Formate as a key intermediate in CO₂ utilization

Replacing fossil feedstocks for chemicals and polymers in the chemical industry is a key step towards a future circular society. Making use of CO2 as a starting material in Carbon Capture and Utilization (CCU) or Carbon Capture and Storage (CCS) processes presents a great opportunity. Unfortunately, converting CO2 is not easy - due to its stability and inherently low reactivity either high energy inputs or nifty catalytic systems are required for its conversion. An electrochemical cell using a gas-diffusion electrode to convert CO2 into formate is such a promising system. But making formate alone does not allow us to substitute many fossil carbon-fed processes. Oxalic acid on the other hand is a potential new platform chemical for material production as useful monomers such as glycolic acid can be derived from it. Fortunately, formate can be converted into oxalate (and subsequently oxalic acid) by coupling two formates in a formate to oxalate coupling reaction (FOCR). The FOCR is a reaction that has been studied for more than 175 years and has seen widespread industrial use in the past. In this work, we critically discuss the history of the FOCR, present the most recent advances and draw a perspective for its future. We provide an overview of all (side)products obtained in FOCR and examine the various reaction parameters and their ability to influence the reaction. To understand the reaction better and improve it in the future, we critically discuss the many mechanisms proposed for the various catalytic systems in the FOCR. At last, we explore the potential to introduce new catalytic and solvent systems or co-reactants to the FOCR to improve reaction performance and broaden the range of products from CO2 derived formate

Signatures of Many-Body Localization in a Controlled Open Quantum System

In the presence of disorder, an interacting closed quantum system can undergo many-body localization (MBL) and fail to thermalize. However, over long times, even weak couplings to any thermal environment will necessarily thermalize the system and erase all signatures of MBL. This presents a challenge for experimental investigations of MBL since no realistic system can ever be fully closed. In this work, we experimentally explore the thermalization dynamics of a localized system in the presence of controlled dissipation. Specifically, we find that photon scattering results in a stretched exponential decay of an initial density pattern with a rate that depends linearly on the scattering rate. We find that the resulting susceptibility increases significantly close to the phase transition point. In this regime, which is inaccessible to current numerical studies, we also find a strong dependence on interactions. Our work provides a basis for systematic studies of MBL in open systems and opens a route towards extrapolation of closed-system properties from experiments.We acknowledge financial support by the European Commission (UQUAM, AQuS) and the Nanosystems Initiative Munich (NIM). Work at Strathclyde is supported by the EOARD via AFOSR Grant No. FA2386-14-1-5003. This research was supported in part by the National Science Foundation under Grant No. NSF PHY11-25915. M. H. F. acknowledges additional support from the Swiss Society of Friends of the Weizmann Institute of Science and S. S. H. acknowledges additional support from the Australian Research Council through Discovery Early Career Research Award No. DE150100315

Changes in social inequality with respect to health-related living conditions of 6-year-old children in East Germany after re-unification

BACKGROUND: Since Germany re-unified in 1990, substantial social and economic changes have happened in East Germany, the former socialist German Democratic Republic (GDR). The aim of this study was to investigate the influence of these socio-economic changes in East Germany on the association between social status, measured by parental educational level, and health-related living conditions of children during the ten-year period after re-unification. METHODS: In total, 25,864 6-year-old school beginner children (51.2% male and 48.8% female) participated in cross-sectional studies which have been repeated every year from 1991 to 2000 in East Germany. Parental educational level as a social indicator was the independent variable. Dependent variables included not employed parents, small living space and health-related living conditions (e. g. damp housing, single oven heating and living at busy road). The relationships were described by odds ratios using logistic regression. RESULTS: A large overall effect of parental educational level on health-related living conditions was observed. The time trends showed that the situation regarding small living space, damp housing conditions and single oven heating improved from 1991 to 2000, while regarding not employed parents (1996–2000) and living at busy road (1991–2000) did not, but even deteriorated. 6-year old children with low parental educational level, who lived at the time of re-unification, were often under damp housing conditions and with single oven heating at homes. Nevertheless, this social inequality has almost vanished ten years later. In contrast, we found an increasing gap between low and high parental educational level with respect to the proportion of parents who were not employed (22%: 4% gain), or lived under cramped housing conditions (22%: 37% reduction), or close to a busy road (7% gain: 2% reduction). CONCLUSION: The social inequalities which already existed under the socialist system in East Germany persisted in the system of social market economy between 1991 and 2000. 6-year-old children from families with the lowest social status were living under the worst domestic conditions (e. g. living at busy road, having damp housing conditions, single oven heating and small living space) and for some conditions (e. g. living at busy road and having small living space) the gap betweenlow and high social status was even bigger in 2000 than in 1991

Lower plate structure and upper plate deformational segmentation at the Sunda-Banda arc transition, Indonesia

