Volcanism and the Greenland ice cores: A new tephrochronological framework for the last glacial-interglacial transition (LGIT) based on cryptotephra deposits in three ice cores

Chemical profiles from Greenland ice cores show that the frequency of volcanism was higher during the last glacial-interglacial transition (LGIT) and early Holocene, (17–9 ka b2k) than in any other period during the last 110 kyr. This increased frequency has partly been linked to climate-driven melting of the Icelandic ice sheet during the last deglaciation, with regional isostatic changes thought to alter mantle viscosity and lead to more eruptions. Our study is the first to construct a comprehensive tephrochronological framework from Greenland ice cores over the LGIT to aid in the reconstruction of volcanic activity over this period. The framework is based on extensive high-resolution sampling of three Greenland ice cores between 17.4 and 11.6 ka b2k and comprises a total of 64 cryptotephra deposits from the NGRIP, GRIP and NEEM ice cores. We show that many of these tephras are preserved within the core without an associated chemical signature in the ice, which implies that reconstructions of volcanism based solely on glacio-chemical indicators might underestimate the number of events. Single glass shards from each deposit were geochemically characterised to trace the volcanic source and many of these deposits could be correlated between cores. We show that the 64 deposits represent tephra deposits from 42 separate volcanic events, and of these, 39 are from Iceland, two from the north Pacific region (Japan and USA) and one has an unknown source. Six deposits can be correlated to terrestrial and/or marine tephra deposits in the Northern Hemisphere and the remaining 36 are unreported in other archives. We did not locate tephra from the compositionally distinctive Laacher See eruption (∼13 ka b2k) in our records. Combining our new discoveries with the previously published tephra framework, raises the number of individual tephra horizons found in Greenland ice over this interval to 50. This significantly improves the regional tephrochronological framework, our knowledge of the eruptive history of Iceland during the LGIT and provides new tephra constraints over key LGIT climate events. Consequentially, this framework can guide sampling strategies of future tephra studies in the terrestrial and marine realms aiming to link these records to the Greenland ice cores to assess regional climate synchroneity

Managing hyponatraemia in a patient with malignant melanoma: a case report

We report the case of a 46-year-old male with a known diagnosis of metastatic malignant melanoma who presented with hyponatraemia. The report details the challenges we faced in identifying the cause of his hyponatraemia and in attempting to reverse his electrolyte disturbance

A Holocene cryptotephra record from the Chukchi margin: the first tephrostratigraphic study in the Arctic Ocean

Developing geochronology for sediments in the Arctic Ocean and its continental margins is an important but challenging task complicated by multiple problems. In particular, the Chukchi/Beaufort margin, a critical area for reconstructing paleoceanographic conditions in the Pacific sector of the Arctic, features widespread dissolution of calcareous material, which limits posibilities for radiocarbon chronology. In order to evaluate the untapped potential of tephrochronology for constraining the age of these sediments, we investigated a sediment core from the eastern Chukchi Sea margin for cryptotephra. The core was collected in the area of sediment focusing on the upper slope (Darby et al., 2009). Samples were taken from the upper sedimentary unit composed of homogenous, fine-grained mud inferred to represent marine environmental conditions of the last 8-9 ka. Based on this age estimate, the initial set of 36 samples has an average resolution of ~250 years. Freeze-dried samples (0.5 g) were treated with HCl, wet-sieved to obtain a 80-25-μm fraction, treated with 1% NaOH to disaggregate clay clumps, and separated at specific density between 2.3 and 2.5 g/cm3. Residues in all samples featured abundant shards of colorless volcanic glass with an admixture of brown shards in the lower part of the unit. Three apparent tephra peaks were identified in the upper part of the record. The electron microprobe analysis of individual shards from these peaks showed nearly identical chemical compositions indicative of the late-Holocene tephras of the Aniakchak volcano in southwestern Alaska (e.g., Kaufman et al., 2012). The glasses analyzed exhibit a continuous composition range from 55 to 77 wt% SiO2 overlapping with two major populations of Aniakchak glasses (andesitic and dacitic) and also including some intermediate compositions. We infer that the three tephra peaks identified correspond to the three prominent tephra layers investigated in lake deposits between Aniakchak and the core site and dated to ~0.4, 3.1, and 3.7 ka (Kaufman et al., 2012). Further detailed study of tephra distribution in the Chukchi margin cores is underway. Identification of distinct tephra peaks with the composition traceable to specific known eruptions provides a powerful, independent chronological tool, much needed for Arctic paleoceanography. The consistent presence of cryptotephra in the analyzed samples suggests its wide occurrence in at least the Chukchi margin sediments; studies from other Arctic shelves and basins are needed to understand the geographic pattern of tephra distribution in seafloor sediments from this part of the world. Darby, D.A., Ortiz, J. Polyak, L., et al., 2009. The role of currents and sea ice in both slowly deposited central Arctic and rapidly deposited Chukchi-Alaskan margin sediments. Global Planet. Change 68, 58-72. Kaufman, D.S., Jensen, B.J.L., Reyes, A.V., et al., 2012. Late Quaternary tephrostratigraphy, Ahklun Mountains, SW Alaska. J. Quatern. Sci. 27, 344–359

