Thermodynamic and rheological properties of rhyolite and andesite melts

The heat capacities of a rhyolite and an andesite glass and liquid have been investigated from relative-enthalpy measurements made between 400 and 1800 K. For the glass phases, the experimental data agree with empirical models of calculation of the heat capacity. For the liquid phases, the agreement is less good owing to strong interactions between alkali metals and aluminum, which are not currently accounted for by empirical heat capacity models. The viscosity of both liquids has been measured from the glass transition to 1800 K. The temperature dependence of the viscosity is quantitatively related to the configurational heat capacity (determined calorimetrically) through the configurational entropy theory of relaxation processes. For both rhyolite and andesite melts, the heat capacity and viscosity do not differ markedly from those obtained by additive modeling from components with mineral compositions

Thermodynamic and rheological properties of rhyolite and andesite melts

The heat capacities of a rhyolite and an andesite glass and liquid have been investigated from relative-enthalpy measurements made between 400 and 1800 K. For the glass phases, the experimental data agree with empirical models of calculation of the heat capacity. For the liquid phases, the agreement is less good owing to strong interactions between alkali metals and aluminum, which are not currently accounted for by empirical heat capacity models. The viscosity of both liquids has been measured from the glass transition to 1800 K. The temperature dependence of the viscosity is quantitatively related to the configurational heat capacity (determined calorimetrically) through the configurational entropy theory of relaxation processes. For both rhyolite and andesite melts, the heat capacity and viscosity do not differ markedly from those obtained by additive modeling from components with mineral compositions

Estimating Dynamic Gait Stability Using Data from Non-aligned Inertial Sensors

Recently, two methods for quantifying the stability of a dynamical system have been applied to human locomotion: local stability (quantified by finite time maximum Lyapunov exponents, λs and λL) and orbital stability (quantified by maximum Floquet multipliers, MaxFm). In most studies published to date, data from optoelectronic measurement systems were used to calculate these measures. However, using wireless inertial sensors may be more practical as they are easier to use, also in ambulatory applications. While inertial sensors have been employed in some studies, it is unknown whether they lead to similar stability estimates as obtained with optoelectronic measurement systems. In the present study, we compared stability measures of human walking estimated from an optoelectronic measurement system with those calculated from an inertial sensor measurement system. Subjects walked on a treadmill at three different speeds while kinematics were recorded using both measurement systems. From the angular velocities and linear accelerations, λs, λL, and MaxFm were calculated. Both measurement systems showed the same effects of walking speed for all variables. Estimates from both measurement systems correlated high for λs and λL, (R > 0.85) but less strongly for MaxFm (R = 0.66). These results indicate that inertial sensors constitute a valid alternative for an optoelectronic measurement system when assessing dynamic stability in human locomotion, and may thus be used instead, which paves the way to studying gait stability during natural, everyday walking

Crystal plasticity as an indicator of the viscous-brittle transition in magmas

Understanding the flow of multi-phase (melt, crystals and bubbles) magmas is of great importance for interpreting eruption dynamics. Here we report the first observation of crystal plasticity, identified using electron backscatter diffraction, in plagioclase in andesite dome lavas from Volcán de Colima, Mexico. The same lavas, deformed experimentally at volcanic conduit temperature and load conditions, exhibit a further, systematic plastic response in the crystalline fraction, observable as a lattice misorientation. At higher stress, and higher crystal fraction, the amount of strain accommodated by crystal plasticity is larger. Crystal plastic distortion is highest in the intact segments of broken crystals, which have exceeded their plastic limit. We infer that crystal plasticity precludes failure and can punctuate the viscous-brittle transition in crystal-bearing magmas at certain shallow magmatic conditions. Since crystal plasticity varies systematically with imposed conditions, this raises the possibility that it may be used as a strain marker in well-constrained systems

Rhythmic dynamics and synchronization via dimensionality reduction : application to human gait

