EMPRESS : A European project to enhance process control through improved temperature measurement

A new European project called EMPRESS, funded by the EURAMET program ‘European Metrology Program for Innovation and Research,’ is described. The 3 year project, which started in the summer of 2015, is intended to substantially augment the efficiency of high-value manufacturing processes by improving temperature measurement techniques at the point of use. The project consortium has 18 partners and 5 external collaborators, from the metrology sector, high-value manufacturing, sensor manufacturing, and academia. Accurate control of temperature is key to ensuring process efficiency and product consistency and is often not achieved to the level required for modern processes. Enhanced efficiency of processes may take several forms including reduced product rejection/waste; improved energy efficiency; increased intervals between sensor recalibration/maintenance; and increased sensor reliability, i.e., reduced amount of operator intervention. Traceability of temperature measurements to the International Temperature Scale of 1990 (ITS-90) is a critical factor in establishing low measurement uncertainty and reproducible, consistent process control. Introducing such traceability in situ (i.e., within the industrial process) is a theme running through this project

Direct extreme UV-lithographic conversion of metal xanthates into nanostructured metal sulfide layers for hybrid photovoltaics

We present a versatile strategy toward the preparation of nanostructured metal sulfide layers, which exploits the photosensitivity of metal xanthates as a powerful tool for lithographic structuring. Using extreme ultraviolet interference lithography (EUV-IL), we successfully realized well-defined column and comb nanostructures. This approach provides new pathways to fabricate highly ordered structured metal sulfide layers with periodicities far below 100 nm for potential application in hybrid solar cells. © 2013 The Royal Society of Chemistry

Two-vibron bound states in alpha-helix proteins : the interplay between the intramolecular anharmonicity and the strong vibron-phonon coupling

The influence of the intramolecular anharmonicity and the strong vibron-phonon coupling on the two-vibron dynamics in an $\alpha$-helix protein is studied within a modified Davydov model. The intramolecular anharmonicity of each amide-I vibration is considered and the vibron dynamics is described according to the small polaron approach. A unitary transformation is performed to remove the intramolecular anharmonicity and a modified Lang-Firsov transformation is applied to renormalize the vibron-phonon interaction. Then, a mean field procedure is realized to obtain the dressed anharmonic vibron Hamiltonian. It is shown that the anharmonicity modifies the vibron-phonon interaction which results in an enhancement of the dressing effect. In addition, both the anharmonicity and the dressing favor the occurrence of two different bound states which the properties strongly depend on the interplay between the anharmonicity and the dressing. Such a dependence was summarized in a phase diagram which characterizes the number and the nature of the bound states as a function of the relevant parameters of the problem. For a significant anharmonicity, the low frequency bound states describe two vibrons trapped onto the same amide-I vibration whereas the high frequency bound states refer to the trapping of the two vibrons onto nearest neighbor amide-I vibrations.Comment: may 2003 submitted to Phys. Rev.

Re-energisation of AGN head-tail radio galaxies in the galaxy cluster ZwCl0634.1+47474

Low-frequency radio observations show an increasing number of radio galaxies located in galaxy clusters that display peculiar morphologies and spectral profiles. This is the result of the dynamical interaction of the galaxy with the surrounding medium. Studying this phenomenon is key to understanding the evolution of low-energy relativistic particles in the intracluster medium. We present a multi-frequency study of the three head-tail (HT) radio galaxies and the radio halo in the galaxy cluster ZwCl0634.1+4747. We make use of observations at four frequencies performed with LOFAR LBA (53 MHz), HBA (144 MHz), GMRT (323 MHz) and VLA (1518 MHz) data. The use of extremely low radio frequency observations, such as LOFAR at 53 and 144 MHz, allowed us to detect the extension of the tails up to a distance of ~ 1 Mpc. We extracted spectral profiles along the tails in order to identify possible departures from a pure ageing model, such as the Jaffe-Perola (JP) model, which only involves synchrotron and inverse-Compton losses. We found clear evidence of departures from this simple ageing model, such as surface brightness enhancement and spectral flattening along all of the tails. This can be interpreted as the consequence of particle re-acceleration along the tails. Possible explanations for this behaviour include the interaction between a shock and the radio tails or a turbulence-driven re-acceleration mechanism. We show that the latter scenario is able to reproduce the characteristic features that we observed in our profiles

Particle re-acceleration and diffuse radio sources in the galaxy cluster Abell 1550

