A construção dos papéis de gênero na política : Dilma e a revista Istoé de 6 de abril de 2016

Trabalho de Conclusão de Curso (graduação)—Universidade de Brasília, Instituto de Ciências Humanas, Departamento de História, 2018.Esta monografia procurou analisar a capa da revista Istoé de 6 de Abril de 2016 e o artigo de capa “As Explosões Nervosas da Presidente”. A escolha dessa fonte e da presidenta Dilma Rousseff como objetos de pesquisa foi motivada pelas questões de gênero que a fonte suscita e o debate provocado sobre a construção dos papéis masculinos e femininos dentro da política. Foi feita uma análise do documento em questão voltada para a discussão dos papéis de gênero dentro da vida pública e privada, o papel da mídia na naturalização de discursos misóginos e as diferentes abordagens sobre a representação masculina e feminina na política

Municipal Finances in West Virginia

West Virginia’s municipalities are part of the lifeblood of our state. From the smallest incorporated towns and villages to our larger cities like Charleston, Wheeling, and Morgantown, our state’s cities and towns often act as hubs for civic, social, cultural, and economic activity. We associate these municipalities and their surrounding communities as places to shop, work, worship, and receive services like healthcare and education. This report seeks to place West Virginia’s cities and towns in this broader context of change, challenge, and opportunity by providing an in-depth study of major features, trends, and factors in municipal finance

Introducing MR‐TADF emitters into Light‐Emitting Electrochemical Cells for narrowband and efficient emission

The Umeå University authors wish to acknowledge generous financial support from the Swedish Research Council, the Swedish Energy Agency, Bertil och Britt Svenssons stiftelse för belysningsteknik, Länsstyrelsen Västerbotten, Kempestiftelserna, Olle Engkvists Stiftelse, Wenner-Gren Foundations, and the Wallenberg Initiative Materials Science for Sustainability, WISE. The St Andrews authors thank the Engineering and Physical Sciences Research Council (EP/R035164/1).Organic semiconductors that emit by the process of multi‐resonance thermally activated delayed fluorescence (MR‐TADF) can deliver narrowband and efficient electroluminescence while being processable from solvents and metal‐free. This renders them attractive for use as the emitter in sustainable light‐emitting electrochemical cells (LECs), but so far reports of narrowband and efficient MR‐TADF emission from LEC devices are absent. Here, this issue is addressed through careful and systematic material selection and device development. Specifically, the authors show that the detrimental aggregation tendency of an archetypal rigid and planar carbazole‐based MR‐TADF emitter can be inhibited by its dispersion into a compatible carbazole‐based blend host and an ionic‐liquid electrolyte, and it is further demonstrated that the tuning of this active material results in a desired balanced p‐ and n‐type electrochemical doping, a high solid‐state photoluminescence quantum yield of 91%, and singlet and triplet trapping on the MR‐TADF guest emitter. The introduction of this designed metal‐free active MR‐TADF material into a LEC, employing air‐stabile electrodes, results in bright blue electroluminescence of 500 cd m−2, which is delivered at a high external quantum efficiency of 3.8% and shows a narrow emission profile with a full‐width‐at‐half‐maximum of 31 nm.Publisher PDFPeer reviewe

A BODIPY small molecule as hole transporting material for efficient perovskite solar cells

BODIPY-based materials are well known for their outstanding chemical and photo-stability as well as their ease of synthesis and tunability of their frontier molecular orbitals. These are attractive features for hole transporting materials (HTMs) for perovskite solar cells (PSCs) that could help improve device stability and cost. In this paper, we report the straightforward synthesis of a new BODIPY small molecule, PTZ-PTZ-BDP, functionalised with phenothiazine moieties in both the meso and α positions giving rise to a Y-shaped structure. As estimated by DFT calculations, and confirmed by electrochemical and ambient photoemission spectroscopy studies, PTZ-PTZ-BDP presents appropriate energy levels suitable for its use as a HTM in PSCs. Electrochemical measurements also reveal several redox processes with excellent reversibility. Systematic evaluation of its performance as HTM in n–i–p PSC with and without dopants was conducted and the device parameters compared with commonly used HTMs of spiro-OMeTAD and PTAA. The CH3NH3PbI3 based PSCs incorporating simple solution processed PTZ-PTZ-BDP as HTM demonstrated a champion power conversion efficiency of 14.6%, matched in performance and shelf-life stability to complex and expensive state-of-the-art HTMs, showing that BODIPY based HTMs are a promising direction for perovskite solar cells

