Stand der Kenntnisse und Technik bezüglich Wasserstoffsicherheit

Die Einführung von Wasserstoff als sicherer Energieträger braucht eine robuste Wissensbasis, darauf aufgebaute Werkzeuge zur Auslegung und Sicherheitsbewertung von Wasserstofftechnologien und ein international harmonisiertes Regelwerk. Viele der innovativen Technologien implizieren Wasserstoff bei hohen Drücken und/oder kryogenen Temperaturen, mit denen in verteilten Anwendungen erstmalig private Nutzer in Kontakt kommen. Um überkonservative, teure Sicherheitslösungen zu vermeiden, gleichzeitig aber die Einsetzbarkeit und Sicherheit von Wasserstoffanwendungen zu demonstrieren und die Akzeptanz für die Technologie aufrecht zu halten, muss auch die Sicherheitsforschung mit den Trends der technologischen Entwicklung Schritt halten, oder sie besser noch antizipieren. So beschreibt dieser Überblicksartikel nicht nur den gegenwärtigen Stand der Kenntnisse und Technik bezüglich Wasserstoffsicherheit, sondern auch ihre Weiterentwicklung

Filled Carbon Nanotubes as Anode Materials for Lithium-Ion Batteries

Downsizing well-established materials to the nanoscale is a key route to novel functionalities, in particular if different functionalities are merged in hybrid nanomaterials. Hybrid carbon-based hierarchical nanostructures are particularly promising for electrochemical energy storage since they combine benefits of nanosize effects, enhanced electrical conductivity and integrity of bulk materials. We show that endohedral multiwalled carbon nanotubes (CNT) encapsulating high-capacity (here: conversion and alloying) electrode materials have a high potential for use in anode materials for lithium-ion batteries (LIB). There are two essential characteristics of filled CNT relevant for application in electrochemical energy storage: (1) rigid hollow cavities of the CNT provide upper limits for nanoparticles in their inner cavities which are both separated from the fillings of other CNT and protected against degradation. In particular, the CNT shells resist strong volume changes of encapsulates in response to electrochemical cycling, which in conventional conversion and alloying materials hinders application in energy storage devices. (2) Carbon mantles ensure electrical contact to the active material as they are unaffected by potential cracks of the encapsulate and form a stable conductive network in the electrode compound. Our studies confirm that encapsulates are electrochemically active and can achieve full theoretical reversible capacity. The results imply that encapsulating nanostructures inside CNT can provide a route to new high-performance nanocomposite anode materials for LIB.Comment: Invite

Willkommens-Merkel, Chaos-Johnson, and Tore-Klose: Modeling the Evaluative Meaning of German Personal Name Compounds

Eichel A, Deeg T, Blessing A, Belosevic M, Arndt-Lappe S, Schulte im Walde S. Willkommens-Merkel, Chaos-Johnson, and Tore-Klose: Modeling the Evaluative Meaning of German Personal Name Compounds. In: The 2024 Joint International Conference on Computational Linguistics, Language Resources and Evaluation LREC-Coling 2024. Accepted

Kepler-432 b: a massive warm Jupiter in a 52-day eccentric orbit transiting a giant star

We study the Kepler object Kepler-432, an evolved star ascending the red giant branch. By deriving precise radial velocities from multi-epoch high-resolution spectra of Kepler-432 taken with the CAFE spectrograph at the 2.2 m telescope of Calar Alto Observatory and the FIES spectrograph at the Nordic Optical Telescope of Roque de Los Muchachos Observatory, we confirm the planetary nature of the object Kepler-432 b, which has a transit period of 52 days. We find a planetary mass of Mp = 5.84 ± 0.05MJup and a high eccentricity of e = 0.478 ± 0.004. With a semi-major axis of a = 0.303 ± 0.007 AU, Kepler-432 b is the first bona fide warm Jupiter detected to transit a giant star. We also find a radial velocity linear trend of γ̇ = 0.44 ± 0.04 m s-1 d-1, which suggests the presence of a third object in the system. Current models of planetary evolution in the post-main-sequence phase predict that Kepler-432 b will be most likely engulfed by its host star before the latter reaches the tip of the red giant branch