108 research outputs found
Characterization of surface layers in Zn-diffused LiNbO3 waveguides by heavy ion elastic recoil detection
Copyright (2002) American Institute of Physics. This article may be downloaded for personal use only. Any other use requires prior permission of the author and the American Institute of Physics. The following article appeared in Applied Physics Letters 81.11 (2002): 1981-1983 and may be found at http://apl.aip.org
Influence of primary particle density in the morphology of agglomerates
Agglomeration processes occur in many different realms of science such as
colloid and aerosol formation or formation of bacterial colonies. We study the
influence of primary particle density in agglomerate structure using
diffusion-controlled Monte Carlo simulations with realistic space scales
through different regimes (DLA and DLCA). The equivalence of Monte Carlo time
steps to real time scales is given by Hirsch's hydrodynamical theory of
Brownian motion. Agglomerate behavior at different time stages of the
simulations suggests that three indices (fractal exponent, coordination number
and eccentricity index) characterize agglomerate geometry. Using these indices,
we have found that the initial density of primary particles greatly influences
the final structure of the agglomerate as observed in recent experimental
works.Comment: 11 pages, 13 figures, PRE, to appea
Size effects in the magnetic behaviour of TbAl_2 milled alloys
The study of the magnetic properties depending upon mechanical milling of the
ferromagnetic polycrystalline TbAl_2 material is reported. The Rietveld
analysis of the X-ray diffraction data reveals a decrease of the grain size
down to 14 nm and -0.15 % of variation of the lattice parameter, after 300
hours of milling time. Irreversibility in the zero field cooled - field cooled
(ZFC-FC) DC-susceptibility and clear peaks in the AC susceptibility between 5
and 300 K show that the long-range ferromagnetic structure is inhibited in
favour of a disordered spin arrangement below 45 K. This glassy behaviour is
also deduced from the variation of the irreversibility transition with the
field (H^{2/3}) and frequency. The magnetization process of the bulk TbAl_2 is
governed by domain wall thermal activation processes. By contrast, in the
milled samples, cluster-glass properties arise as a result of cooperative
interactions due to the substitutional disorder. The interactions are also
influenced by the nanograin structure of the milled alloys, showing a variation
of coercivity with the grain size, below the crossover between the multi- and
single-domain behaviours.Comment: 23 pages, 11 figures, to appear in J. Phys.: Condens. Ma
The pH-responsive PacC transcription factor of Aspergillus fumigatus governs epithelial entry and tissue invasion during pulmonary aspergillosis
Data Availability: The authors confirm that all data underlying the findings are fully available without restriction. Raw data have been deposited in the Gene Expression Omnibus (GEO) (http://www.ncbi.nlm.nih.gov/geo/) under accession number GSE54810. Funding: This work was supported in part by grants to EMB from the MRC (G0501164) and BBSRC (BB/G009619/1), to EMB and NDR from the Wellcome Trust (WT093596MA), to MB from Imperial College London (Division of Investigative Sciences PhD Studentship), to HH from the ERA-NET PathoGenoMics project TRANSPAT, Austrian Science Foundation (FWF I282-B09), to SGF from the National Institutes of Health, USA (R01AI073829). The funders had no role in study design, data collection and analysis, decision to publish, or preparation of the manuscript.Peer reviewedPublisher PD
Oral administration of mebendazole failed to reduce nematode egg shedding in captive African gazelles
Idiosyncrasies are observed in captive wild animals as regards the
pharmacokinetics and efficacy of anthelmintics. This could be attributed
to such factors as differences in host’s metabolism, irregular
distribution of anthelmintics due to the way they are administered and
worm resistance to anthelmintics. Previously mebendazole was found to be
poorly effective when administered in feed. An experiment was conducted
to evaluate the efficacy of mebendazole when administered at the dosage
rate of 15-20 mg/kg body weight to gastrointestinal nematodes in captive
gazelles. Fifty-eight adult gazelles ( Gazella cuvieri) were divided into four
groups: T1 (animals dosed orally, directly into the mouth), T2 (treated
orally, mixed in the water of a herd), T3 (treated orally, mixed in the
water of one animal) and T4 (not treated). Individual faecal samples were
taken before treatment, and 15 days thereafter. Mean percentages of
reduction of egg shedding were calculated for Nematodirus spp., other
trichostrongyles, total trichostrongylids, Trichuris spp. and total
nematodes. No statistically significant differences were detected
between the treatment groups and the control group or among the animals
in the three treatment groups.The articles have been scanned in colour with a HP Scanjet 5590; 600dpi.
