Bestimmung der antioxidativen Kapazität von Nacktgerste-Varietäten

In dieser Arbeit wurden 23 schwarz, blau und violett gefärbte Nacktgerste-Varietäten aus dem Jahr 2008 und weitere zwölf schwarz, gelb, blau und violett gefärbte Varietäten aus dem Jahr 2009 untersucht. Die Anthocyane wurden aus beiden Jahren im Vollmehl und aus 2009 in den Fraktionen Kleie, Futtermehl und Mehl ohne die gelben Varietäten bestimmt. Die Phenolsäuren, unterteilt in freie und gebundene, wurden nur in den Vollproben aller Farbgruppen aus 2009 bestimmt. Die Quantifizierung aller Extrakte erfolgte mittels HPLC und Spektroskopie. Zusätzlich wurde aus allen Phenolsäureextrakten die antioxidative Kraft mittels FRAP- und ABTS-Test ermittelt. Der Jahresvergleich der Genotypen zeigte bei den Anthocyanen unterschiedliche Gehaltsbereiche, wobei in beiden Jahren im Farbgruppenvergleich signifikant ähnliche Ergebnisse erkannt werden konnten. Der höchste Gehalt wurde in den violetten Varietäten nachgewiesen, gefolgt von den blauen und schwarzen Varietäten. Der Vergleich der Fraktionen aus 2009 war signifikant unterschiedlich (p < 0,05) hinsichtlich des Gesamtanthocyangehaltes, sowohl in der HPLC-Analyse als auch in der spektroskopischen Messung. Der höchste Gehalt wurde in der Kleie nachgewiesen, gefolgt von Futtermehl und Mehl. Delphinidin und Cyanidin-Glucosid stellten den Hauptanteil der Anthocyane dar. Der Gesamtgehalt der Phenolsäuren teilte sich auf in 91 bis 98 % gebundene Phenolsäuren und 2 bis 9 % freie Phenoläuren. Der Hauptanteil war bei den gebundenen Phenolsäuren die Ferulasäure und bei der freien Phenolsäuren die Kaffeesäure, gefolgt von o-Coumar- und Gallussäure. Im Farbgruppenvergleich zeigten die Phenol-säuren signifikante Unterschiede (p < 0,05), mit Ausnahme der freien Phenolsäuren in der spektroskopischen Messung. Der höchste Gehalt an gebundenen Phenolsäuren konnte in den violetten Varietäten gefunden werden und korrelierte mit der anitoxidativen Wirkung. Die freien Phenoläuren waren in den violetten und blauen Proben am höchsten enthalten und zeigten nur schwache Zusammenhänge mit der antioxidativen Wirkung.In the present thesis 23 black, blue and purple coloured naked barley varieties from 2008 and next 12 black, yellow, blue and purple coloured varieties from 2009 were examined. The anthocyanins were determined from both years in the wholemeal fraction. Additionally, samples from 2009 except the yellow ones were milled and sep-arated into bran, middlings and flour and all fractions were analysed for their anthocy-anin content. The content of phenolic acids, divided into free and bound ones, were determined only in the wholemeal of all colour groups from 2009. The quantification of all extracts was messured by means of HPLC and spectroscopy. In addition, the anti-oxidant potential was determined of all phenolic acid extracts by means of FRAP and ABTS test. The annual comparison of the genotypes showed different content areas of anthocyanins, but in the colour group comparison, significant similar results could be recognised in both years. The highest content was found in the purple group, followed by the blue and black types. The total anthocyanins differed significantly (p < 0,05) between the three fractions, where the highest content was found in the bran, fol-lowed by middlings and flour. Delphinidin and cyanidin-glucosid represented the main of the anthocyanins. The total phenolic acids were devided in 91 to 98% of bound phenolic acids and in 2 to 9% of free phenolic acids. The main constituent of the bound phenolic acids was ferulic acid and among the free phenolic acids caffeic acid, followed by o-coumaric and gallic acid. The phenolic acids showed in the colour group comparison significant differences (p < 0,05), except for the free phenolic acids in the spectroscopic measure-ment. The highest content in bound phenolic acids was found in the purple genotypes and correlated with the antioxidant effect. The free phenolic acids were highest in the purple and blue types and showed only weak connections to the antioxidant effect

Hubble Space Telescope High Resolution Imaging of Kepler Small and Cool Exoplanet Host Stars

High resolution imaging is an important tool for follow-up study of exoplanet candidates found via transit detection with the Kepler Mission. We discuss here HST imaging with the WFC3 of 23 stars that host particularly interesting Kepler planet candidates based on their small size and cool equilibrium temperature estimates. Results include detections, exclusion of background stars that could be a source of false positives for the transits, and detection of physically-associated companions in a number of cases providing dilution measures necessary for planet parameter refinement. For six KOIs, we find that there is ambiguity in which star hosts the transiting planet(s), with potentially strong implications for planetary characteristics. Our sample is evenly distributed in G, K, and M spectral types. Albeit with a small sample size, we find that physically-associated binaries are more common than expected at each spectral type, reaching a factor of 10 frequency excess at M. We document the program detection sensitivities, detections, and deliverables to the Kepler follow-up program archive.Comment: Accepted for the Astronomical Journal; 13 pages with 9 figure

