Improving the functional properties of (K0.5Na0.5)NbO3 piezoceramics by acceptor doping

ZrO2 and TiO2 modified lead-free (K0.5Na0.5)NbO3 (KNN) piezoelectric ceramics are prepared by a conventional solid-state reaction. The effect of acceptor doping on structural and functional properties is investigated. A decrease in the Curie temperature and an increase in the dielectric constant values are observed when doping. More interestingly, an increase in the coercive field E-c and remanent polarization P-r is observed. The piezoelectric properties are greatly increased when doping with small concentrations dopants. ZrO2 doped ceramic exhibits good piezoelectric properties with piezoelectric coefficient d(33) = 134 pC/N and electromechanical coupling factor k(p) = 35%. It is verified that nonlinearity is significantly reduced. Thus, the creation of complex defects capable of pinning the domain wall motion is enhanced with doping, probably due to the formation of oxygen vacancies. These results strongly suggest that compositional engineering using low concentrations of acceptor doping is a good means of improving the functional properties of KNN lead-free piezoceramic system. (C) 2014 Elsevier Ltd. All rights reserved.Postprint (published version

High-precision time-of-flight determination algorithm for ultrasonic flow measurement

© 2019 IEEE. Personal use of this material is permitted. Permission from IEEE must be obtained for all other uses, in any current or future media, including reprinting/republishing this material for advertising or promotional purposes,creating new collective works, for resale or redistribution to servers or lists, or reuse of any copyrighted component of this work in other works.Commercial time-of-flight (TOF) ultrasonic flowme- ters are rapidly expanding in the general industry. Among the different techniques that can be applied to determine the TOF of ultrasonic waves, the cross-correlation method presents numerous advantages, such as robustness for weak signals and noise suppression. However, the selection of an appropriate reference wave is presumably a key element in the precise measurement of TOF. In the present paper, an algorithm to compute an accurate TOF is proposed. The form of the electric signal received by the transducer is obtained from an acoustically-forced underdamped oscillator model, and the analytical solution of the model is proposed as a reference wave. In order to validate the effectiveness of this procedure, an ultrasonic flowmeter system is designed and tested in a flowmeter calibration test rig. It is demonstrated that the use of the presented scheme overcome the average method limitations, and turns out to be a convenient solution in a wide range of conditions. Robust measurements of near-zero flow values are acquired, which allow the achievement of a high dynamic range. The error curve of the proposed system have been obtained, revealing that the absolute value of the relative errors are lower than 2% within all the spectrum of flow rates considered (from 0.2 to 150 m 3 /h). Results demonstrate that the algorithm provides high-precision measurements within a wide dynamic range. The algorithm is portable and versatile: it can be adapted to different types of transducers without the need of additional measurements, allowing to adjust parameters on-the-fly for an optimal performance of the ultrasonic flowmeter system.Peer ReviewedPostprint (author's final draft

The Area and Population of Cities: New Insights from a Different Perspective on Cities

The distribution of the population of cities has attracted a great deal of attention, in part because it sharply constrains models of local growth. However, to this day, there is no consensus on the distribution below the very upper tail, because available data need to rely on the “legal” rather than “economic” definition of cities for medium and small cities. To remedy this difficulty, in this work we construct cities “from the bottom up” by clustering populated areas obtained from high-resolution data. This method allows us to investigate the population and area of cities for urban agglomerations of all sizes. We find that Zipf’s law (a power law with exponent close to 1) for population holds for cities as small as 12,000 inhabitants in the USA and 5,000 inhabitants in Great Britain. In addition the distribution of city areas is also close to a Zipf’s law. We provide a parsimonious model with endogenous city area that is consistent with those findings.

Microstructure and Defect Formation in BaTiO3 Ceramics Obtained by Flash Sintering of Micro and Nanopowders

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Análisis multidimensional de la estructura de las rutinas competitivas en natación sincronizada