Context. Radio observations of galaxy clusters reveal a plethora of diffuse, steep-spectrum sources related to the re-acceleration of cosmic-ray electrons, such as halos, relics, and phoenices. In this context, the LOw Frequency ARray Low-Band Antenna (LOFAR-LBA) Sky Survey (LoLSS) provides the most sensitive images of the sky at 54 MHz to date, allowing us to investigate re-acceleration processes in a poorly explored frequency regime. Aims. We study diffuse radio emission in the galaxy cluster Abell 1550, with the aim of constraining particle re-acceleration in the intra-cluster medium. Methods. We exploited observations at four different radio frequencies: 54, 144, 400, and 1400 MHz. To complement our analysis, we made use of archival Chandra X-ray data. Results. At all frequencies we detect an ultra-steep spectrum radio halo (Sν ν1.6) with an extent of 1.2 Mpc at 54 MHz. Its morphology follows the distribution of the thermal intra-cluster medium inferred from the Chandra observation. West of the centrally located head-tail radio galaxy, we detect a radio relic with a projected extent of 500 kpc. From the relic, a 600 kpc long bridge departs and connects with the halo. Between the relic and the radio galaxy, we observe what is most likely a radio phoenix, given its curved spectrum. The phoenix is connected to the tail of the radio galaxy through two arms, which show a nearly constant spectral index for 300 kpc. Conclusions. The halo could be produced by turbulence induced by a major merger, with the merger axis lying in the NE-SW direction. This is supported by the position of the relic, whose origin could be attributed to a shock propagating along the merger axis. It is possible that the same shock has also produced the phoenix through adiabatic compression, while we propose that the bridge could be generated by electrons which were pre-accelerated by the shock, and then re-accelerated by turbulence. Finally, we detect hints of gentle re-energisation in the two arms that depart from the tail of the radio galaxy

Particle re-acceleration and diffuse radio sources in the galaxy cluster Abell 1550

We study diffuse radio emission in the galaxy cluster A1550, with the aim of constraining particle re-acceleration in the intra-cluster medium. We exploit observations at four different frequencies: 54, 144, 400 and 1400 MHz. To complement our analysis, we make use of archival Chandra X-ray data. At all frequencies we detect an ultra-steep spectrum radio halo ($S_\nu \propto \nu^{-1.6}$) with an extent of 1.2 Mpc at 54 MHz. Its morphology follows the distribution of the thermal intra-cluster medium inferred from the Chandra observation. West of the centrally located head-tail radio galaxy, we detect a radio relic with projected extent of 500 kpc. From the relic, a 600 kpc long bridge departs and connect it to the halo. Between the relic and the radio galaxy, we observe what is most likely a radio phoenix, given its curved spectrum. The phoenix is connected to the tail of the radio galaxy through two arms, which show a nearly constant spectral index for 300 kpc. The halo could be produced by turbulence induced by a major merger, with its axis lying in the NE-SW direction. This is supported by the position of the relic, whose origin could be attributed to a shock propagating along the merger axis. It is possible that the same shock has also produced the phoenix through adiabatic compression, while the bridge could be generated by electrons which were pre-accelerated by the shock, and then re-accelerated by turbulence. Finally, we detect hints of gentle re-energisation in the two arms which depart from the tail of the radio galaxy.Comment: 16 pages, 10 figure

Submesoscale physicochemical dynamics directly shape bacterioplankton community structure in space and time

Submesoscale eddies and fronts are important components of oceanic mixing and energy fluxes. These phenomena occur in the surface ocean for a period of several days, on scales between a few hundred meters and few tens of kilometers. Remote sensing and modeling suggest that eddies and fronts may influence marine ecosystem dynamics, but their limited temporal and spatial scales make them challenging for observation and in situ sampling. Here, the study of a submesoscale filament in summerly Arctic waters (depth 0–400 m) revealed enhanced mixing of Polar and Atlantic water masses, resulting in a ca. 4 km wide and ca. 50 km long filament with distinct physical and biogeochemical characteristics. Compared to the surrounding waters, the filament was characterized by a distinct phytoplankton bloom, associated with depleted inorganic nutrients, elevated chlorophyll a concentrations, as well as twofold higher phyto- and bacterioplankton cell abundances. High-throughput 16S rRNA gene sequencing of bacterioplankton communities revealed enrichment of typical phytoplankton bloom-associated taxonomic groups (e.g., Flavobacteriales) inside the filament. Furthermore, linked to the strong water subduction, the vertical export of organic matter to 400 m depth inside the filament was twofold higher compared to the surrounding waters. Altogether, our results show that physical submesoscale mixing can shape distinct biogeochemical conditions and microbial communities within a few kilometers of the ocean. Hence, the role of submesoscale features in polar waters for surface ocean biodiversity and biogeochemical processes need further investigation, especially with regard to the fate of sea ice in the warming Arctic Ocean

Versatile thiol-based reactions for micrometer- and nanometer-scale photopatterning of polymers and biomolecules

Thiol-based chemistry provides a mild and versatile tool for surface functionalization. In the present work, mercaptosilane films were patterned by utilizing UV-induced photo-oxidation of the thiol to yield sulfonate groups via contact and interferometric lithography (IL). These photo-generated sulfonic acid groups were used for selective immobilization of amino-functionalized molecules after activation with triphenylphosphine ditriflate (TPPDF). Moreover, protein-resistant poly(oligoethyleneglycolmethacrylate) (POEGMA) brushes were grown from the intact thiol groups by a surface-induced polymerization reaction. Exploiting both reactions it is possible to couple amino-labelled nitrilotriacetic acid (NH2-NTA) to sulfonate-functionalized regions, enabling the site-specific binding of green fluorescent protein (GFP) to regions defined lithographically, while exploiting the protein-resistant character of POEGMA brushes to prevent non-specific protein adsorption to previously masked areas. The outstanding reactivity of thiol groups paves the way towards novel strategies for the fabrication of complex protein nanopatterns beyond thiol–ene chemistry