476 research outputs found
High resolution characterisation of microstructural evolution in RbFeSe crystals on annealing
The superconducting and magnetic properties of phase-separated
AFeSe compounds are known to depend on post-growth heat
treatments and cooling profiles. This paper focusses on the evolution of
microstructure on annealing, and how this influences the superconducting
properties of RbFeSe crystals. We find that the minority phase in
the as-grown crystal has increased unit cell anisotropy (c/a ratio), reduced Rb
content and increased Fe content compared to the matrix. The microstructure is
rather complex, with two-phase mesoscopic plate-shaped features aligned along
{113} habit planes. The minority phase are strongly facetted on the {113}
planes, which we have shown to be driven by minimising the volume strain energy
introduced as a result of the phase transformation. Annealing at 488K results
in coarsening of the mesoscopic plate-shaped features and the formation of a
third distinct phase. The subtle differences in structure and chemistry of the
minority phase(s) in the crystals are thought to be responsible for changes in
the superconducting transition temperature. In addition, scanning photoemission
microscopy has clearly shown that the electronic structure of the minority
phase has a higher occupied density of states of the low binding energy Fe3d
orbitals, characteristic of crystals that exhibit superconductivity. This
demonstrates a clear correlation between the Fe-vacancy-free phase with high
c/a ratio and the electronic structure characteristics of the superconducting
phase.Comment: 6 figures v2 is exactly the same as v1. The typesetting errors in the
abstract have been correcte
Correlations in nano-scale step fluctuations: comparison of simulation and experiments
We analyze correlations in step-edge fluctuations using the
Bortz-Kalos-Lebowitz kinetic Monte Carlo algorithm, with a 2-parameter
expression for energy barriers, and compare with our VT-STM line-scan
experiments on spiral steps on Pb(111). The scaling of the correlation times
gives a dynamic exponent confirming the expected step-edge-diffusion
rate-limiting kinetics both in the MC and in the experiments. We both calculate
and measure the temperature dependence of (mass) transport properties via the
characteristic hopping times and deduce therefrom the notoriously-elusive
effective energy barrier for the edge fluctuations. With a careful analysis we
point out the necessity of a more complex model to mimic the kinetics of a
Pb(111) surface for certain parameter ranges.Comment: 10 pages, 9 figures, submitted to Physical Review
Quantum interference structures in the conductance plateaus of gold nanojunctions
The conductance of breaking metallic nanojunctions shows plateaus alternated
with sudden jumps, corresponding to the stretching of stable atomic
configurations and atomic rearrangements, respectively. We investigate the
structure of the conductance plateaus both by measuring the voltage dependence
of the plateaus' slope on individual junctions and by a detailed statistical
analysis on a large amount of contacts. Though the atomic discreteness of the
junction plays a fundamental role in the evolution of the conductance, we find
that the fine structure of the conductance plateaus is determined by quantum
interference phenomenon to a great extent.Comment: 4 pages, 4 figure
Fluctuations, line tensions, and correlation times of nanoscale islands on surfaces
We analyze in detail the fluctuations and correlations of the (spatial)
Fourier modes of nano-scale single-layer islands on (111) fcc crystal surfaces.
We analytically show that the Fourier modes of the fluctuations couple due to
the anisotropy of the crystal, changing the power spectrum of the fluctuations,
and that the actual eigenmodes of the fluctuations are the appropriate linear
combinations of the Fourier modes. Using kinetic Monte Carlo simulations with
bond-counting parameters that best match realistic energy barriers for hopping
rates, we deduce absolute line tensions as a function of azimuthal orientation
from the analyses of the fluctuation of each individual mode. The
autocorrelation functions of these modes give the scaling of the correlation
times with wavelength, providing us with the rate-limiting kinetics driving the
fluctuations, here step-edge diffusion. The results for the energetic
parameters are in reasonable agreement with available experimental data for
Pb(111) surfaces, and we compare the correlation times of island-edge
fluctuations to relaxation times of quenched Pb crystallites.Comment: 11 pages, 8 figures; to appear in PRB 70, xxx (15 Dec 2004), changes
in MC and its implication
Manufacture of electrical and magnetic graded and anisotropic materials for novel manipulations of microwaves
Spatial transformations (ST) provide a design framework to generate a required spatial distribution of electrical and magnetic properties of materials to effect manipulations of electromagnetic waves. To obtain the electromagnetic properties required by these designs, the most common materials approach has involved periodic arrays of metal-containing subwavelength elements. While aspects of ST theory have been confirmed using these structures, they are often disadvantaged by narrowband operation, high losses and difficulties in implementation. An all-dielectric approach involves weaker interactions with applied fields, but may offer more flexibility for practical implementation. This paper investigates manufacturing approaches to produce composite materials that may be conveniently arranged spatially, according to ST-based designs. A key aim is to highlight the limitations and possibilities of various manufacturing approaches, to constrain designs to those that may be achievable. The article focuses on polymer-based nano- and microcomposites in which interactions with microwaves are achieved by loading the polymers with high-permittivity and high-permeability particles, and manufacturing approaches based on spray deposition, extrusion, casting and additive manufacture
