed
Development of Representative Tests to Quantify the Susceptibility to Stress Corrosion Cracking of , '-Brass Used for Gas Transfer Devices
Corrosion susceptibility of an α,β'-brass CuZn40Pb2 (CW617N), used for gas transfer devices, was investigated through accelerated corrosion tests at a constant anodic potential in NaNO3 solution with basic pHs. The anodic dissolution behavior of the α,β'-brass was characterized by a two stages-mechanism, with each stage including both dezincification and simultaneous dissolution phenomena of the β' phase but with different kinetics at each stage. Compressive or tensile stresses applied on brass specimens during the accelerated tests were observed largely to influence the anodic dissolution kinetics. Stresses were assumed to open or close the pores present in the dezincified β' phase, which promoted or slowed the dezincification mechanism, including with the Zn diffusion into the solution trapped inside of the pores
Dissolution Kinetics of α,β′-Brass in Basic NaNO3 Solutions
Corrosion tests at a constant anodic potential, referred to as dissolution tests, were performed to determine the dissolution kinetics of an α,β′-brass CuZn40Pb2 (CW617N) in a basic nitrate solution with and without mechanical loading. The corrosion behavior of the α,β′-brass was characterized by a two-step mechanism, with an initiation step for which the simultaneous dissolution of all the alloying elements of the β′ phase occurred only and a propagation step including at first, the afore-mentioned simultaneous dissolution process before a critical time tc and then, both simultaneous dissolution and dezincification of the β′ phase after tc. The pH and Cu concentration of the electrolyte near the brass surface were determined to be two of the major factors influencing the occurrence of the dezincification process. The dezincification of the β′ phase extended in depth by a percolation dissolution mechanism. Mechanical loading during the dissolution tests was observed to largely influence the dezincification process. It was assumed to open or close the pores present in the dezincified β′ phase, which promoted or slowed down the dezincification mechanism depending on the sign of the stress
The Electrochemical Behavior of α,β′-Brass in Basic NaNO3Solutions
The electrochemical behavior of an α,β'-brass CuZn40Pb2 (CW617N) was studied in basic nitrate solutions with various basic pHs and nitrate ion concentrations. In all the chosen experimental conditions, corrosion at the open circuit potential proceeded by the galvanic coupling of the α and β' phases, leading to a surface dezincification of the β' phase. The study showed that the extent of the dezincification was affected by the presence of lead in the alloy but the pH was the major parameter. During polarization tests, a pseudo-passive or a passive stage followed by a breakdown was observed: corrosion phenomena mainly involved copper and zinc dissolution from the β' phase. At pH 11, a Cu2O/PbO layer was efficient in achieving passivity of the brass. At pH 12, a Cu(OH)2-rich surface layer was formed: it was not protective enough, and complete dissolution of the β' phase was observed leading to the removal of lead particles
The Physics of the Colloidal Glass Transition
As one increases the concentration of a colloidal suspension, the system
exhibits a dramatic increase in viscosity. Structurally, the system resembles a
liquid, yet motions within the suspension are slow enough that it can be
considered essentially frozen. This kinetic arrest is the colloidal glass
transition. For several decades, colloids have served as a valuable model
system for understanding the glass transition in molecular systems. The spatial
and temporal scales involved allow these systems to be studied by a wide
variety of experimental techniques. The focus of this review is the current
state of understanding of the colloidal glass transition. A brief introduction
is given to important experimental techniques used to study the glass
transition in colloids. We describe features of colloidal systems near and in
glassy states, including tremendous increases in viscosity and relaxation
times, dynamical heterogeneity, and ageing, among others. We also compare and
contrast the glass transition in colloids to that in molecular liquids. Other
glassy systems are briefly discussed, as well as recently developed synthesis
techniques that will keep these systems rich with interesting physics for years
to come.Comment: 56 pages, 18 figures, Revie
Tracking Rotational Diffusion of Colloidal Clusters
We describe a novel method of tracking the rotational motion of clusters of
colloidal particles. Our method utilizes rigid body transfor- mations to
determine the rotations of a cluster and extends conventional proven particle
tracking techniques in a simple way, thus facilitating the study of rotational
dynamics in systems containing or composed of colloidal clusters. We test our
method by measuring dynamical properties of simulated Brownian clusters under
conditions relevant to microscopy experiments. We then use the technique to
track and describe the motions of a real colloidal cluster imaged with confocal
microscopy.Comment: 14 pages, 6 figures. Submitted to Optics Expres
Family Firms and Firm Performance: Evidence from Japan
Corrigendum: Nature Structural and Molecular Biology 16 (12), 1331 (2009) doi:10.1038/nsmb1209-1331bInternational audienceThioredoxins (Trxs) are oxidoreductase enzymes, present in all organisms, that catalyze the reduction of disulfide bonds in proteins. By applying a calibrated force to a substrate disulfide, the chemical mechanisms of Trx catalysis can be examined in detail at the single-molecule level. Here we use single-molecule force-clamp spectroscopy to explore the chemical evolution of Trx catalysis by probing the chemistry of eight different Trx enzymes. All Trxs show a characteristic Michaelis-Menten mechanism that is detected when the disulfide bond is stretched at low forces, but at high forces, two different chemical behaviors distinguish bacterial-origin from eukaryotic-origin Trxs. Eukaryotic-origin Trxs reduce disulfide bonds through a single-electron transfer reaction (SET), whereas bacterial-origin Trxs show both nucleophilic substitution (SN2) and SET reactions. A computational analysis of Trx structures identifies the evolution of the binding groove as an important factor controlling the chemistry of Trx catalysis
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