414 research outputs found

    A possible mechanism for the capture of microparticles by the earth and other planets of the solar system

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    By application of Lyttleton's theory for the formation of comets, it is shown that a possible mechanism for the origin and formation of a concentration of cosmic particles around the earth and the other planets of the solar system exists. In the vicinity of the neutral point, where the velocity of colliding particles is not greater than 6 km/s, it is found that if the solid particles after collision must remain in a solid state, there can be no possibility of accretion for Mercury, Mars, and the Moon, where the maximum value of the distance of the center of the planet to the asymptotic trajectory is less than the radius of the planet. On the other hand, the capture radii of microparticles in solid form varies from a minimum of 2.95 planetary radii for Venus and 3.47 for the Earth, to about 986 for Jupiter

    Parallel Exhaustive Search without Coordination

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    We analyze parallel algorithms in the context of exhaustive search over totally ordered sets. Imagine an infinite list of "boxes", with a "treasure" hidden in one of them, where the boxes' order reflects the importance of finding the treasure in a given box. At each time step, a search protocol executed by a searcher has the ability to peek into one box, and see whether the treasure is present or not. By equally dividing the workload between them, kk searchers can find the treasure kk times faster than one searcher. However, this straightforward strategy is very sensitive to failures (e.g., crashes of processors), and overcoming this issue seems to require a large amount of communication. We therefore address the question of designing parallel search algorithms maximizing their speed-up and maintaining high levels of robustness, while minimizing the amount of resources for coordination. Based on the observation that algorithms that avoid communication are inherently robust, we analyze the best running time performance of non-coordinating algorithms. Specifically, we devise non-coordinating algorithms that achieve a speed-up of 9/89/8 for two searchers, a speed-up of 4/34/3 for three searchers, and in general, a speed-up of k4(1+1/k)2\frac{k}{4}(1+1/k)^2 for any k1k\geq 1 searchers. Thus, asymptotically, the speed-up is only four times worse compared to the case of full-coordination, and our algorithms are surprisingly simple and hence applicable. Moreover, these bounds are tight in a strong sense as no non-coordinating search algorithm can achieve better speed-ups. Overall, we highlight that, in faulty contexts in which coordination between the searchers is technically difficult to implement, intrusive with respect to privacy, and/or costly in term of resources, it might well be worth giving up on coordination, and simply run our non-coordinating exhaustive search algorithms

    Synthesis and characterization of p-n junction ternary mixed oxides for photocatalytic coprocessing of CO2 and H2O

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    In the present paper, we report the synthesis and characterization of both binary (Cu2 O, Fe2 O3, and In2 O3 ) and ternary (Cu2 O-Fe2 O3 and Cu2 O-In2 O3 ) transition metal mixed-oxides that may find application as photocatalysts for solar driven CO2 conversion into energy rich species. Two different preparation techniques (High Energy Milling (HEM) and Co-Precipitation (CP)) are compared and materials properties are studied by means of a variety of characterization and analytical techniques UV-Visible Diffuse Reflectance Spectroscopy (UV-VIS DRS), X-ray Photoelectron Spectroscopy (XPS), X-Ray Diffraction (XRD), Transmission Electron Microscopy (TEM), and Energy Dispersive X-Ray spectrometry (EDX). Appropriate data elaboration methods are used to extract materials bandgap for Cu2 O@Fe2 O3 and Cu2 O@In2 O3 prepared by HEM and CP, and foresee whether the newly prepared semiconductor mixed oxides pairs are useful for application in CO2-H2 O coprocessing. The experimental results show that the synthetic technique influences the photoactivity of the materials that can correctly be foreseen on the basis of bandgap experimentally derived. Of the mixed oxides prepared and described in this work, only Cu2 O@In2 O3 shows positive results in CO2-H2 O photo-co-processing. Preliminary results show that the composition and synthetic methodologies of mixed-oxides, the reactor geometry, the way of dispersing the photocatalyst sample, play a key role in the light driven reaction of CO2 –H2 O. This work is a rare case of full characterization of photo-materials, using UV-Visible DRS, XPS, XRD, TEM, EDX for the surface and bulk analytical characterization. Surface composition may not be the same of the bulk composition and plays a key role in photocatalysts behavior. We show that a full material knowledge is necessary for the correct forecast of their photocatalytic behavior, inferred from experimentally determined bandgaps