Reliable characterization of locomotor dynamics of human walking is vital to understanding the neuromuscular control of human locomotion and disease diagnosis. However, the inherent oscillation and ubiquity of noise in such non-strictly periodic signals pose great challenges to current methodologies. To this end, we exploit the state-of-the-art technology in pattern recognition and, specifically, dimensionality reduction techniques, and propose to reconstruct and characterize the dynamics accurately on the cycle scale of the signal. This is achieved by deriving a low-dimensional representation of the cycles through global optimization, which effectively preserves the topology of the cycles that are embedded in a high-dimensional Euclidian space. Our approach demonstrates a clear advantage in capturing the intrinsic dynamics and probing the subtle synchronization patterns from uni/bivariate oscillatory signals over traditional methods. Application to human gait data for healthy subjects and diabetics reveals a significant difference in the dynamics of ankle movements and ankle-knee coordination, but not in knee movements. These results indicate that the impaired sensory feedback from the feet due to diabetes does not influence the knee movement in general, and that normal human walking is not critically dependent on the feedback from the peripheral nervous system

The rheological response of magma to nanolitisation

Viscosity exerts a fundamental control on magmatic kinetics and dynamics, controlling magma ascent, eruptive style, and the emplacement of lava. Nanolites – crystals smaller than a micron – are thought to affect magma viscosity, but the underlying mechanisms for this remain unclear. Here, we use a cylinder compression creep technique to measure the viscosity of supercooled silicate liquids with different amounts of iron (0–20 wt% FeOtot) as a function of temperature, applied shear stress, and time. Sample viscosity was independent on the applied shear stresses, and as expected, melt viscosity decreases as temperature is increased, but only until a critical temperature where a time-dependent increase in viscosity occurs for samples contaning 6.0 wt% FeOtot or more. The magnitude of this increase is controlled by the melt iron content. At constant temperature, these changes are substantial and can reach up to three orders of magnitude for the sample with the most iron. Using transmission electron microscopy, X-ray diffraction, and viscosity modelling, we conclude that this viscosity increase is caused by the formation of nanolites. By using scaling approaches to test suspension effects with and without crystal aggregation, we conclude that the nanolites have only a minimal direct physical effect on the observed viscosity change. Rather, our models show that it is the chemical shift in the groundmass silicate melt composition associated with non-stoichiometric crystallisation that dominates the observed viscosity increase. These findings suggest that iron-rich silicates may encounter chemical viscosity jumps once certain elements are removed from the melt phase to form nanolites. Our work demonstrates an underlying mechanism for the role played by nanolites in viscosity changes of magmas

Dynamic buckling and fragmentation in brittle rods

We present experiments on the dynamic buckling and fragmentation of slender rods axially impacted by a projectile. By combining the results of Saint-Venant and elastic beam theory, we derive a preferred wavelength lambda for the buckling instability, and experimentally verify the resulting scaling law for a range of materials including teflon, dry pasta, glass, and steel. For brittle materials, buckling leads to the fragmentation of the rod. Measured fragment length distributions show two clear peaks near lambda/2 and lambda/4. The non-monotonic nature of the distributions reflect the influence of the deterministic buckling process on the more random fragmentation processes.Comment: 4 pages, 5 figures, submitted to Physical Review Letter

Pre‐Eruptive Outgassing and Pressurization, and Post‐Fragmentation Bubble Nucleation, Recorded by Vesicles in Breadcrust Bombs From Vulcanian Activity at Guagua Pichincha Volcano, Ecuador

Breadcrust bombs formed during Vulcanian eruptions are assumed to originate from the shallow plug or dome. Their rim to core texture reflects the competition between cooling and degassing timescales, which results in a dense crust with isolated vesicles contrasting with a highly vesicular vesicle network in the interior. Due to relatively fast quenching, the crust can shed light on pre- and syn-eruptive conditions prior to or during fragmentation, whereas the interior allows us to explore post-fragmentation vesiculation. Investigation of pre- to post-fragmentation processes in breadcrust bombs from the 1999 Vulcanian activity at Guagua Pichincha, Ecuador, via 2D and 3D textural analysis reveals a complex vesiculation history, with multiple, spatially localized nucleation and growth events. Large vesicles (Type 1), present in low number density in the crust, are interpreted as pre-eruptive bubbles formed by outgassing and collapse of a permeable bubble network during ascent or stalling in the plug. Haloes of small, syn-fragmentation vesicles (Type 2), distributed about large vesicles, are formed by pressurization and enrichment of volatiles in these haloes. The nature of the pressurization process in the plug is discussed in light of seismicity and ground deformation signals, and previous textural and chemical studies. A third population (Type 3) of post-fragmentation small vesicles appears in the interior of the bomb, and growth and coalescence of Type 2 and 3 vesicles causes the transition from isolated to interconnected bubble network in the interior. We model the evolution of viscosity, bubble growth rate, diffusion timescales, bubble radius and porosity during fragmentation and cooling. These models reveal that thermal quenching dominates in the crust whereas the interior undergoes a viscosity quench caused by degassing, and that the transition from crust to interior corresponds to the onset of percolation and development of permeability in the bubble network