El objetivo de este estudio fue caracterizar la estructura de las rutinas de solo y dúo de natación sincronizada. Para ello se utilizó un diseño observacional puntual, nomotético y multidimensional. El instrumento observacional ad hoc fue validado por 12 especialistas. Se utilizó como instrumento de registro el programa LINCE. La fiabilidad en la observación se determinó mediante el grado de concordancia intra e interobservador. Dieciocho nadadoras (seis medallistas olímpicas) participaron en el estudio. Se analizaron 39 rutinas: solo técnico (n = 9), solo libre (n = 11), dúo técnico (n = 10) y dúo libre (n = 9). El 61.6 ± 6.4 %) del tiempo de competición las nadadoras estaban con la cara dentro del agua, con apneas máximas de 21.1 ± 4.0 s. La posición más utilizada en el conjunto de rutinas fue la inferior (43.2 ± 5.3 %), siendo la fase de inmersión alta inferior la más reproducida (35.3 ± 5.0 %). En conclusión: 1) se dispone de una herramienta válida para el análisis de la estructura de las rutinas en natación sincronizada, 2) existen diferencias significativas en la estructura de las rutinas atendiendo a la duración total, las fases relativas de apnea y a la inmersión en distintas posiciones corporales.The aim of this study was to characterize the structure of solo and duet-based synchronized swimming routines. This was done using a specific nomothetic multidimensional observational design. The ad hoc observational instrument was validated by 12 specialists. The data was recorded using LINCE software, and observational reliability was determined by calculating the degree of intra-observer and inter-observer agreement. The participants were 18 female swimmers (including six Olympic medallists), and 39 routines were analysed: technical solos (n = 9), free solos (n = 11), technical duets (n = 10) and free duets (n = 9). The swimmers spent 61.6 ± 6.4 % of the competition time with their faces immersed in the water, with maximum apnea of 21.1 ± 4.0 s. The inverted-vertical position was the most widely taken in routines (43.2 ± 5.3 %), with the phase of deep immersion in that position being the most commonly reproduced (35.3 ± 5.0 %). In conclusion: 1) the observational instrument is a valid tool for analysing the structure of routines in synchronized swimming; and 2) there are significant differences in the structure of routines as regards their total duration, episodes of apnea, and the degree of immersion in different body positions.O objectivo deste estudo foi caracterizar a estrutura das rotinas individuais e duplas de natação sincronizada. Para tal foi utilizado um delineamento observacional pontual, nomotético e multidimensional. O instrumento observacional ad hoc foi validado por 12 especialistas. Utilizou-se como instrumento de registo o programa LINCE. A fidelidade na observação foi determinada mediante o grau de concordância intra e interobservador. Dezoito nadadoras (seis medalhistas olímpicas) participaram no estudo. Foram analisadas 39 rotinas; solo técnico (n = 9), solo livre (n = 11), duo técnico (n = 10) e duo livre (n = 9). As nadadoras estavam totalmente imersas na água em 61.6 % (± 6.4 %) do tempo de competição, com apneias máximas de 21.1 ± 4.0 s. A posição mais utilizada no conjunto de rotinas foi a imersão inferior (43.2 ± 5.3 %), sendo a fase de imersão total a mais reproduzida (35.3 ± 5.0 %). Em suma: 1) dispõem-se de uma ferramenta válida para a análise da estructura das rotinas na natação sincronizada, 2) existem diferenças significativas na estructura das rotinas atendendo à duração total, às fases relativas de apneia e à imersão em distintas posições corporais

Enhancement of piezoelectric properties stability of submicron-structured piezoceramics obtained by spark plasma sintering

Grain-size effect on functional properties of piezoceramics is nowadays an important topic due to the potential applications of these materials at the submicron scale. In this context, we explore the effect of the grain size reduction on the functional properties stability of piezoceramics. Submicron- and micro-structured Pb(Zr,Ti)O3-based materials are taken as model samples to carry out this study. Rayleigh analysis is used to quantitatively evaluate the domain wall contribution. The results show that the stability of properties depends strongly on grain size. Specifically, the nonlinear response decreases significantly when the grain size is reduced to the submicron scale. This behavior can be explained by taking into account that a grain size reduction involves a grain boundary increment, which may clamp domain walls. The results suggest that grain size engineering may be an effective alternative to the widely used compositional engineering in order to control the undesirable nonlinear behavior in piezoceramics.Postprint (author's final draft

Tailoring the microstructure by a proper electric current control in flash sintering: The case of barium titanate

Flash sintering is arousing growing interest because high-density ceramics can be obtained at lower temperatures and shorter dwell times than conventional sintering. However, not only temperature and dwell times should be controlled during flash sintering but also parameters such as the electric field and electric current should be considered. Controlling all the parameters during the processing allows comprehensive control of the microstructure and, consequently, functional properties can be improved. In this work, it is evidenced that an exhaustive control of the flash electric current is a crucial factor for tailoring the microstructure of BaTiO3 ceramics. The results reveal that the most suitable way to control the sintering process is by using non-linear current profiles because better densification and improved grain growth is achieved. Although the results focus on BaTiO3, this work offers a new pathway to tailor the microstructure of flash sintered ceramics, which may be extended to other materials.Peer ReviewedPostprint (published version

Tailoring the microstructure by a proper electric current control in flash sintering: The case of barium titanate

Flash sintering is arousing growing interest because high-density ceramics can be obtained at lower temperatures and shorter dwell times than conventional sintering. However, not only temperature and dwell times should be controlled during flash sintering but also parameters such as the electric field and electric current should be considered. Controlling all the parameters during the processing allows comprehensive control of the microstructure and, consequently, functional properties can be improved. In this work, it is evidenced that an exhaustive control of the flash electric current is a crucial factor for tailoring the microstructure of BaTiO3 ceramics. The results reveal that the most suitable way to control the sintering process is by using nonlinear current profiles because better densification and improved grain growth is achieved. Although the results focus on BaTiO3, this work offers a new pathway to tailor the microstructure of flash sintered ceramics, which may be extended to other materials

Particle size effect on the microstructure and the aging process of flash-sintered barium titanate from micro and nanopowders

Flash sintering is a novel sintering technique that allows high-density ceramics to be obtained at lowtemperatures and using short dwell times, thus providing an energy-efficient alternative to conventionalsintering. The microstructure of flash-sintered samples can be fine-tuned by a proper control ofelectrical parameters such as current density, electric field, and current profile, yielding significantimprovements of functional properties. The starting powder should also be carefully selected sincebetter sintering results are reported for smaller green grain sizes. However, this work evidences timeevolution of electrical properties of flash-sintered BaTiO3 ceramics from submicron powders. Theresults reveal that these transformations greatly depend on powder grain size and can be furtheradjusted with an adequate selection of electric power profiles. This work provides new insights intoongoing phenomena during field-assisted sintering, such as grain growth and defect formationdynamics. Although the results focus on BaTiO3, it offers a new pathway to tailor the microstructure offlash-sintered ceramics, which may be extended to other electronic materials