New thiophene-based conjugated macrocycles for optoelectronic applications

GC acknowledges the EPSRC for funding (EP/E036244/1). JMS acknowledges the Coordenação de Aperfeiçoamento de Pessoal de Nível Superior – Brasil (CAPES) – Finance Code 001 for PhD funding. JMS also acknowledges Dr Nor Basid Adiwibawa Prasetya for helpful advice. Dr L. K. Jagadamma acknowledges support from a Marie Skłodowska-Curie Individual Fellowship (European Commission) (MCIF: No. 745776).Thiophene-based semiconductors are amongst the most successful materials in organic electronics. In this contribution, we present the synthesis and characterisation of two thiophene-based macrocycles as well as their evaluation in organic-electronic devices. McT-1 is composed of ten thiophene moieties, whereas in McT-2, four additional electron-deficient benzothiadiazole moieties are incorporated to form a donor–acceptor (D–A) π-system. Red-shifted and broadened absorption spectra as well as more positive redox potentials are observed in McT-2, whereas McT-1 displays a sharper absorption band with a higher extinction coefficient. Macrocycle McT-1 shows emission in the yellow region whereas McT-2 displays emission in the red wavelength region. DFT calculations predict the macrocycles to comprise of mainly the E,E isomers with a near-planar structure, which is further supported by the single crystal X-ray structure for McT-1. Their charge transporting properties are determined by fabricating thin-film OFETs. The photovoltaic properties of McT-1 and McT-2 are also investigated by fabricating bulk heterojunction (BHJ) devices and their potential as photodetectors has been evaluated.Publisher PDFPeer reviewe

Forecasting incidence of tuberculosis cases in Brazil based on various univariate time-series models

Tuberculosis (TB) remains the world\u27s deadliest infectious disease and is a serious public health problem. Control for this disease still presents several difficulties, requiring strategies for the execution of immediate combat and intervention actions. Given that changes through the decision-making process are guided by current information and future prognoses, it is critical that a country\u27s public health managers rely on accurate predictions that can detect the evolving incidence phenomena. of TB. Thus, this study aims to analyze the accuracy of predictions of three univariate models based on time series of diagnosed TB cases in Brazil, from January 2001 to June 2018, in order to establish which model presents better performance. For the second half of 2018. From this, data were collected from the Department of Informatics of the Unified Health System (DATASUS), which were submitted to the methods of Simple Exponential Smoothing (SES), Holt-Winters Exponential Smoothing (HWES) and the Integrated Autoregressive Moving Average (ARIMA) model. In the performance analysis and model selection, six criteria based on precision errors were established: Mean Square Error (MSE), Root Mean Square Error (RMSE), Mean Absolute Error (MAE), Mean Absolute Percent Error (MAPE) and Theil\u27s U statistic (U1 and U2). According to the results obtained, the HWES (0.2, 0.1, 0.1) presented a high performance in relation to the error metrics, consisting of the best model compared to the other two methodologies compared here

Efeitos da terapia a laser de baixa potência em pacientes com neuralgia trigeminal / Effects of low power laser therapy in patients with trigeminal neuralgia

A neuralgia do trigêmeo (TN) consiste em dores recorrentes, agudas, semelhantes à uma descarga elétrica que perpassa pelos ramos do nervo trigêmeo, sendo sentida nos olhos, lábios, nariz, testa e mandíbula. Evidências atuais afirmam que a terapia a laser de baixo nível (LLLT) pode alterar a função celular e tecidual por meio da radiação com luz monocromática e outras configurações específicas do laser, promovendo efeitos analgésicos e anti-inflamatórios. A presente pesquisa tem por objetivo verificar a efetividade clínica da terapia com laser de baixa potência em pacientes com neuralgia trigeminal. Realizou-se uma busca nas plataformas bibliográficas Scielo, PubMed, BVS e Science Direct entre os anos de 2011 a 2021. Foram encontrados 146 artigos e apenas 5 atenderam os requisitos da pesquisa. Os ramos trigeminais frequentemente afetados, em maior quantidade, são o maxilar ou mandibular, na qual a dor começa depois da estimulação dos pontos-gatilho, em práticas rotineiras como falar e mastigar. Nesse ínterim, a LLLT baseia seus efeitos na melhora da função celular em nível mitocondrial, aumentando os níveis de serotonina, beta endorfina, a síntese de colágeno, o trifosfato de adenosina (ATP), as encefalinas e, principalmente, o limiar de dor. Bem como atua na redução de histaminas, acetilcolina, bradicinina, prostaglandinas e substância P. Além disso, a LLLT é um tratamento não invasivo e não farmacológico com efeitos adversos mínimos. Constatou-se o aumento das evidências a favor da terapia com laser de baixa potência referentes à redução dos níveis de inflamação e dor, contribuindo para a redução da sintomatologia causada pela neuralgia trigeminal

LIME -- a gas TPC prototype for directional Dark Matter search for the CYGNO experiment