    Selective Aerobic Oxidation of 5-Hydroxymethylfurfural to 2,5-Diformylfuran or 2-Formyl-5-furancarboxylic Acid in Water by using MgO⋅CeO2 Mixed Oxides as Catalysts

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    Mixed oxides based on MgO⋅CeO2 were used as efficient catalysts in the aerobic oxidation of 5-hydroxymethylfurfural (5-HMF) to afford, with very high selectivity, either 2,5-diformylfuran (DFF, 99 %) or 2-formyl-5-furancarboxylic acid (FFCA, 90 %), depending on the reaction conditions. 5-Hydroxymethyl-2-furancarboxylic acid (HMFCA, 57–90 %) was formed only at low concentration of 5-HMF (<0.03 m) or in presence of external bases. The conversion of 5-HMF ranged from a few percent to 99 %, according to the reaction conditions. The oxidation was performed in water, with O2 as oxidant, without any additives. The surface characterization of the catalysts gave important information about their acid–base properties, which drive the selectivity of the reaction towards DFF. FFCA was formed from DFF at longer reaction times. Catalysts were studied by XPS and XRD before and after catalytic runs to identify the reason why they undergo reversible deactivation. XRD showed that MgO is hydrated to Mg(OH)2, which, even if not leached out, changes the basic properties of the catalyst that becomes less active after some time. Calcination of the recovered catalyst allows recovery of its initial activity. The catalyst is thus recoverable (>99 %) and reusable. The use of mixed oxides allows tuning of the basicity of the catalysts, avoiding the need for external bases for efficient and selective conversion of 5-HMF and waste formation, resulting in an environmentally friendly, sustainable process

    Opto‐Electronic Characterization of Photocatalysts Based on p,n‐Junction Ternary and Quaternary Mixed Oxides Semiconductors (Cu2O‐In2O3 and Cu2O‐In2O3‐TiO2)

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    Semiconductor materials are the basis of electronic devices employed in the communication and media industry. In the present work, we report the synthesis and characterization of mixed metal oxides (MOs) as p,n‐junction photocatalysts, and demonstrate the correlation between the preparation technique and the properties of the materials. Solid‐state UV-visible diffuse reflectance spectroscopy (UV‐VIS DRS) allowed for the determination of the light absorption properties and the optical energy gap. X‐ray photoelectron spectroscopy (XPS) allowed for the determination of the surface speciation and composition and for the determination of the valence band edge. The opto‐electronic behavior was evaluated measuring the photocurrent generated after absorption of chopped visible light in a 3‐electrode cell. Scanning electron microscopy (SEM) measurements allowed for auxiliary characterization of size and morphology, showing the formation of composites for the ternary Cu2O‐In2O3 p,n‐mixed oxide, and even more for the quaternary Cu2O‐In2O3‐TiO2 MO. Light absorption spectra and photocurrent‐time curves mainly depend upon the composition of MOs, while the optical energy gap and defective absorption tail are closely related to the preparation methodology, time and thermal treatment. Qualitative electronic band structures of semiconductors are also presented

    Riesz potentials and nonlinear parabolic equations

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    The spatial gradient of solutions to nonlinear degenerate parabolic equations can be pointwise estimated by the caloric Riesz potential of the right hand side datum, exactly as in the case of the heat equation. Heat kernels type estimates persist in the nonlinear cas

    Modeling characterization of the vertical and temporal variability of environmental DNA in the mesopelagic ocean