Extending the limits of the Borrobol Tephra to Scandinavia and detection of new early Holocene tephras

Abstract Analyses of two infilled lakes in Blekinge, southeast Sweden, indicate the presence of at least three tephra horizons of Termination 1 and early Holocene age. Geochemical analyses confirm the presence of the Borrobol Tephra, the Askja Tephra (10,000 14 C yr B.P.), and one previously unreported tephra of Icelandic origin. Extending the limits of the Borrobol Tephra to Scandinavia illustrates that this ash is far more widespread than previously realized and is therefore, an important marker horizon for determining the rate and timing of the initial warming at the start of Greenland Interstade 1 (GI-1) within Europe. The relatively unknown Askja Tephra and the newly discovered Hässeldalen Tephra are stratigraphically placed at the Younger Dryas/Preboreal transition. This paper demonstrates the suitability and success associated with the extraction techniques for tracing microtephra horizons in areas distal to volcanic sources

Identification of the Askja-S Tephra in a rare turlough record from Pant-y-Llyn, south Wales

Tephrochronology and especially crypto-tephrochronology is an established chronological technique employed in a range of depositional environments in Europe and beyond. During the late Quaternary, Icelandic cryptotephra deposits are widely found in palaeorecords across northern latitudes of Europe e.g. Scotland, Ireland, Norway, Sweden and the Faroe Islands but are sporadic in southerly latitudes as distance from Iceland increases. As yet, very few Icelandic cryptotephras have been identified in Wales or southern England which may well reflect the geographical limit of Icelandic tephra distribution. Here, however, we report the discovery of an Icelandic cryptotephra deposit within a sediment sequence retrieved from the Pant-y-Llyn turlough (Carmarthenshire, south Wales), the only known turlough in Britain. Turloughs are groundwater-fed ephemeral lakes associated with limestone bedrock and can accumulate sediments that may yield records suitable for palaeoreconstructions. A discrete peak of glass shards originating from the Askja-S eruption is identified in the sediment record. This discovery extends the distribution of this early Holocene eruption giving new insight into its dispersal patterns and also indicates that sedimentary sequences from sites in these more southerly latitudes are valuable repositories for ash preservation. Furthermore, its discovery within a carbonate-rich sequence provides a minimum age constraint on the timing of sediment accumulation and provides an alternative tool for what is typically a problematic dating environment

Geochemical ice-core constraints on the timing and climatic impact of Aniakchak II (1628 BCE) and Thera (Minoan) volcanic eruptions

This work was supported by funding from the European Research Council (ERC) under the European Union’s Horizon 2020 research and innovation programme (grant agreement 820047 to M.Si.), the Malcolm H. Wiener Foundation (Interdisciplinary Chronology of Civilizations Project to C.P.) and a UKRI Future Leader Fellowship (MR/S035478/1 to P.A).Decades of research have focused on establishing the exact year and climatic impact of the Minoan eruption of Thera, Greece (c.1680–1500 BCE). Ice cores offer key evidence to resolve this controversy, but attempts have been hampered by a lack of multi-volcanic event synchronization between records. In this study, Antarctic and Greenland ice-core records are synchronized using a double bipolar sulfate marker and calendar dates are assigned to each eruption revealed within the ‘Thera period’. From this global scale sequence of volcanic sulfate loading, we derive indications towards each eruption’s latitude and potential to disrupt the climate system. Ultra-fine sampling for sulfur isotopes and tephra conclusively demonstrate a colossal eruption of Alaska’s Aniakchak II as the source of stratospheric sulfate in the now precisely dated 1628 BCE ice layer. These findings end decades of speculation that Thera was responsible for the 1628 BCE event, and place Aniakchak II (52 ± 17 Tg S) and an unknown volcano at 1654 BCE (50 ± 13 Tg S) as two of the largest Northern Hemisphere sulfur injections in the last 4000 years. This opens possibilities to explore widespread climatic impacts for contemporary societies and, in pinpointing Aniakchak II, confirms that stratospheric sulfate can be globally distributed from eruptions outside the tropics. Dating options for Thera are reduced to a series of precisely dated, constrained stratospheric sulfur injection events at 1611 BCE, 1562-1555 BCE and c.1538 BCE which are all below 14 ± 5 Tg S, indicating a climatic forcing potential for Thera well below that of Tambora (1815 CE).Publisher PDFPeer reviewe