The Sunda‐Banda arc transition at the eastern termination of the Sunda margin (Indonesia) represents a unique natural laboratory to study the effects of lower plate variability on upper plate deformational segmentation. Neighboring margin segments display a high degree of structural diversity of the incoming plate (transition from an oceanic to a continental lower plate, presence/absence of an oceanic plateau, variability of subducting seafloor morphology) as well as a wide range of corresponding fore‐arc structures, including a large sedimentary basin and an accretionary prism/outer arc high of variable size and shape. Here, we present results of a combined analysis of seismic wide‐angle refraction, multichannel streamer and gravity data recorded in two trench normal corridors located offshore the islands of Lombok (116°E) and Sumba (119°E). On the incoming plate, the results reveal a 8.6–9.0 km thick oceanic crust, which is progressively faulted and altered when approaching the trench, where upper mantle velocities are reduced to ∼7.5 km/s. The outer arc high, located between the trench and the fore‐arc basin, is characterized by sedimentary‐type velocities (Vp < 5.5 km/s) down to the top of the subducting slab (∼13 km depth). The oceanic slab can be traced over 70–100 km distance beneath the fore arc. A shallow serpentinized mantle wedge at ∼16 km depth offshore Lombok is absent offshore Sumba, where our models reveal the transition to the collisional regime farther to the east and to the Sumba block in the north. Our results allow a detailed view into the complex structure of both the deeper and shallower portions of the eastern Sunda margin

Socioeconomic status and health in the second half of life: findings from the German Ageing Survey

This study examined social inequalities in health in the second half of life. Data for empirical analyses came from the second wave of the German Ageing Survey (DEAS), an ongoing population-based, representative study of community dwelling persons living in Germany, aged 40–85 years (N = 2,787). Three different indicators for socioeconomic status (SES; education, income, financial assets as an indicator for wealth) and health (physical, functional and subjective health) were employed. It could be shown that SES was related to health in the second half of life: Less advantaged persons between 40 and 85 years of age had worse health than more advantaged persons. Age gradients varied between status indicators and health dimensions, but in general social inequalities in health were rather stable or increasing over age. The latter was observed for wealth-related absolute inequalities in physical and functional health. Only income-related differences in subjective health decreased at higher ages. The amount of social inequality in health as well as its development over age did not vary by gender and place of residence (East or West Germany). These results suggest that, in Germany, the influence of SES on health remains important throughout the second half of life

Sport, War and Democracy in Classical Athens

This article concerns the paradox of athletics in classical Athens. Democracy may have opened up politics to every class of Athenian but it had little impact on sporting participation. The city’s athletes continued to drawn predominantly from the upper class. It comes as a surprise then that lower-class Athenians actually esteemed athletes above every other group in the public eye, honoured them very generously when they won, and directed a great deal of public and private money to sporting competitions and facilities. In addition athletics escaped the otherwise persistent criticism of upper-class activities in the popular culture of the democracy. The research of social scientists on sport and aggression suggests this paradox may have been due to the cultural overlap between athletics and war under the Athenian democracy. The article concludes that the practical and ideological democratization of war by classical Athens legitimized and supported upper-class sport

Periodically driving a many-body localized quantum system

We experimentally study a periodically driven many-body localized system realized by interacting fermions in a one-dimensional quasi-disordered optical lattice. By preparing the system in a far-from-equilibrium state and monitoring the remains of an imprinted density pattern, we identify a localized phase at high drive frequencies and an ergodic phase at low ones. These two distinct phases are separated by a dynamical phase transition which depends on both the drive frequency and the drive strength. Our observations are quantitatively supported by numerical simulations and are directly connected to the change in the statistical properties of the effective Floquet Hamiltonian.We acknowledge support from Technical University of Munich - Institute for Advanced Study, funded by the German Excellence Initiative and the European Union FP7 under grant agreement 291763, from the DFG grant no. KN 1254/1-1, the European Commission (UQUAM, AQuS) and the Nanosystems Initiative Munich (NIM)

TRANSALP—A transect through a young collisional orogen: Introduction

TRANSALP is a multidisciplinary and international research programme for investigating the deep structure and evolution of the Eastern Alps (Fig. 1) as a paradigmatic example for mountain building by continent–continent collision. The Alps as the youngest and highest mountain range in Europe have always been a challenge for geoscientists, and have played a key role in the development of new concepts and theories of mountain building (e.g. Termier, 1904, Ampferer, 1906, Argand, 1924, Dal Piaz, 1934, Dewey and Bird, 1970, Laubscher, 1970 and Oxburgh, 1972). While our former understanding was mainly based on geology and low resolution geophysical methods such as gravimetry and deep seismic soundings (DSS) with wide-angle and refraction seismics, more recently remarkable progress has been gained in the Western and Central Alps by applying the high-resolution technology of deep seismic reflection profiling (Roure et al., 1990 and Pfiffner et al., 1997), adapted from exploration techniques used in oil and gas industry