264 research outputs found
A transient network of telechelic polymers and microspheres : structure and rheology
We study the structure and dynamics of a transient network composed of
droplets of microemulsion connected by telechelic polymers. The polymer induces
a bridging attraction between droplets without changing their shape. A
viscoelastic behaviour is induced in the initially liquid solution,
characterised in the linear regime by a stretched exponential stress
relaxation. We analyse this relaxation in the light of classical theories of
transient networks. The role of the elastic reorganisations in the deformed
network is emphasized. In the non linear regime, a fast relaxation dynamics is
followed by a second one having the same rate as in the linear regime. This
behaviour, under step strain experiments, should induce a non monotonic
behaviour in the elastic component of the stress under constant shear rate.
However, we obtain in this case a singularity in the flow curve very different
from the one observed in other systems, that we interpret in terms of fracture
behaviour.Comment: 9 pages, 4 figure
OGLE-2005-BLG-018: Characterization of Full Physical and Orbital Parameters of a Gravitational Binary Lens
We present the analysis result of a gravitational binary-lensing event
OGLE-2005-BLG-018. The light curve of the event is characterized by 2 adjacent
strong features and a single weak feature separated from the strong features.
The light curve exhibits noticeable deviations from the best-fit model based on
standard binary parameters. To explain the deviation, we test models including
various higher-order effects of the motions of the observer, source, and lens.
From this, we find that it is necessary to account for the orbital motion of
the lens in describing the light curve. From modeling of the light curve
considering the parallax effect and Keplerian orbital motion, we are able to
measure not only the physical parameters but also a complete orbital solution
of the lens system. It is found that the event was produced by a binary lens
located in the Galactic bulge with a distance kpc from the Earth.
The individual lens components with masses and are separated with a semi-major axis of AU and
orbiting each other with a period yr. The event demonstrates
that it is possible to extract detailed information about binary lens systems
from well-resolved lensing light curves.Comment: 19 pages, 6 figure
Impact Factor: outdated artefact or stepping-stone to journal certification?
A review of Garfield's journal impact factor and its specific implementation
as the Thomson Reuters Impact Factor reveals several weaknesses in this
commonly-used indicator of journal standing. Key limitations include the
mismatch between citing and cited documents, the deceptive display of three
decimals that belies the real precision, and the absence of confidence
intervals. These are minor issues that are easily amended and should be
corrected, but more substantive improvements are needed. There are indications
that the scientific community seeks and needs better certification of journal
procedures to improve the quality of published science. Comprehensive
certification of editorial and review procedures could help ensure adequate
procedures to detect duplicate and fraudulent submissions.Comment: 25 pages, 12 figures, 6 table
Unstable Flow and Non-Monotonic Constitutive Equation of Transient Networks
We have measured the nonlinear rheological response of a model transient
network over a large range of steady shear rates. The system is built up from
an oil in water droplet microemulsion into which a telechelic polymer is
incorporated. The phase behaviour is characterized which comprises a liquid-gas
phase separation and a percolation threshold. The rheological measurements are
performed in the one phase region above the percolation line. Shear thinning is
observed for all samples, leading in most cases to an unstable stress response
at intermediate shear rates. We built up a very simple mean field model which
involves the reduction of the residence time of the stickers in the droplets
due to the chain tensions at high shear. The computed constitutive equation is
non-monotonic with a range where the stress is a decreasing function of the
rate, a feature that indeed makes homogeneous flows unstable. The computed the
flow curves compare well to the experiments.Comment: mai 200
Determinantes Nacionais e Setoriais da Estrutura de Capital na América Latina
This study identified the role of the national environment (the Macroeconomy, Financial Development and
Institutional Quality) and industry characteristics (Munificence, Dynamism, Concentration, Life Cycle,
Technological Efficiency Dispersion, Product Quality Dispersion, Customer Bargaining Power and Supplier
Bargaining Power) on debt of 612 listed companies from 7 Latin American countries (Argentina, Brazil, Chile,
Colombia, Mexico, Peru and Venezuela). For comparison purposes, the analysis is also extended to 847 U.S.