Adobe Acrobat v.9 was used to OCR the text and also for the merging and conversion to the final presentation PDF-format.mn201
Substitutional effects of in by Cu in CeIn2
We have investigated the evolution of the magnetic properties on the Ce(In1'xCux)2 (0 < x ≤ 0.3) series of alloys. The orthorhombic structure of the CeIn2 alloy (Imma) changes into the hexagonal AlB2-type (P6/mmm) for x = 0.05 and, then, into the hexagonal CaIn2-type (P63/mmm) for higher Cu concentrations, up to x = 0.3. The dc (ac) magnetic susceptibility shows an abrupt decrease of the magnetic transition temperature from 22 K to 5.4 K (x = 0.05). The results indicate the influence of the crystallographic type of structure and disorder effects on the magnetic behavior along the series. © Owned by the authors, published by EDP Sciences, 2014
Size-induced superantiferromagnetism with reentrant spin-glass behavior in metallic nanoparticles of TbCu2
An unusual 4f -superantiferromagnetic state characterized by simultaneous antiferromagnetic and spin-glass behaviors induced by particle-size reduction is revealed in metallic nanoparticles (≈ 9 nm) of TbCu 2 . The Néel temperature is 46 K and the glassy freezing is below ≈ 9 K and governed by a critical slowing down process. Neutron diffraction at 1.8 K establishes the superantiferromagnetism. The latter is settled by the nanoparticle moments and the freezing mechanism is provided by the surface spins
Reduction of the Yb valence in YbAl3 nanoparticles
Measurements of specific heat, dc magnetic susceptibility, and Yb LII and LIII x-ray absorption near-edge
structure XANES and extended x-ray absorption fine structure EXAFS on YbAl3 milled alloys are reported.
X-ray diffraction patterns are consistent with a reduction in particle size down to 10 nm and an increase in the
lattice strain up to 0.4% for 120 h of milling time. A decrease in the mean valence from 2.86 for the unmilled
alloy to 2.70 for 120 h milled YbAl3 is obtained from the analysis of XANES spectra. From the analysis of
spectra in the EXAFS region, an increase in the mean-square disorder of neighbor distance with milling time
is detected in good agreement with the results of x-ray diffraction. Size effects strongly influence the magnetic
and thermal properties. The value for the maximum of the magnetic susceptibility decreases around 30% for
120 h milled alloy and an excess specific heat, with a peak around 40 K in the milled samples, is derived.
These changes in the physical properties along the milled YbAl3 alloys are associated with the reduction in
particle size. Such a reduction leads to the existence of a large number of Yb2+ atoms at the surface with
respect to the bulk affecting the overall electronic state
Use of a neuroleptic in assisted reproduction of the critically endangered Mohor gazelle (Gazella dama mhorr)
Abstract Stress is a limiting factor in assisted reproduction in wild animals maintained in captivity and measures to reduce it should improve reproductive success. The effect of the long-acting neuroleptic (LAN) perphenazine enanthate was assessed on ovarian stimulation for the recovery of immature oocytes from Mohor gazelle (Gazella dama mhorr) and their subsequent in vitro maturation, fertilization and embryo culture. The viability of embryos after transfer was also examined. Perphenazine enanthate decreased activity levels and facilitated handling of treated animals when compared to controls. LAN-treated animals showed a more regular pattern of respiratory and heart rates and body temperature than controls; no major differences were found in hematological and biochemical parameters between groups. Perphenazine-treated females had lower plasma cortisol levels during the days of intense handling. No significant differences were found in the number of punctured follicles and recovered oocytes between groups. The percentage of mature oocytes per female was significantly higher in the LAN-group. Fertilization and cleavage rates were not significantly different between groups. Embryos developed in culture but none reached the blastocyst stage, and those transferred to the oviduct of synchronized recipients did not develop to term. In conclusion, treatment of females with perphenazine enanthate during ovarian stimulation did not have negative effects on maturation, fertilization and embryo development in vitro. Moreover, an increase in oocyte maturation rate per female was observed. Thus, the use of LANs could be useful to alleviate the effects of handling-stress during assisted reproductive procedures in wild ungulates.
Avaliação das características de transporte em membranas de poliamida 66 preparadas com diferentes solventes
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