1,268 research outputs found
Ambipolar charge injection and transport in a single pentacene monolayer island
Electrons and holes are locally injected in a single pentacene monolayer
island. The two-dimensional distribution and concentration of the injected
carriers are measured by electrical force microscopy. In crystalline monolayer
islands, both carriers are delocalized over the whole island. On disordered
monolayer, carriers stay localized at their injection point. These results
provide insight into the electronic properties, at the nanometer scale, of
organic monolayers governing performances of organic transistors and molecular
devices.Comment: To be published in Nano Letter
Physical Study by Surface Characterizations of Sarin Sensor on the Basis of Chemically Functionalized Silicon Nanoribbon Field Effect Transistor
Surface characterizations of an organophosphorus (OP) gas detector based on
chemically functionalized silicon nanoribbon field-effect transistor (SiNR-FET)
were performed by Kelvin Probe Force Microscopy (KPFM) and ToF-SIMS, and
correlated with changes in the current-voltage characteristics of the devices.
KPFM measurements on FETs allow (i) to investigate the contact potential
difference (CPD) distribution of the polarized device as function of the gate
voltage and the exposure to OP traces and, (ii) to analyze the CPD hysteresis
associated to the presence of mobile ions on the surface. The CPD measured by
KPFM on the silicon nanoribbon was corrected due to side capacitance effects in
order to determine the real quantitative surface potential. Comparison with
macroscopic Kelvin probe (KP) experiments on larger surfaces was carried out.
These two approaches were quantitatively consistent. An important increase of
the CPD values (between + 399 mV and + 302 mV) was observed after the OP sensor
grafting, corresponding to a decrease of the work function, and a weaker
variation after exposure to OP (between - 14 mV and - 61 mV) was measured.
Molecular imaging by ToF-SIMS revealed OP presence after SiNR-FET exposure. The
OP molecules were essentially localized on the Si-NR confirming effectiveness
and selectivity of the OP sensor. A prototype was exposed to Sarin vapors and
succeeded in the detection of low vapor concentrations (40 ppm).Comment: Paper and supporting information, J. Phys. Chem. C, 201
Fruit scent and observer colour vision shape food-selection strategies in wild capuchin monkeys
The senses play critical roles in helping animals evaluate foods, including fruits that can change both in colour and scent during ripening to attract frugivores. Although numerous studies have assessed the impact of colour on fruit selection, comparatively little is known about fruit scent and how olfactory and visual data are integrated during foraging. We combine 25 months of behavioural data on 75 wild, white-faced capuchins (Cebus imitator) with measurements of fruit colours and scents from 18 dietary plant species. We show that frequency of fruit-directed olfactory behaviour is positively correlated with increases in the volume of fruit odours produced during ripening. Monkeys with red-green colour blindness sniffed fruits more often, indicating that increased reliance on olfaction is a behavioural strategy that mitigates decreased capacity to detect red-green colour contrast. These results demonstrate a complex interaction among fruit traits, sensory capacities and foraging strategies, which help explain variation in primate behaviour.https://www.nature.com/articles/s41467-019-10250-9Published versio
Conductance switching at the nanoscale of diarylethene derivatives self-assembled monolayers on LaSrMnO
We report on the phosphonic acid route for the grafting of functional
molecules, optical switch (dithienylethene diphosphonic acid, DDA), on
La0.7Sr0.3MnO3 (LSMO). Compact self-assembled monolayers (SAMs) of DDA are
formed on LSMO as studied by topographic atomic force microscopy (AFM),
ellipsometry, water contact angle and X-ray photoemission spectroscopy (XPS).
The conducting AFM measurements show that the electrical conductance of
LSMO/DDA is about 3 decades below that of the bare LSMO substrate. Moreover,
the presence of the DDA SAM suppresses the known conductance switching of the
LSMO substrate that is induced by mechanical and/or bias constraints during
C-AFM measurements. A partial light-induced conductance switching between the
open and closed forms of the DDA is observed for the LSMO/DDA/C-AFM tip
molecular junctions (closed/open conductance ratio of about 8). We show that,
in the case of long-time exposition to UV light, this feature can be masked by
a non-reversible decrease (a factor of about 15) of the conductance of the LSMO
electrode.Comment: Full paper with supporting informatio
Activity budget and gut microbiota stability and flexibility across reproductive states in wild capuchin monkeys in a seasonal tropical dry forest
Abstract
Background
Energy demands associated with pregnancy and lactation are significant forces in mammalian evolution. To mitigate increased energy costs associated with reproduction, female mammals have evolved behavioural and physiological responses. Some species alter activity to conserve energy during pregnancy and lactation, while others experience changes in metabolism and fat deposition. Restructuring of gut microbiota with shifting reproductive states may also help females increase the energy gained from foods, especially during pregnancy. The goal of this study was to examine the relationships among behaviour, gut microbiota composition, and reproductive state in a wild, non-human primate to better understand reproductive ecology. We combined life history data with > 13,000 behavioural scans and 298 fecal samples collected longitudinally across multiple years from 33 white-faced capuchin monkey (Cebus imitator) females. We sequenced the V4 region of the 16S rRNA gene and used the DADA2 pipeline to analyze microbial diversity. We used PICRUSt2 to assess putative functions.
