Solvent Effect on Electrochemical CO₂ Reduction Reaction on Nanostructured Copper Electrodes

The electrochemical reduction of CO2 (CO2RR) is a sustainable alternative for producing fuels and chemicals, although the production of highly desired hydrocarbons is still a challenge due to the higher overpotential requirement in combination with the competitive hydrogen evolution reaction (HER). Tailoring the electrolyte composition is a possible strategy to favor the CO2RR over the HER. In this work we studied the solvent effect on the CO2RR on a nanostructured Cu electrode in acetonitrile solvent with different amounts of water. Similar to what has been observed for aqueous media, our online gas chromatography results showed that CO2RR in acetonitrile solvent is also structure-dependent, since nanocube-covered copper (CuNC) was the only surface (in comparison to polycrystalline Cu) capable of producing a detectable amount of ethylene (10% FE), provided there is enough water present in the electrolyte (>500 mM). In situ Fourier Transform Infrared (FTIR) spectroscopy showed that in acetonitrile solvent the presence of CO2 strongly inhibits HER by driving away water from the interface. CO is by far the main product of CO2RR in acetonitrile (>85% Faradaic efficiency), but adsorbed CO is not detected. This suggests that in acetonitrile media CO adsorption is inhibited compared to aqueous media. Remarkably, the addition of water to acetonitrile has little quantitative and almost no qualitative effect on the activity and selectivity of the CO2RR. This indicates that water is not strongly involved in the rate-determining step of the CO2RR in acetonitrile. Only at the highest water concentrations and at the CuNC surface, the CO coverage becomes high enough that a small amount of C2+ product is formed

Four new T dwarfs identified in PanSTARRS 1 commissioning data

A complete well-defined sample of ultracool dwarfs is one of the key science programs of the Pan-STARRS 1 optical survey telescope (PS1). Here we combine PS1 commissioning data with 2MASS to conduct a proper motion search (0.1--2.0\arcsec/yr) for nearby T dwarfs, using optical+near-IR colors to select objects for spectroscopic followup. The addition of sensitive far-red optical imaging from PS1 enables discovery of nearby ultracool dwarfs that cannot be identified from 2MASS data alone. We have searched 3700 sq. deg. of PS1 y-band (0.95--1.03 um) data to y$\approx$19.5 mag (AB) and J$\approx$16.5 mag (Vega) and discovered four previously unknown bright T dwarfs. Three of the objects (with spectral types T1.5, T2 and T3.5) have photometric distances within 25 pc and were missed by previous 2MASS searches due to more restrictive color selection criteria. The fourth object (spectral type T4.5) is more distant than 25 pc and is only a single-band detection in 2MASS. We also examine the potential for completing the census of nearby ultracool objects with the PS1 3$\pi$ survey.Comment: 25 pages, 8 figures, 5 table, AJ accepted, updated to comply with Pan-STARRS1 naming conventio

HIP 38939B: A New Benchmark T Dwarf in the Galactic Plane Discovered with Pan-STARRS1

We report the discovery of a wide brown dwarf companion to the mildly metal-poor ([Fe/H]=-0.24), low galactic latitude (b = 1.88 deg) K4V star HIP 38939. The companion was discovered by its common proper motion with the primary and its red optical (Pan-STARRS1) and blue infrared (2MASS) colors. It has a projected separation of 1630 AU and a near-infrared spectral type of T4.5. As such it is one of only three known companions to a main sequence star which have early/mid-T spectral types (the others being HN Peg B and eps Indi B). Using chromospheric activity we estimate an age for the primary of 900{+1900,-600} Myr. This value is also in agreement with the age derived from the star's weak ROSAT detection. Comparison with evolutionary models for this age range indicates that HIP 38939B falls in the mass range 38+/-20 Mjup with an effective temperature range of 1090+/-60 K. Fitting our spectrum with atmospheric models gives a best fitting temperature of 1100 K. We include our object in an analysis of the population of benchmark T dwarfs and find that while older atmospheric models appeared to over-predict the temperature of the coolest objects compared to evolutionary models, more recent atmospheric models provide better agreement.Comment: ApJ, in press. Tiny changes incorporated into final version: added analysis of likelihood of companionship, clarified the fitting proceedure, and updated the benchmark analysis to highlight when the quoted evolutionary models use the atmospheric model they are being compared to as a boundary conditio

First Results from Pan-STARRS1: Faint, High Proper Motion White Dwarfs in the Medium-Deep Fields

The Pan-STARRS1 survey has obtained multi-epoch imaging in five bands (Pan-STARRS1 gps, rps, ips, zps, and yps) on twelve "Medium Deep Fields", each of which spans a 3.3 degree circle. For the period between Apr 2009 and Apr 2011 these fields were observed 50-200 times. Using a reduced proper motion diagram, we have extracted a list of 47 white dwarf (WD) candidates whose Pan-STARRS1 astrometry indicates a non-zero proper motion at the 6-sigma level, with a typical 1-sigma proper motion uncertainty of 10 mas/yr. We also used astrometry from SDSS (when available) and USNO-B to assess our proper motion fits. None of the WD candidates exhibits evidence of statistically significant parallaxes, with a typical 1-sigma uncertainty of 8 mas. Twelve of these candidates are known WDs, including the high proper motion (1.7"/yr) WD LHS 291. We confirm three more objects as WDs through optical spectroscopy. Based on the Pan-STARRS1 colors, ten of the stars are likely to be cool WDs with 4170 K Teff 5000 K and cooling ages <9 Gyr. We classify these objects as likely thick disk WDs based on their kinematics. Our current sample represents only a small fraction of the Pan-STARRS1 data. With continued coverage from the Medium Deep Field Survey and the 3pi survey, Pan-STARRS1 should find many more high proper motion WDs that are part of the old thick disk and halo.Comment: 33 pages, 8 figures, submitted to Ap

Soft Openings: The psycho-technological expertise of third sector curriculum reform

Since the late 1990s the "third sector" has become active in generating new curriculum programmes in England. Based on tracing third sector participation in public education during the New Labour years, the article explores a documentary archive of third sector curriculum texts and argues that the programmes, strategies and techniques of the third sector have sought to pursue a new form of governmentality. The type of governmentality pursued by the third sector takes form as a "soft" style of curriculum reform derived from assembling together cybernetic and psychological forms of expertise, interactionist and constructivist pedagogies, and an emerging "psycho-technology" of subjectivity. The third sector fabricates reform proposals for a curriculum of the future in which governance is done by cross-sectoral networking, epistemological categories are blurred, and student subjectivities are made up to be malleable, soft-skilled and psychologically self-shaping. The article examines how third sector texts have assembled this new psycho-technological expertise of curriculum reform through both cybernetic and psychological styles of thinking