First Resolved Scattered-light Images of Four Debris Disks in Scorpius-Centaurus with the Gemini Planet Imager

We present the first spatially resolved scattered-light images of four debris disks around members of the Scorpius-Centaurus (Sco-Cen) OB association with high-contrast imaging and polarimetry using the Gemini Planet Imager (GPI). All four disks are resolved for the first time in polarized light, and one disk is also detected in total intensity. The three disks imaged around HD 111161, HD 143675, and HD 145560 are symmetric in both morphology and brightness distribution. The three systems span a range of inclinations and radial extents. The disk imaged around HD 98363 shows indications of asymmetries in morphology and brightness distribution, with some structural similarities to the HD 106906 planet–disk system. Uniquely, HD 98363 has a wide comoving stellar companion, Wray 15-788, with a recently resolved disk with very different morphological properties. HD 98363 A/B is the first binary debris disk system with two spatially resolved disks. All four targets have been observed with ALMA, and their continuum fluxes range from one nondetection to one of the brightest disks in the region. With the new results, a total of 15 A/F stars in Sco-Cen have resolved scattered-light debris disks, and approximately half of these systems exhibit some form of asymmetry. Combining the GPI disk structure results with information from the literature on millimeter fluxes and imaged planets reveals a diversity of disk properties in this young population. Overall, the four newly resolved disks contribute to the census of disk structures measured around A/F stars at this important stage in the development of planetary systems

The JWST Early Release Science Program for Direct Observations of Exoplanetary Systems II: A 1 to 20 Micron Spectrum of the Planetary-Mass Companion VHS 1256-1257 b

We present the highest fidelity spectrum to date of a planetary-mass object. VHS 1256 b is a $<$20 M$_\mathrm{Jup}$ widely separated ($\sim$8\arcsec, a = 150 au), young, planetary-mass companion that shares photometric colors and spectroscopic features with the directly imaged exoplanets HR 8799 c, d, and e. As an L-to-T transition object, VHS 1256 b exists along the region of the color-magnitude diagram where substellar atmospheres transition from cloudy to clear. We observed VHS 1256~b with \textit{JWST}'s NIRSpec IFU and MIRI MRS modes for coverage from 1 $\mu$m to 20 $\mu$m at resolutions of $\sim$1,000 - 3,700. Water, methane, carbon monoxide, carbon dioxide, sodium, and potassium are observed in several portions of the \textit{JWST} spectrum based on comparisons from template brown dwarf spectra, molecular opacities, and atmospheric models. The spectral shape of VHS 1256 b is influenced by disequilibrium chemistry and clouds. We directly detect silicate clouds, the first such detection reported for a planetary-mass companion.Comment: Accepted ApJL Iterations of spectra reduced by the ERS team are hosted at this link: https://github.com/bemiles/JWST_VHS1256b_Reduction/tree/main/reduced_spectr

The JWST Early Release Science Program for Direct Observations of Exoplanetary Systems V: Do Self-Consistent Atmospheric Models Represent JWST Spectra? A Showcase With VHS 1256 b

The unprecedented medium-resolution (R~1500-3500) near- and mid-infrared (1-18um) spectrum provided by JWST for the young (140+/-20Myr) low-mass (12-20MJup) L-T transition (L7) companion VHS1256b gives access to a catalogue of molecular absorptions. In this study, we present a comprehensive analysis of this dataset utilizing a forward modelling approach, applying our Bayesian framework, ForMoSA. We explore five distinct atmospheric models to assess their performance in estimating key atmospheric parameters: Teff, log(g), [M/H], C/O, gamma, fsed, and R. Our findings reveal that each parameter's estimate is significantly influenced by factors such as the wavelength range considered and the model chosen for the fit. This is attributed to systematic errors in the models and their challenges in accurately replicating the complex atmospheric structure of VHS1256b, notably the complexity of its clouds and dust distribution. To propagate the impact of these systematic uncertainties on our atmospheric property estimates, we introduce innovative fitting methodologies based on independent fits performed on different spectral windows. We finally derived a Teff consistent with the spectral type of the target, considering its young age, which is confirmed by our estimate of log(g). Despite the exceptional data quality, attaining robust estimates for chemical abundances [M/H] and C/O, often employed as indicators of formation history, remains challenging. Nevertheless, the pioneering case of JWST's data for VHS1256b has paved the way for future acquisitions of substellar spectra that will be systematically analyzed to directly compare the properties of these objects and correct the systematics in the models.Comment: 32 pages, 16 figures, 6 tables, 2 appendice

The JWST Early Release Science Program for Direct Observations of Exoplanetary Systems IV: NIRISS Aperture Masking Interferometry Performance and Lessons Learned