Fluidal pyroclasts reveal the intensity of peralkaline rhyolite pumice cone eruptions

This work is a contribution to the Natural Environment Research Council (NERC) funded RiftVolc project (NE/L013932/1, Rift volcanism: past, present and future) through which several of the authors are supported. In addition, Clarke was funded by a NERC doctoral training partnership grant (NE/L002558/1).Peralkaline rhyolites are medium to low viscosity, volatile-rich magmas typically associated with rift zones and extensional settings. The dynamics of peralkaline rhyolite eruptions remain elusive with no direct observations recorded, significantly hindering the assessment of hazard and risk. Here we describe uniquely-preserved, fluidal-shaped pyroclasts found within pumice cone deposits at Aluto, a peralkaline rhyolite caldera in the Main Ethiopian Rift. We use a combination of field-observations, geochemistry, X-ray computed microtomography (XCT) and thermal-modelling to investigate how these pyroclasts are formed. We find that they deform during flight and, depending on size, quench prior to deposition or continue to inflate then quench in-situ. These findings reveal important characteristics of the eruptions that gave rise to them: that despite the relatively low viscosity of these magmas, and similarities to basaltic scoria-cone deposits, moderate to intense, unstable, eruption columns are developed; meaning that such eruptions can generate extensive tephra-fall and pyroclastic density currents.Publisher PDFPeer reviewe

Effects of an attention demanding task on dynamic stability during treadmill walking

<p>Abstract</p> <p>Background</p> <p>People exhibit increased difficulty balancing when they perform secondary attention-distracting tasks while walking. However, a previous study by Grabiner and Troy (<it>J. Neuroengineering Rehabil</it>., 2005) found that young healthy subjects performing a concurrent Stroop task while walking on a motorized treadmill exhibited <it>decreased </it>step width variability. However, measures of variability do not directly quantify how a system responds to perturbations. This study re-analyzed data from Grabiner and Troy 2005 to determine if performing the concurrent Stroop task directly affected the dynamic stability of walking in these same subjects.</p> <p>Methods</p> <p>Thirteen healthy volunteers walked on a motorized treadmill at their self-selected constant speed for 10 minutes both while performing the Stroop test and during undisturbed walking. This Stroop test consisted of projecting images of the name of one color, printed in text of a different color, onto a wall and asking subjects to verbally identify the color of the text. Three-dimensional motions of a marker attached to the base of the neck (C5/T1) were recorded. Marker velocities were calculated over 3 equal intervals of 200 sec each in each direction. Mean variability was calculated for each time series as the average standard deviation across all strides. Both "local" and "orbital" dynamic stability were quantified for each time series using previously established methods. These measures directly quantify how quickly small perturbations grow or decay, either continuously in real time (local) or discretely from one cycle to the next (orbital). Differences between Stroop and Control trials were evaluated using a 2-factor repeated measures ANOVA.</p> <p>Results</p> <p>Mean variability of trunk movements was significantly reduced during the Stroop tests compared to normal walking. Conversely, local and orbital stability results were mixed: some measures showed slight increases, while others showed slight decreases. In many cases, different subjects responded differently to the Stroop test. While some of our comparisons reached statistical significance, many did not. In general, measures of variability and dynamic stability reflected different properties of walking dynamics, consistent with previous findings.</p> <p>Conclusion</p> <p>These findings demonstrate that the decreased movement variability associated with the Stroop task did <it>not </it>translate to greater dynamic stability.</p