Tracing marine cryptotephras in the North Atlantic during the last glacial period: Improving the North Atlantic marine tephrostratigraphic framework

Tephrochronology is increasingly being recognised as a key tool for the correlation of disparate palaeoclimatic archives, underpinning chronological models and facilitating climatically independent comparisons of climate proxies. Tephra frameworks integrating both distal and proximal tephra occurrences are essential to these investigations providing key details on their spatial distributions, geochemical signatures, eruptive sources as well as any available chronological and/or stratigraphic information. Frameworks also help to avoid mis-correlation of horizons and provide important information on volcanic history. Here we present a comprehensive chronostratigraphic framework of 14 tephra horizons from North Atlantic marine sequences spanning 60-25 cal ka BP. Horizons previously discovered as visible or coarse-grained deposits have been combined with 11 newly recognised volcanic deposits, identified through the application of cryptotephra identification and characterisation methods to a wide network of marine sequences. Their isochronous integrity has been assessed using their physical characteristics. All horizons originated from Iceland with the vast majority having a basaltic composition sourced from the Grímsvötn, Kverkfjöll, Hekla/Vatnafjöll and Katla volcanic systems. New occurrences, improved stratigraphic placements and a refinement of the geochemical signature of the NAAZ II are reported and the range of the FMAZ IV has been extended. In addition, several significant geochemical populations that further investigations could show to be isochronous are reported. This tephra framework provides the foundation for the correlation and synchronisation of these marine records to the Greenland ice-cores and European terrestrial records to investigate the phasing, rate, timing and mechanisms controlling rapid climate changes that characterised the last glacial period

Visualizing tephra deposits and sedimentary processes in the marine environment: The potential of X‐ray microtomography

Localized tephra deposition in marine sequences is the product of many complex primary and secondary depositional processes. These can significantly influence the potential applicability of tephra deposits as isochronous marker horizons and current techniques, used in isolation, may be insufficient to fully unravel these processes. Here we demonstrate the innovative application of X-ray microtomography (µCT) to successfully identify tephra deposits preserved within marine sediments and use these parameters to reconstruct their internal three-dimensional structure. Three-dimensional visualizations and animations of tephra dispersal in the sediment permit a more thorough assessment of postdepositional processes revealing a number of complex microsedimentological features that are not revealed by conventional methods. These features include bioturbation burrows and horizontally discontinuous tephra packages, which have important ramifications for the stratigraphic placement of the isochron in a sedimentary sequence. Our results demonstrate the potential for utilizing rigorous two and three-dimensional microsedimentological analysis of the ichnofabric to enhance and support the use of tephra deposits as isochronous marker horizons and to identify the stratigraphic position that best reflects the primary fallout of ash. The application also provides an exceptional insight into the style and rate of sedimentation processes and permits an assessment of the stratigraphic integrity of a tephra deposit. We discuss the possibility of applying these µCT methods to the identification of cryptotephras within various paleoclimatic sequences and to enhance our understanding of marine sedimentation processes

A North Atlantic tephrostratigraphical framework for 130-60 ka b2k:new tephra discoveries, marine-based correlations, and future challenges

Building chronological frameworks for proxy sequences spanning 130–60 ka b2k is plagued by difficulties and uncertainties. Recent developments in the North Atlantic region, however, affirm the potential offered by tephrochronology and specifically the search for cryptotephra. Here we review the potential offered by tephrostratigraphy for sequences spanning 130–60 ka b2k. We combine newly identified cryptotephra deposits from the NGRIP ice-core and a marine core from the Iceland Basin with previously published data from the ice and marine realms to construct the first tephrostratigraphical framework for this time-interval. Forty-three tephra or cryptotephra deposits are incorporated into this framework; twenty three tephra deposits are found in the Greenland ice-cores, including nine new NGRIP tephras, and twenty separate deposits are preserved in various North Atlantic marine sequences. Major, minor and trace element results are presented for the new NGRIP horizons together with age estimates based on their position within the ice-core record. Basaltic tephras of Icelandic origin dominate the framework with only eight tephras of rhyolitic composition found. New results from marine core MD99-2253 also illustrate some of the complexities and challenges of assessing the depositional integrity of marine cryptotephra deposits. Tephra-based correlations in the marine environment provide independent tie-points for this time-interval and highlight the potential of widening the application of tephrochronology. Further investigations, however, are required, that combine robust geochemical fingerprinting and a rigorous assessment of tephra depositional processes, in order to trace coeval events between the two depositional realms