82 research outputs found

    Reply to Comments on Effect of heating rate on kinetic parameters of beta-irradiated Li2B4O7:Cu,Ag,P in TSL measurements

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    We appreciate the opportunity to respond to comments regarding the paper published by Ege et al (2007 Effect of heating rate on kinetic parameters of beta-irradiated Li2B4O7: Cu, Ag, P in TSL measurements Meas. Sci. Technol. 18 889). We would like to thank the authors for taking the time to tell us about their opinion, but unfortunately we do not agree with them completely. In the article presented by Kumar and Chourasiya some comment is advanced to the analysis of the glow curves measured with different heating rates, presented in our recent study. According to our study, the area under the glow curve decreases with increasing heating rate in TL-temperature plots due to the quenching effects. Contrary to this, Kumar and Chourasiya suggest that this decrease is due to the normalization process. Here we hope to clarify any confusion regarding our published study

    Enhancement of luminescence and thermal stability in Eu3+-doped K3Y (BO2)6 with Li+ and Na+ co-doping

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    Eu3+-doped and Li+/Na+ co-doped K3Y(BO2)6 (KYBO) phosphors were synthesized through a microwave- assisted sol-gel method, and their structural and photoluminescent (PL) characteristics were examined. X-ray diffraction (XRD) and Rietveld refinement confirm effective dopant incorporation and preservation of the crystalline structure. Fourier Transform Infrared (FTIR) spectroscopy indicates the maintenance of the borate structure, confirming the structural integrity of the phosphors upon doping. The addition of Li+ and Na+ co-dopants notably enhances luminescent efficiency and thermal stability, making these phosphors promising candidates for solid-state lighting (SSL) applications. PL analysis reveals strong red emission peaks at 612 nm, attributed to the 5 D o ? 7 F 2 transition of Eu3+ ions. The study indicates that electric dipole-quadrupole interactions are the primary mechanism for energy migration, with a critical distance of approximately 22.68 & Aring;. This mechanism contributes to concentration quenching at higher doping levels. High temperature PL measurements indicated an activation energy of 0.1389 eV for thermal quenching in the Li+ co-doped sample. Additionally, the Na+ co-doped sample exhibited an abnormal thermal stability behavior, with an even higher activation energy of 0.2536 eV. This suggests that Na+ co-doping significantly enhances the thermal resilience of the phosphor, making it more suitable for high-power light-emitting applications that operate under extreme conditions. CIE chromaticity diagrams highlight the potential for optimizing Eu3+ doping levels, combined with Li+ and Na+ co-doping, to improve luminescent performance and thermal stability for advanced SSL applications. (c) 2024 The Society of Powder Technology Japan. Published by Elsevier BV and The Society of Powder Technology Japan. All rights are reserved, including those for text and data mining, AI training, and similar technologies.Princess Nourah bint Abdulrahman University, Riyadh, Saudi Arabia [PNURSP2024R16]; Turkish Scientific Research Council [223M036, TUBITAK-1001]; Scientific and Technological Research Council of Turkey (TUBITAK) [2221]We express our gratitude to the Princess Nourah bint Abdulrahman University Researchers Supporting Project number (PNURSP2024R16) , Princess Nourah bint Abdulrahman University, Riyadh, Saudi Arabia. This study was supported by the Turkish Scientific Research Council with the project numbered 223M036 within the scope of theTUBITAK-1001 project. The authors also extend their sincere gratitude for the support rendered to this study by the Scientific and Technological Research Council of Turkey (TUBITAK) through the 2221-Fellowships for Visiting Scientists and Scientists on Sabbatical Leave Programme

    Data sharing reveals complexity in the westward spread of domestic animals across Neolithic Turkey

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    This study presents the results of a major data integration project bringing together primary archaeozoological data for over 200,000 faunal specimens excavated from seventeen sites in Turkey spanning the Epipaleolithic through Chalcolithic periods, c. 18,000-4,000 cal BC, in order to document the initial westward spread of domestic livestock across Neolithic central and western Turkey. From these shared datasets we demonstrate that the westward expansion of Neolithic subsistence technologies combined multiple routes and pulses but did not involve a set 'package' comprising all four livestock species including sheep, goat, cattle and pig. Instead, Neolithic animal economies in the study regions are shown to be more diverse than deduced previously using quantitatively more limited datasets. Moreover, during the transition to agro-pastoral economies interactions between domestic stock and local wild fauna continued. Through publication of datasets with Open Context (opencontext.org), this project emphasizes the benefits of data sharing and web-based dissemination of large primary data sets for exploring major questions in archaeology (Alternative Language Abstract S1)

    Efforts towards setting eutrophication assessment criteria for coastal marine ecosystems

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    Eutrophication of coastal marine environments is a widespread and transboundary problem necessitating consideration of measures to conserve and restore the marine environments that have been adversely affected. As of now, there exist no criteria set for eutrophication of coastal marine waters due to the difficulty to establish single national/international assessment criteria for eutrophication applicable to all coastal waters with different geographic and climatic conditions. However, there appear to be a number of joint and integrated studies among coastal countries to harmonise the outcomes of their scientific research and monitoring activities that might change the natural attributes of the environment. The common findings may then be utilised to develop guidelines on establishing eutrophication criteria together with application of policies and strategies. This Study attempts to review the recent efforts of certain groups gathered together and of some countries to develop and improve approaches for assessment of eutrophication in coastal marine waters. Studies of OSPAR Commission, USEPA, and Australia and New Zealand related councils will also be referred
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