Results
Reproductive state explained some variation in activity, but overall resting behaviours were relatively stable across pregnancy and lactation. Foraging was less frequent among females in the early stage of nursing compared to the cycling stage, though otherwise remained at comparable levels. Maximum temperature was a strong, significantly positive predictor of resting, while social dominance had a small but significantly negative effect on resting. Ecological variables such as available fruit biomass and rainfall had a small but significantly positive effects on measures of foraging time. Gut microbial community structure, including richness, alpha diversity, and beta diversity remained stable across the reproductive cycle. In pairwise comparisons, pregnant females exhibited increased relative abundances of multiple microbial ASVs, suggesting small changes in relation to reproductive state. Reproductive state was not linked to differential abundance of putative metabolic pathways.
Conclusions
Previous data suggest that activity budget and the gut microbiome shifts considerably during reproduction. The present study finds that both activity and gut microbial communities are less associated with reproduction compared to other predictors, including ecological contexts. This suggests that behavioural flexibility and gut microbial community plasticity is contrained by ecological factors in this population. These data contribute to a broader understanding of plasticity and stability in response to physiological shifts associated with mammalian reproduction
Random interactions and spin-glass thermodynamic transition in the hole-doped Haldane system YCaBaNiO
Magnetization, DC and AC bulk susceptibility of the =1 Haldane chain
system doped with electronic holes, YCaBaNiO
(0x0.20), have been measured and analyzed. The most striking
results are (i) a sub-Curie power law behavior of the linear susceptibility,
, for temperature lower than the Haldane gap
of the undoped compound (x=0) (ii) the existence of a spin-glass thermodynamic
transition at = 2-3 K. These findings are consistent with (i) random
couplings within the chains between the spin degrees of freedom induced by hole
doping, (ii) the existence of ferromagnetic bonds that induce magnetic
frustration when interchain interactions come into play at low temperature.Comment: 4 pages, 4 figures, to appear in Phys. Rev.
Connection between low energy effective Hamiltonians and energy level statistics
We study the level statistics of a non-integrable one dimensional interacting
fermionic system characterized by the GOE distribution. We calculate
numerically on a finite size system the level spacing distribution and
the Dyson-Mehta correlation. We observe that its low energy spectrum
follows rather the Poisson distribution, characteristic of an integrable
system, consistent with the fact that the low energy excitations of this system
are described by the Luttinger model. We propose this Random Matrix Theory
analysis as a probe for the existence and integrability of low energy effective
Hamiltonians for strongly correlated systems.Comment: REVTEX, 5 postscript figures at the end of the fil
Cassini observations of ion and electron beams at Saturn and their relationship to infrared auroral arcs
We present Cassini Visual and Infrared Mapping Spectrometer observations of infrared auroral emissions from the noon sector of Saturn's ionosphere revealing multiple intense auroral arcs separated by dark regions poleward of the main oval. The arcs are interpreted as the ionospheric signatures of bursts of reconnection occurring at the dayside magnetopause. The auroral arcs were associated with upward field-aligned currents, the magnetic signatures of which were detected by Cassini at high planetary latitudes. Magnetic field and particle observations in the adjacent downward current regions showed upward bursts of 100–360 keV light ions in addition to energetic (hundreds of keV) electrons, which may have been scattered from upward accelerated beams carrying the downward currents. Broadband, upward propagating whistler waves were detected simultaneously with the ion beams. The acceleration of the light ions from low altitudes is attributed to wave-particle interactions in the downward current regions. Energetic (600 keV) oxygen ions were also detected, suggesting the presence of ambient oxygen at altitudes within the acceleration region. These simultaneous in situ and remote observations reveal the highly energetic magnetospheric dynamics driving some of Saturn's unusual auroral features. This is the first in situ identification of transient reconnection events at regions magnetically conjugate to Saturn's magnetopause
Academic team formation as evolving hypergraphs
This paper quantitatively explores the social and socio-semantic patterns of
constitution of academic collaboration teams. To this end, we broadly underline
two critical features of social networks of knowledge-based collaboration:
first, they essentially consist of group-level interactions which call for
team-centered approaches. Formally, this induces the use of hypergraphs and
n-adic interactions, rather than traditional dyadic frameworks of interaction
such as graphs, binding only pairs of agents. Second, we advocate the joint
consideration of structural and semantic features, as collaborations are
allegedly constrained by both of them. Considering these provisions, we propose
a framework which principally enables us to empirically test a series of
hypotheses related to academic team formation patterns. In particular, we
exhibit and characterize the influence of an implicit group structure driving
recurrent team formation processes. On the whole, innovative production does
not appear to be correlated with more original teams, while a polarization
appears between groups composed of experts only or non-experts only, altogether
corresponding to collectives with a high rate of repeated interactions
Random Antiferromagnetic Spin-1/2 Chains with Competing Interactions
We study disordered antiferromagnetic spin-1/2 chains with nearest- and
further-neighbor interactions using the real-space renormalization-group
method. We find that the system supports two different phases, depending on the
ratio of the strength between nearest-neighbor and further-neighbor
interactions as well the bond randomness strength. For weak further neighbor
coupling the system is in the familiar random singlet phase, while stronger
further neighbor coupling drives the system to a large spin phase similar to
that found in the study of random antiferromagnetic-ferromagnetic spin chains.
The appearance of the large spin phase in the absence of ferromagnetic coupling
is due to the frustration introduced by further neighboring couplings, and is
unique to the disordered chains.Comment: 11 pages, 7 figure
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