The CYGNO experiment aims at the development of a large gaseous TPC with GEM-based amplification and an optical readout by means of PMTs and scientific CMOS cameras for 3D tracking down to O(keV) energies, for the directional detection of rare events such as low mass Dark Matter and solar neutrino interactions. The largest prototype built so far towards the realisation of the CYGNO experiment demonstrator is the 50 L active volume LIME, with 4 PMTs and a single sCMOS imaging a 33$\times$33 cm\textsuperscript{2} area for 50 cm drift, that has been installed in underground Laboratori Nazionali del Gran Sasso in February 2022. We will illustrate LIME performances as evaluated overground in Laboratori Nazionali di Frascati by means of radioactive X-ray sources, and in particular the detector stability, energy response and energy resolution. We will discuss the MC simulation developed to reproduce the detector response and show the comparison with actual data. We will furthermore examine the background simulation worked out for LIME underground data taking and illustrate the foreseen expected measurement and results in terms of natural and materials intrinsic radioactivity characterisation and measurement of the LNGS underground natural neutron flux. The results that will be obtained by underground LIME installation will be paramount in the optimisation of the CYGNO demonstrator, since this is foreseen to be composed by multiple modules with the same LIME dimensions and characteristics

Technical Design Report - TDR CYGNO-04/INITIUM

The aim of this Technical Design Report is to illustrate the technological choices foreseen to be implemented in the construction of the CYGNO-04 demonstrator, motivate them against the experiment physics goals of CYGNO-30 and demonstrate the financial sustainability of the project. CYGNO-04 represents PHASE 1 of the long term CYGNO roadmap, towards the development of large high precision tracking gaseous Time Projection Chamber (TPC) for directional Dark Matter searches and solar neutrino spectroscopy. The CYGNO project1 peculiarities reside in the optical readout of the light produced during the amplification of the primary ionization electrons in a stack of triple Gas Electron Multipliers (GEMs), thanks to the nice scintillation properties of the chosen He:CF4 gas mixture. To this aim, CYGNO is exploiting the fast progress in commercial scientific Active Pixel Sensors (APS) development for highly performing sCMOS cameras, whose high granularity and sensitivity allow to significantly boost tracking, improve particle identification and lower the energy threshold. The X-Y track project obtained from the reconstruction of the sCMOS images is combined with a PMT measurement to obtain a full 3D track reconstruction. In addition, several synergic R&Ds based on the CYGNO experimental approach are under development in the CYGNO collaboration (see Sec 2) to further enhance the light yield by means of electro luminescence after the amplification stage, to improve the tracking performances by exploiting negative ion drift operation within the INITIUM ERC Consolidator Grant, and to boost the sensitivity to O(GeV) Dark Matter masses by employing hydrogen rich target towards the development of PHASE 2 (see Sec. 1.2). While still under optimization and subject to possible significant improvements, the CYGNO experimental approach performances and capabilities demonstrated so far with prototypes allow to foresee the development of an O(30) m3 experiment by 2026 for a cost of O(10) MEUROs. A CYGNO-30 experiment would be able to give a significant contribution to the search and study of Dark Matter with masses below 10 GeV/c2 for both SI and SD coupling. In case of a Dark Matter observation claim by other experiments, the information provided by a directional detector such as CYGNO would be fundamental to positively confirm the galactic origin of the allegedly detected Dark Matter signal. CYGNO-30 could furthermore provide the first directional measurement of solar neutrinos from the pp chain, possibly extending to lower energies the Borexino measurement2. In order to reach this goal, the CYGNO project is proceeding through a staged approach. The PHASE 0 50 L detector (LIME, recently installed underground LNGS) will validate the full performances of the optical readout via APS commercial cameras and PMTs and the Montecarlo simulation of the expected backgrounds. The full CYGNO-04 demonstrator will be realized with all the technological and material choices foreseen for CYGNO-30, to demonstrate the scalability of the experimental approach and the potentialities of the large PHASE 2 detector to reach the expected physics goals. The first PHASE 1 design anticipated a 1 m3 active volume detector with two back-to-back TPCs with a central cathode and 500 mm drift length. Each 1 m2 readout area would have been composed by 9 + 9 readout modules having the LIME PHASE 0 dimensions and layout. Time (end of INITIUM project by March 2025) and current space availability at underground LNGS (only Hall F) forced the rescaling of the PHASE 1 active volume and design to a 0.4 m3, hence CYGNO-04. CYGNO-04 will keep the back-to-back double TPC layout with 500 mm drift length each, but with an 800 x 500 mm2 readout area covered by a 2 + 2 modules based on LIME design. The reduction of the detector volume has no impact on the technological objectives of PHASE 1, since the modular design with central cathode, detector materials and shieldings and auxiliary systems are independent of the total volume. The physics reach (which is a byproduct of PHASE 1 and NOT an explicit goal) will be only very partially reduced (less than a factor 2 overall) since a smaller detector volume implies also a reduced background from internal materials radioactivity. In addition, the cost reduction of CYGNO-04 of about 1⁄3 with respect to CYGNO-1 illustrated in the CDR effectively makes the overall project more financially sustainable (see CBS in the last section). In summary this document will explain: the physical motivation of the CYGNO project and the technical motivations of the downscale of the PHASE 1 to CYGNO-04, 400 liters of active volume, with respect to the demonstrator presented in the CDR; the results of R&D and the Montecarlo expectations for PHASE 0; the technical choices, procedures and the executive drawings of CYGNO-04 in the Hall F of the LNGS; safety evaluations and the interference/request to the LNGS services; Project management, WBS/WBC, WP, GANTT, ec