Production of hydrogen by unmixed steam reforming of methane

Unmixed steam reforming is an alternative method of catalytic steam reforming that uses separate air and fuel–steam feeds, producing a reformate high in H2 content using a single reactor and a variety of fuels. It claims insensitivity to carbon formation and can operate autothermally. The high H2 content is achieved by in situ N2 separation from the air using an oxygen transfer material (OTM), and by CO2 capture using a solid sorbent. The OTM and CO2 sorbent are regenerated during the fuel–steam feed and the air feed, respectively, within the same reactor. This paper describes the steps taken to choose a suitable CO2-sorbent material for this process when using methane fuel with the help of microreactor tests, and the study of the carbonation efficiency and regeneration ability of the materials tested. Elemental balances from bench scale experiments using the best OTM in the absence of the CO2 sorbent allow identifying the sequence of the chemical reaction mechanism. The effect of reactor temperature between 600 and on the process outputs is investigated. Temperatures of 600 and under the fuel–steam feed were each found to offer a different set of desirable outputs. Two stages during the fuel–steam feed were characterised by a different set of global reactions, an initial stage where the OTM is reduced directly by methane, and indirectly by hydrogen produced by methane thermal decomposition, in the second stage, steam reforming takes over once sufficient OTM has been reduced. The implications of these stages on the process desirable outputs such as efficiency of reactants conversion, reformate gas quality, and transient effects are discussed

Indentation of the Pamirs with respect to the northern margin of Tibet: constraints from the Tarim basin sedimentary record

The Pamirs represent the indented westward continuation of the northern margin of the Tibetan Plateau, dividing the Tarim and Tajik basins. Their evolution may be a key factor influencing aridification of the Asian interior, yet the tectonics of the Pamir Salient are poorly understood. We present a provenance study of the Aertashi section, a Paleogene to late Neogene clastic succession deposited in the Tarim basin to the north of the NW margin of Tibet (the West Kunlun) and to the east of the Pamirs. Our detrital zircon U-Pb ages coupled with zircon fission track, bulk rock Sm-Nd, and petrography data document changes in contributing source terranes during the Oligocene to Miocene, which can be correlated to regional tectonics. We propose a model for the evolution of the Pamir and West Kunlun (WKL), in which the WKL formed topography since at least ~200 Ma. By ~25 Ma, movement along the Pamir-bounding faults such as the Kashgar-Yecheng Transfer System had commenced, marking the onset of Pamir indentation into the Tarim-Tajik basin. This is coincident with basinward expansion of the northern WKL margin, which changed the palaeodrainage pattern within the Kunlun, progressively cutting off the more southerly WKL sources from the Tarim basin. An abrupt change in the provenance and facies of sediments at Aertashi has a maximum age of 14 Ma; this change records when the Pamir indenter had propagated sufficiently far north that the North Pamir was now located proximal to the Aertashi region

Increasing human motor skill acquisition by driving theta-gamma coupling

Skill learning is a fundamental adaptive process, but the mechanisms remain poorly understood. Some learning paradigms, particularly in the memory domain, are closely associated with gamma activity that is amplitude-modulated by the phase of underlying theta activity, but whether such nested activity patterns also underpin skill learning is unknown. Here we addressed this question by using transcranial alternating current stimulation (tACS) over sensorimotor cortex to modulate theta-gamma activity during motor skill acquisition, as an exemplar of a non-hippocampal-dependent task. We demonstrated, and then replicated, a significant improvement in skill acquisition with theta-gamma tACS, which outlasted the stimulation by an hour. Our results suggest that theta-gamma activity may be a common mechanism for learning across the brain and provides a putative novel intervention for optimising functional improvements in response to training or therapy

Designer diatom episomes delivered by bacterial conjugation.

Eukaryotic microalgae hold great promise for the bioproduction of fuels and higher value chemicals. However, compared with model genetic organisms such as Escherichia coli and Saccharomyces cerevisiae, characterization of the complex biology and biochemistry of algae and strain improvement has been hampered by the inefficient genetic tools. To date, many algal species are transformable only via particle bombardment, and the introduced DNA is integrated randomly into the nuclear genome. Here we describe the first nuclear episomal vector for diatoms and a plasmid delivery method via conjugation from Escherichia coli to the diatoms Phaeodactylum tricornutum and Thalassiosira pseudonana. We identify a yeast-derived sequence that enables stable episome replication in these diatoms even in the absence of antibiotic selection and show that episomes are maintained as closed circles at copy number equivalent to native chromosomes. This highly efficient genetic system facilitates high-throughput functional characterization of algal genes and accelerates molecular phytoplankton research