companies. The period of study is 1996-2009 and the analysis employed a Hierarchical Linear Model, which
controls the effects according to the level of the variables (country, industry, time and firm). The results suggest
that Financial Development eases access to external funds and Institutional Quality is negatively related to firm
Leverage. The research also finds evidence that institutional quality can promote asymmetrical development
between stock markets and credit markets
Ovaries of Tubificinae (Clitellata, Naididae) resemble ovary cords found in Hirudinea (Clitellata)
The ultrastructure of the ovaries and oogenesis was studied in three species of three genera of Tubificinae. The paired ovaries are small, conically shaped structures, connected to the intersegmental septum between segments X and XI by their narrow end. The ovaries are composed of syncytial cysts of germ cells interconnected by stable cytoplasmic bridges (ring canals) and surrounded by follicular cells. The architecture of the germ-line cysts is exactly the same as in all clitellate annelids studied to date, i.e. each cell in a cyst has only one ring canal connecting it to the central, anuclear cytoplasmic mass, the cytophore. The ovaries found in all of the species studied seem to be meroistic, i.e. the ultimate fate of germ cells within a cyst is different, and the majority of cells withdraw from meiosis and become nurse cells; the rest continue meiosis, gather macromolecules, cell organelles and storage material, and become oocytes. The ovaries are polarized; their narrow end contains mitotically dividing oogonia and germ cells entering the meiosis prophase; whereas within the middle and basal parts, nurse cells, a prominent cytophore and growing oocytes occur. During late previtellogenesis/early vitellogenesis, the oocytes detach from the cytophore and float in the coelom; they are usually enveloped by the peritoneal epithelium and associated with blood vessels. Generally, the organization of ovaries in all of the Tubificinae species studied resembles the polarized ovary cords found within the ovisacs of some Euhirudinea. The organization of ovaries and the course of oogenesis between the genera studied and other clitellate annelids are compared. Finally, it is suggested that germ-line cysts formation and the meroistic mode of oogenesis may be a primary character for all Clitellata
Governance Conditions for Improving Quality Drinking Water Resources: the Need for Enhancing Connectivity
Realising the water quality objectives of the European Water Framework Directive have appeared to stagnate over the last decade all across Europe because of their highly complex nature. In the literature, interactive governance approaches tend to be regarded as the best way of dealing with complex water issues, but so far little empirical evidence has been reported on this perspective in regard to water quality issues. In this paper we have analysed how conditions of governance contribute to the realisation of water quality objectives at different types of drinking water resources in the Netherlands. The analysis demonstrates the importance of addressing different hydrological scales, institutional levels and sectors and thus enhance connectivity in order to improve water quality. The two other important conditions of governance approaches for water quality improvement which were identified are the use of joint fact-finding to gain a shared perception of risks, and the use of explicit decision-making and close monitoring of outcomes (re. water quality improvement), both of which contribute to this enhanced connectivity
Inter-population variations in concentrations, determinants of and correlations between 2,2',4,4',5,5'-hexachlorobiphenyl (CB-153) and 1,1-dichloro-2,2-bis (p-chlorophenyl)-ethylene (p,p'-DDE): a cross-sectional study of 3161 men and women from Inuit and European populations
BACKGROUND: The study is part of a collaborative project (Inuendo), aiming to assess the impact of dietary persistent organochlorine pollutants (POPs) on human fertility. The aims with the present study are to analyze inter-population variations in serum concentrations of 2,2',4,4',5,5'-hexachlorobiphenyl (CB-153) and 1,1-dichloro-2,2-bis (p-chlorophenyl)-ethylene (p,p'-DDE), to assess inter-population variations in biomarker correlations, and to evaluate the relative impact of different determinants for the inter-individual variations in POP-biomarkers. METHOD: In study populations of 3161 adults, comprising Greenlandic Inuits, Swedish fishermen and their wives, and inhabitants from Warsaw, Poland and Kharkiv, Ukraine, serum concentrations of CB-153 and p,p'-DDE, were analysed by gas chromatography-mass spectrometry. RESULTS: The median serum concentrations of CB-153 were for male and female Inuits 200 and 110, for Swedish fishermen 190 and their wives 84, for Kharkiv men and women 44 and 27, and for Warsaw men and women 17 and 11 ng/g lipids, respectively. The median serum concentrations of p,p'-DDE were for Kharkiv men and women 930 and 650, for male and female Inuits 560 and 300, for Warsaw men and women 530 and 380, and for Swedish fishermen 240 and their wives 140 ng/g lipids, respectively. The correlation coefficients between CB-153 and p,p'-DDE varied between 0.19 and 0.92, with the highest correlation among Inuits and the lowest among men from Warsaw. Men had averagely higher serum concentrations of CB-153 and p,p'-DDE, and there were positive associations between age and the POP-biomarkers, whereas the associations with BMI and smoking were inconsistent. Dietary seafood was of importance only in the Inuit and Swedish populations. CONCLUSION: CB-153 concentrations were much higher in Inuits and Swedish fishermen's populations than in the populations from Eastern Europe, whereas the pattern was different for p,p'-DDE showing highest concentrations in the Kharkiv population. The correlations between the POP-biomarkers varied considerably between the populations, underlining that exposure sources differ and that the choice of representative biomarkers of overall POP exposure has to be based on an analysis of the specific exposure situation for each population. Age and gender were consistent determinants of serum POPs; seafood was of importance only in the Inuit and Swedish populations
Functional Evolution of Leptin of Ochotona curzoniae in Adaptive Thermogenesis Driven by Cold Environmental Stress
BACKGROUND: Environmental stress can accelerate the directional selection and evolutionary rate of specific stress-response proteins to bring about new or altered functions, enhancing an organism's fitness to challenging environments. Plateau pika (Ochotona curzoniae), an endemic and keystone species on Qinghai-Tibetan Plateau, is a high hypoxia and low temperature tolerant mammal with high resting metabolic rate and non-shivering thermogenesis to cope in this harsh plateau environment. Leptin is a key hormone related to how these animals regulate energy homeostasis. Previous molecular evolutionary analysis helped to generate the hypothesis that adaptive evolution of plateau pika leptin may be driven by cold stress. METHODOLOGY/PRINCIPAL FINDINGS: To test the hypothesis, recombinant pika leptin was first purified. The thermogenic characteristics of C57BL/6J mice injected with pika leptin under warm (23±1°C) and cold (5±1°C) acclimation is investigated. Expression levels of genes regulating adaptive thermogenesis in brown adipose tissue and the hypothalamus are compared between pika leptin and human leptin treatment, suggesting that pika leptin has adaptively and functionally evolved. Our results show that pika leptin regulates energy homeostasis via reduced food intake and increased energy expenditure under both warm and cold conditions. Compared with human leptin, pika leptin demonstrates a superior induced capacity for adaptive thermogenesis, which is reflected in a more enhanced β-oxidation, mitochondrial biogenesis and heat production. Moreover, leptin treatment combined with cold stimulation has a significant synergistic effect on adaptive thermogenesis, more so than is observed with a single cold exposure or single leptin treatment. CONCLUSIONS/SIGNIFICANCE: These findings support the hypothesis that cold stress has driven the functional evolution of plateau pika leptin as an ecological adaptation to the Qinghai-Tibetan Plateau
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