Microstructural analysis of phase separation in iron chalcogenide superconductors
The interplay between superconductivity, magnetism and crystal structure in
iron-based superconductors is a topic of great interest amongst the condensed
matter physics community as it is thought to be the key to understanding the
mechanisms responsible for high temperature superconductivity. Alkali metal
doped iron chalcogenide superconductors exhibit several unique characteristics
which are not found in other iron-based superconducting materials such as
antiferromagnetic ordering at room temperature, the presence of ordered iron
vacancies and high resistivity normal state properties. Detailed
microstructural analysis is essential in order to understand the origin of
these unusual properties. Here we have used a range of complementary scanning
electron microscope based techniques, including high-resolution electron
backscatter di raction mapping, to assess local variations in composition and
lattice parameter with high precision and sub-micron spatial resolution. Phase
separation is observed in the Csx Fe2-ySe2 crystals, with the minor phase
distributed in a plate-like morphology throughout the crystal. Our results are
consistent with superconductivity occurring only in the minority phase.Comment: Accepted for publication in a special edition of Supercond. Sci.
Techno
Conformity of spin fluctuations in alkali-metal iron selenide superconductors inferred from the observation of a magnetic resonant mode in K(x)Fe(2-y)Se(2)
Spin excitations stemming from the metallic phase of the ferrochalcogenide
superconductor K(0.77)Fe(1.85)Se(2) (T_c=32 K) were mapped out in the ab plane
by means of the time-of-flight neutron spectroscopy. We observed a magnetic
resonant mode at Q_res=(1/2 1/4), whose energy and in-plane shape are almost
identical to those in the related compound Rb(0.8)Fe(1.6)Se(2). This lets us
infer that there is a unique underlying electronic structure of the bulk
superconducting phase K(x)Fe(2)Se(2), which is universal for all alkali-metal
iron selenide superconductors and stands in contrast to the doping-tunable
phase diagrams of the related iron pnictides. Furthermore, the spectral weight
of the resonance on the absolute scale, normalized to the volume fraction of
the superconducting phase, is several times larger than in optimally doped
BaFe(2-x)Co(x)As(2). We also found no evidence for any additional low-energy
branches of spin excitations away from Q_res. Our results provide new input for
theoretical models of the spin dynamics in iron based superconductors
New criteria for the molecular identification of cereal grains associated with archaeological artefacts.
The domestication and transmission of cereals is one of the most fundamental components of early farming, but direct evidence of their use in early culinary practices and economies has remained frustratingly elusive. Using analysis of a well-preserved Early Bronze Age wooden container from Switzerland, we propose novel criteria for the identification of cereal residues. Using gas chromatography mass spectrometry (GC-MS), we identified compounds typically associated with plant products, including a series of phenolic lipids (alkylresorcinols) found only at appreciable concentration in wheat and rye bran. The value of these lipids as cereal grain biomarkers were independently corroborated by the presence of macrobotanical remains embedded in the deposit, and wheat and rye endosperm peptides extracted from residue. These findings demonstrate the utility of a lipid-based biomarker for wheat and rye bran and offer a methodological template for future investigations of wider range of archaeological contexts. Alkylresorcinols provide a new tool for residue analysis which can help explore the spread and exploitation of cereal grains, a fundamental component of the advent and spread of farming
Transition from tunneling to direct contact in tungsten nanojunctions
We apply the mechanically controllable break junctions technique to
investigate the transition from tunneling to direct contact in tungsten. This
transition is quite different from that of other metals and is determined by
the local electronic properties of the tungsten surface and the relief of the
electrodes at the point of their closest proximity. The conductance traces show
a rich variety of patterns from the avalanche-like jump to a mesoscopic contact
to the completely smooth transition between direct contact and tunneling. Due
to the occasional absence of an adhesive jump the conductance of the contact
can be continuously monitored at ultra-small electrode separations. The
conductance histograms of tungsten are either featureless or show two distinct
peaks related to the sequential opening of spatially separated groups of
conductance channels. The role of surface states of tungsten and their
contribution to the junction conductance at sub-Angstrom electrode separations
are discussed.Comment: 6 pages, 6 figure
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