We present a performance analysis for the aperture masking interferometry (AMI) mode on board the James Webb Space Telescope Near Infrared Imager and Slitless Spectrograph (JWST/NIRISS). Thanks to self-calibrating observables, AMI accesses inner working angles down to and even within the classical diffraction limit. The scientific potential of this mode has recently been demonstrated by the Early Release Science (ERS) 1386 program with a deep search for close-in companions in the HIP 65426 exoplanetary system. As part of ERS 1386, we use the same dataset to explore the random, static, and calibration errors of NIRISS AMI observables. We compare the observed noise properties and achievable contrast to theoretical predictions. We explore possible sources of calibration errors, and show that differences in charge migration between the observations of HIP 65426 and point-spread function calibration stars can account for the achieved contrast curves. Lastly, we use self-calibration tests to demonstrate that with adequate calibration, NIRISS AMI can reach contrast levels of $\sim9-10$ mag. These tests lead us to observation planning recommendations and strongly motivate future studies aimed at producing sophisticated calibration strategies taking these systematic effects into account. This will unlock the unprecedented capabilities of JWST/NIRISS AMI, with sensitivity to significantly colder, lower mass exoplanets than ground-based setups at orbital separations inaccessible to JWST coronagraphy.Comment: 20 pages, 12 figures, submitted to AAS Journal

The \textit{JWST} Early Release Science Program for Direct Observations of Exoplanetary Systems III: Aperture Masking Interferometric Observations of the star HIP\,65426 at 3.8 μm\boldsymbol{3.8\,\rm{\mu m}}

We present aperture masking interferometry (AMI) observations of the star HIP 65426 at $3.8\,\rm{\mu m}$ as a part of the \textit{JWST} Direct Imaging Early Release Science (ERS) program obtained using the Near Infrared Imager and Slitless Spectrograph (NIRISS) instrument. This mode provides access to very small inner working angles (even separations slightly below the Michelson limit of ${}0.5\lambda/D$ for an interferometer), which are inaccessible with the classical inner working angles of the \textit{JWST} coronagraphs. When combined with \textit{JWST}'s unprecedented infrared sensitivity, this mode has the potential to probe a new portion of parameter space across a wide array of astronomical observations. Using this mode, we are able to achieve a contrast of $\Delta m_{F380M}{\sim }7.8$\,mag relative to the host star at a separation of {\sim}0.07\arcsec but detect no additional companions interior to the known companion HIP\,65426\,b. Our observations thus rule out companions more massive than 10{-}12\,\rm{M\textsubscript{Jup}} at separations ${\sim}10{-}20\,\rm{au}$ from HIP\,65426, a region out of reach of ground or space-based coronagraphic imaging. These observations confirm that the AMI mode on \textit{JWST} is sensitive to planetary mass companions orbiting at the water frost line, even for more distant stars at $\sim$100\,pc. This result will allow the planning and successful execution of future observations to probe the inner regions of nearby stellar systems, opening essentially unexplored parameter space.Comment: 15 pages, 9 figures, submitted to ApJ Letter

The JWST Early Release Science Program for the Direct Imaging and Spectroscopy of Exoplanetary Systems

The direct characterization of exoplanetary systems with high-contrast imaging is among the highest priorities for the broader exoplanet community. As large space missions will be necessary for detecting and characterizing exo-Earth twins, developing the techniques and technology for direct imaging of exoplanets is a driving focus for the community. For the first time, JWST will directly observe extrasolar planets at mid-infrared wavelengths beyond 5 μm, deliver detailed spectroscopy revealing much more precise chemical abundances and atmospheric conditions, and provide sensitivity to analogs of our solar system ice-giant planets at wide orbital separations, an entirely new class of exoplanet. However, in order to maximize the scientific output over the lifetime of the mission, an exquisite understanding of the instrumental performance of JWST is needed as early in the mission as possible. In this paper, we describe our 55 hr Early Release Science Program that will utilize all four JWST instruments to extend the characterization of planetary-mass companions to ∼15 μm as well as image a circumstellar disk in the mid-infrared with unprecedented sensitivity. Our program will also assess the performance of the observatory in the key modes expected to be commonly used for exoplanet direct imaging and spectroscopy, optimize data calibration and processing, and generate representative data sets that will enable a broad user base to effectively plan for general observing programs in future Cycles

The JWST Early-release Science Program for Direct Observations of Exoplanetary Systems II: A 1 to 20 μ m Spectrum of the Planetary-mass Companion VHS 1256–1257 b

We present the highest fidelity spectrum to date of a planetary-mass object. VHS 1256 b is a MJup widely separated (∼8″, a = 150 au), young, planetary-mass companion that shares photometric colors and spectroscopic features with the directly imaged exoplanets HR 8799c, d, and e. As an L-to-T transition object, VHS 1256 b exists along the region of the color–magnitude diagram where substellar atmospheres transition from cloudy to clear. We observed VHS 1256 b with JWST's NIRSpec IFU and MIRI MRS modes for coverage from 1 to 20 μm at resolutions of ∼1000–3700. Water, methane, carbon monoxide, carbon dioxide, sodium, and potassium are observed in several portions of the JWST spectrum based on comparisons from template brown dwarf spectra, molecular opacities, and atmospheric models. The spectral shape of VHS 1256 b is influenced by disequilibrium chemistry and clouds. We directly detect silicate clouds, the first such detection reported for a planetary-mass companion