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    © The Author(s), 2021. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Allan, E. A., DiBenedetto, M. H., Lavery, A. C., Govindarajan, A. F., & Zhang, W. G. Modeling characterization of the vertical and temporal variability of environmental DNA in the mesopelagic ocean. Scientific Reports, 11(1), (2021): 21273, https://doi.org/10.1038/s41598-021-00288-5.Increasingly, researchers are using innovative methods to census marine life, including identification of environmental DNA (eDNA) left behind by organisms in the water column. However, little is understood about how eDNA is distributed in the ocean, given that organisms are mobile and that physical and biological processes can transport eDNA after release from a host. Particularly in the vast mesopelagic ocean where many species vertically migrate hundreds of meters diurnally, it is important to link the location at which eDNA was shed by a host organism to the location at which eDNA was collected in a water sample. Here, we present a one-dimensional mechanistic model to simulate the eDNA vertical distribution after its release and to compare the impact of key biological and physical parameters on the eDNA vertical and temporal distribution. The modeled vertical eDNA profiles allow us to quantify spatial and temporal variability in eDNA concentration and to identify the most important parameters to consider when interpreting eDNA signals. We find that the vertical displacement by advection, dispersion, and settling has limited influence on the eDNA distribution, and the depth at which eDNA is found is generally within tens of meters of the depth at which the eDNA was originally shed from the organism. Thus, using information about representative vertical migration patterns, eDNA concentration variability can be used to answer ecological questions about migrating organisms such as what depths species can be found in the daytime and nighttime and what percentage of individuals within a species diurnally migrate. These findings are critical both to advance the understanding of the vertical distribution of eDNA in the water column and to link eDNA detection to organism presence in the mesopelagic ocean as well as other aquatic environments.This research is part of the Woods Hole Oceanographic Institution’s Ocean Twilight Zone project, funded as part of The Audacious Project housed at TED

    Pontryagin´s principle for state-constrained boundary control problems of semilinear parabolic equations

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    This paper deals with state-constrained optimal control problems governed by semilinear parabolic equations. We establish a minimum principle of Pontryagin's type. To deal with the state constraints, we introduce a penalty problem by using Ekeland's principle. The key tool for the proof is the use of a special kind of spike perturbations distributed in the domain where the controls are de ned. Conditions for normality of optimality conditions are given

    Large time behavior for a quasilinear diffusion equation with critical gradient absorption

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    International audienceWe study the large time behavior of non-negative solutions to thenonlinear diffusion equation with critical gradient absorption\partial_t u-\Delta_{p}u+|\nabla u|^{q_*}=0 \quad \hbox{in} \(0,\infty)\times\mathbb{R}^N\ ,for p(2,)p\in(2,\infty) and q:=pN/(N+1)q_*:=p-N/(N+1). We show that theasymptotic profile of compactly supported solutions is given by asource-type self-similar solution of the pp-Laplacian equation with suitable logarithmic time and space scales. In the process, we also get optimal decay rates for compactly supported solutions and optimal expansion rates for their supports that strongly improve previous results

    La paratubercolosi negli ovini e caprini I: prolegomeni allo studio delle cause predisponenti a questa malattia

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    La paratubercolosi, o enterite paratubercolare (conosciuta anche come malattia di Johne), è una patologia infettiva ad andamento cronico sostenuta da Mycobacterium avium subsp. paratuberculosis (MAP). È diffusa ovunque si pratichi l’allevamento ovino e caprino, rappresentando una delle malattie infettive più importanti per i danni arrecati agli allevamenti. Alla diffusione del MAP hanno contribuito specifici fattori gestionali, ma soprattutto la commercializzazione incontrollata di animali, con conseguente aumento dell’incidenza della malattia e prevalenza di allevamenti infetti ormai variabile tra il 7 ed il 60% su scala mondiale. In questo quadro si colloca il progetto PON “EpiSud-Programma per lo sviluppo di metodologie per l’identificazione ed il controllo di infezioni micobatteriche animali”, che vede il Parco Tecnologico Padano come proponente e l’Istituto Zooprofilattico della Sicilia nonché l’Università degli Studi di Bari Aldo Moro (DETO-Sez. Cliniche veterinarie e Produzioni Animali) in qualità di partner. L’Università di Bari, in particolare, sta conducendo un’indagine epidemiologica in Puglia su allevamenti estensivi ovini e caprini al fine di studiare la prevalenza della malattia ed i fattori di rischio scatenanti l’infezione in relazione alle pratiche gestionali adottate dagli allevatori. L’indagine è ancora in fieri ed è prematuro trarre conclusioni circa i dati epidemiologici; è tuttavia possibile, ancorché su dati parziali, avanzare ipotesi circa i fattori di rischio. Data la natura complessa di detti fattori, per l’analisi è stato scelto un approccio multivariato, cosicché nel presente lavoro si riportano i risultati dei primi dati raccolti mediante la somministrazione agli allevatori di un’apposita scheda aziendale, redatta al fine di reperire una serie di informazioni di carattere strutturale, igienico-sanitario e gestionale
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