Attracting Manifold for a Viscous Topology Transition

An analytical method is developed describing the approach to a finite-time singularity associated with collapse of a narrow fluid layer in an unstable Hele-Shaw flow. Under the separation of time scales near a bifurcation point, a long-wavelength mode entrains higher-frequency modes, as described by a version of Hill's equation. In the slaved dynamics, the initial-value problem is solved explicitly, yielding the time and analytical structure of a singularity which is associated with the motion of zeroes in the complex plane. This suggests a general mechanism of singularity formation in this system.Comment: 4 pages, RevTeX, 3 ps figs included with text in uuencoded file, accepted in Phys. Rev. Let

Neutron capture cross section measurements for 197Au from 3.5 to 84 keV at GELINA

Cross section measurements have been performed at the time-of-flight facility GELINA to determine the average capture cross section for 197Au in the energy region between 3.5 keV and 84 keV. Prompt gamma-rays, originating from neutron induced capture events, were detected by two C6D6 liquid scintillators. The sample was placed at about 13 m distance from the neutron source. The total energy detection principle in combination with the pulse height weighting technique was applied. The energy dependence of the neutron flux was measured with a double Frisch-gridded ionization chamber based on the 10B(n,alpha)reaction. The data have been normalized to the well-isolated and saturated 197Au resonance at 4.9 eV. Special care was taken to reduce bias effects due to the weighting function, normalization, dead time and background corrections. The total uncertainty due to normalization, neutron flux and weighting function is 1.0%. An additional uncertainty of 0.5% results from the correction for self-shielding and multiple interaction events. Fluctuations due to resonance structures have been studied by complementary measurements at a 30 m flight path station. The results reported in this work deviate systematically by more than 5% from the cross section that is recommended as a reference for astrophysical applications. They are about 2% lower compared to an evaluation of the 197Au(n,gamma) cross section, which was based on a least squares fit of experimental data available in the literature prior to this work. The average capture cross section as a function of neutron energy has been parameterized in terms of average resonance parameters. Maxwellian average cross sections at different temperatures have been calculated.JRC.D.4-Standards for Nuclear Safety, Security and Safeguard

Surface Region of Superfluid Helium as an Inhomogeneous Bose-Condensed Gas

We present arguments that the low density surface region of self-bounded superfluid $^4$He systems is an inhomogeneous dilute Bose gas, with almost all of the atoms occupying the same single-particle state at $T = 0$. Numerical evidence for this complete Bose-Einstein condensation was first given by the many-body variational calculations of $^4$He droplets by Lewart, Pandharipande and Pieper in 1988. We show that the low density surface region can be treated rigorously using a generalized Gross-Pitaevskii equation for the Bose order parameter.Comment: 4 pages, 1 Postscript figur

The First 1 1/2 Years of TOTEM Roman Pot Operation at LHC

Since the LHC running season 2010, the TOTEM Roman Pots (RPs) are fully operational and serve for collecting elastic and diffractive proton-proton scattering data. Like for other moveable devices approaching the high intensity LHC beams, a reliable and precise control of the RP position is critical to machine protection. After a review of the RP movement control and position interlock system, the crucial task of alignment will be discussed.Comment: 3 pages, 6 figures; 2nd International Particle Accelerator Conference (IPAC 2011), San Sebastian, Spain; contribution MOPO01

Engaging with sustainability issues in metropolitan Chennai : city report

Chennai is the largest metropolitan city in South India (8.7 million in 2011) and the provincial capital of the large state of Tamil Nadu (population 72 million in 2011). Before that, under British rule, the city was the capital of the Madras Presidency, and was known as Madras until 1996, when the name was officially changed to Chennai. Located on the east coast of India, on the Bay of Bengal, sea trade has been an important aspect of the regional economy since at least the colonial period. Still today, the city combines political functions with economic command functions for both manufacturing and services, reflecting the region's diversified economy. The Chennai metropolitan area has witnessed strong growth over the last 20 years in automobile manufacturing, software services, hardware manufacturing, healthcare and financial services (CDP 2009). However, it should be noted that only 30% of total employment in the city takes place in the formal sector i.e., is covered by contracts and labour laws, the remaining 70% falls in the informal sector. This underscores the importance of small and micro enterprises and self-employment for providing goods, services and livelihoods in the local economy