Comprehensive Organic Analysis of Antartic Micrometeorites

Introduction: Micrometeorites (MMs) are thought to be significant contributors of organic material to the early Earth [1], and a variety of techniques have been employed to identify their organic composition [2-6]. These include the identification of key organic groups using combinations of infrared, energy dispersive Xray, electron energy loss and Raman spectroscopy and scanning transmission X-ray microscopy [2-4], highlighting similarities between that of MMs and carbonaceous chondrites. Few studies, however, have focused on the characterisation of individual micrometeoritic organic components. Microscopic L2MS has been used to identify up to C5 polycyclic aromatic hydrocarbons and their alkyl derivatives [5]. A combination of ionexchange chromatography and fluorimetric detection has also been successful in identifying a number of protein amino acids including glycine and alanine [6]. We have previously reported a method to analyse ?g-sized quantities of extraterrestrial materials, with prior application to assessing organic volatile release from MM atmospheric entry heating simulations [7]. In this study we utilise this technique to characterise the organic composition of Antarctic terrestrial particles and MMs collected in 1994 from Cap-Prudhomme [8]

Two-scale EHL: three-dimensional topography in tilted-pad bearings

Derived from the Heterogeneous Multiscale Methods (HMM), a two-scale method is developed for the analysis of Elastohydrodynamic Lubrication (EHL) and micro-EHL in tilted-pad bearings with three-dimensional topography. A relationship linking the pressure gradient to mass flow rate is derived and represented in the bearing domain through homogenisation of near-periodic simulations describing the Fluid Structure Interaction (FSI) of topographical features. For the parameters investigated the influence of compressibility and piezoviscosity was found to be more significant than that of non-Newtonian (shear-thinning) behaviour on textured bearing performance. As the size of topography increased two-scale solutions demonstrated that at constant load the coefficient of friction increased and the minimum film thickness decreased over a range of pad lengths and tilt angles

Fifth European Dirofilaria and Angiostrongylus Days (FiEDAD) 2016

Peer reviewe

Four‐dimensional‐STEM analysis of the phyllosilicate‐rich matrix of Ryugu samples

Ryugu asteroid grains brought back to the Earth by the Hayabusa2 space mission are pristine samples containing hydrated minerals and organic compounds. Here, we investigate the mineralogy of their phyllosilicate-rich matrix with four-dimensional scanning transmission electron microscopy (4D-STEM). We have identified and mapped the mineral phases at the nanometer scale (serpentine, smectite, pyrrhotite), observed the presence of Ni-bearing pyrrhotite, and identified the serpentine polymorph as lizardite, in agreement with the reported aqueous alteration history of Ryugu. Furthermore, we have mapped the d-spacings of smectite and observed a broad distribution of values, ranging from 1 to 2 nm, with an average d-spacing of 1.24 nm, indicating significant heterogeneity within the sample. Such d-spacing variability could be the result of either the presence of organic matter trapped in the interlayers or the influence of various geochemical conditions at the submicrometer scale, suggestive of a range of organic compounds and/or changes in smectite crystal chemistry

Dobrica et al 2023 Carbonates, useful tools to investigate shock metamorphic effects in CM chondrites

Carbonates, useful tools to investigate shock metamorphic effects in CM chondritesTHIS DATASET IS ARCHIVED AT DANS/EASY, BUT NOT ACCESSIBLE HERE. TO VIEW A LIST OF FILES AND ACCESS THE FILES IN THIS DATASET CLICK ON THE DOI-LINK ABOV

Investigation of Ultracarbonaceous Antarctic Micrometeorites by Analytical Transmission Electron Microscopy

International audienceUltracarbonaceous micrometeorites were studied by TEM in order to understand the mineralogy and petrology of probable cometary grains. GEMS, and spherical objects with an igneous signature similar to chondrules were observed in these samples

Fine-grained Mineralogy of Cometary Ultracarbonaceous Antarctic Micrometeorites

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A Statistical Overview of Concordia Antarctic Micrometeorites

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Raman characterization of carbonaceous matter in CONCORDIA Antarctic micrometeorites

We report a multi-wavelength Raman spectroscopy study of carbonaceous matter in 38 Antarctic micrometeorites (AMMs) from the 2006 CONCORDIA collection. The particles were selected as a function of their degree of thermal alteration developed during the deceleration in the atmosphere. These samples range from unmelted (fine-grained-Fg; ultracarbonaceous-UCAMMs) to partially melted AMMs (scorias-Sc) and completely melted particles (cosmic spherules-CS). More than half of the analyzed AMMs contain a substantial amount of polyaromatic carbonaceous matter with a high degree of disorder. The proportion of particles where carbon is not detected increase from the Fg to the Fg-Sc and to the Sc-AMMs, and no carbon is detected in CS. In addition, the spectral characteristics of the G and D bands of the carbonaceous matter in Sc-AMMs plot apart from the trend formed by the data from Fg-AMMs and UCAMMs. These results suggest that oxidation processes occurred during the deceleration of the particles in the atmosphere. In Fg-AMMs and UCAMMs, the spectral characteristics of the G and D bands reveal the high degree of disorder of the carbonaceous matter, precluding a long duration thermal metamorphism on the parent body and suggesting that AMMs have a connection with C1-C2 chondrites. The Raman parameters of the deuterium-rich carbonaceous matter of UCAMMs do not differ from that of Fg-AMMs. Using a 244 nm excitation, we detected the cyanide (-CN) functional group for the first time in a UCAMM, reinforcing the likely cometary origin of this type of micrometeorites