Robust Neighboring Optimal Guidance for the Advanced Launch System

In recent years, optimization has become an engineering tool through the availability of numerous successful nonlinear programming codes. Optimal control problems are converted into parameter optimization (nonlinear programming) problems by assuming the control to be piecewise linear, making the unknowns the nodes or junction points of the linear control segments. Once the optimal piecewise linear control (suboptimal) control is known, a guidance law for operating near the suboptimal path is the neighboring optimal piecewise linear control (neighboring suboptimal control). Research conducted under this grant has been directed toward the investigation of neighboring suboptimal control as a guidance scheme for an advanced launch system

A tunable vacuum ultraviolet xenon laser

Imperial Users onl

Neighboring suboptimal control for vehicle guidance

The neighboring optimal feedback control law is developed for systems with a piecewise linear control for the case where the optimal control is obtained by nonlinear programming techniques. To develop the control perturbation for a given deviation from the nominal path, the second variation is minimized subject to the constraint that the final conditions be satisfied (neighboring suboptimal control). This process leads to a feedback relationship between the control perturbation and the measured deviation from the nominal state. Neighboring suboptimal control is applied to the lunar launch problem. Two approaches, single optimization and multiple optimization for calculating the gains are used, and the gains are tested in a guidance simulation with a mismatch in the acceleration of gravity. Both approaches give acceptable results, but multiple optimization keeps the perturbed path closer to the nominal path

Microstructural and strength stability of CVD SiC fibers in argon environment

The room temperature tensile strength and microstructure of three types of commercially available chemically vapor deposited silicon carbide fibers were measured after 1, 10, and 100 hour heat treatments under argon pressures of 0.1 to 310 MPa at temperatures to 2100 C. Two types of fiber had carbon-rich surface coatings and the other contained no coating. All three fiber types showed strength degradation beyond 1400 C. Time and temperature of exposure had greater influence on strength degradation than argon pressure. Recrystallization and growth of near stoichiometric SiC grains appears to be the dominant mechanism for the strength degradation

Advanced launch system trajectory optimization using suboptimal control

The maximum-final mass trajectory of a proposed configuration of the Advanced Launch System is presented. A model for the two-stage rocket is given; the optimal control problem is formulated as a parameter optimization problem; and the optimal trajectory is computed using a nonlinear programming code called VF02AD. Numerical results are presented for the controls (angle of attack and velocity roll angle) and the states. After the initial rotation, the angle of attack goes to a positive value to keep the trajectory as high as possible, returns to near zero to pass through the transonic regime and satisfy the dynamic pressure constraint, returns to a positive value to keep the trajectory high and to take advantage of minimum drag at positive angle of attack due to aerodynamic shading of the booster, and then rolls off to negative values to satisfy the constraints. Because the engines cannot be throttled, the maximum dynamic pressure occurs at a single point; there is no maximum dynamic pressure subarc. To test approximations for obtaining analytical solutions for guidance, two additional optimal trajectories are computed: one using untrimmed aerodynamics and one using no atmospheric effects except for the dynamic pressure constraint. It is concluded that untrimmed aerodynamics has a negligible effect on the optimal trajectory and that approximate optimal controls should be able to be obtained by treating atmospheric effects as perturbations

Modernism and state power in the pre-war poetry and prose of Ezra Pound, 1911–1914

Pound scholars have tended to assume that questions of state power, and of the relationship between the state and the individual, only become central to his work during the inter-war period. The present thesis, however, argues that these questions are a major concern in Pound’s writing during the years immediately preceding the First World War, and that questions of state power significantly colour Pound’s imagist and vorticist work. Chapter one reads Pound’s translation of the Anglo-Saxon Seafarer as a contribution to the radical Edwardian debate about the expansion of the state’s bureaucratic power and the threat it might pose to individual autonomy. I also consider the way Pound’s translation links state power to the division of labour. Chapter two reassesses Pound’s instigation of the imagist movement, against the backdrop of his concurrent fascination with the First Balkan War, an episode all but ignored in previous Pound scholarship. I argue that Pound interpreted the Balkan states as undertaking on the battlefield the very same modernizing struggle that he saw himself as embarking upon in the field of letters. Chapter three argues that as Pound’s pursuit of the ‘new’ intensifies, his identity as an American—as, in his words, ‘a citizen of a free State, a member of the sovereign people’—takes on a dual significance. Poetically, America’s perceived national youthfulness and virility become important tropes for novelty and modernity in his poetry. Politically, though, Pound casts the unfolding national, political and nascent imperial project of the United States as a metonym for modernity itself, scoffing at the Italian Futurist’s ‘automobilism’ as essentially provincial, and proposing instead his own ‘American Risorgimento’. Methodologically, this thesis strives to combine close readings of Pound’s poetry and prose, seen within its original publication context (that is, largely in little magazines), with careful reference to the broader historical context. Please note: For the purpose of online publication, all copyrighted material reproduced in the examination copy of this thesis (except that considered ‘fair use’) has been removed. The redacted material is collected in a supplementary volume

Duality Symmetric Strings, Dilatons and O(d,d) Effective Actions

We calculate the background field equations for the T-duality symmetric string building on previous work by including the effect of the Dilaton up to two-loops. Inclusion of the Dilaton allows us to obtain the full beta functionals of the duality symmetric sigma model. We are able to interpret the result in terms of a dimensionally reduced O(d,d) invariant target space effective action.Comment: 15 pages, latex; v2 reference added, typos fixe

The effect of surface structure on the optical and electronic properties of nanomaterials

Surface passivation of semiconductor quantum dots is essential to preserve their efficient and robust light emitting properties. By using a lattice matched (mismatch = 0.5%) lead halide perovskite matrix, we achieve shell-like passivation of lead sulfide QDs in crystalline films, leading to efficient infrared light emission. These structures are made from a simple one-step spin coating process of an electrostatically stabilized colloidal suspension. Photoluminescence and transient absorption spectroscopy indicate rapid energy transfer between the perovskite matrix and the QDs, suggesting an interface with few trap states. In addition to housing the efficient infrared QD emitters, lead halide perovskites themselves have good carrier mobilities and low trap densities, making these solution-processable heterostructures an attractive option for electrically pumped light emitting devices. The highest performing quantum dots for visible light applications are CdE (E=chalcogenide) core/shell heterostructures. Again, surface passivation plays a huge role in determining the brightness and robustness of visible QD emitters. Multilayer shell passivation is usually used to produce the highest quantum yield particles. Surface trap states are shown to be detrimental to luminescence output, even in thick-shelled particles. Spherical quantum wells allow for thicker shells and with good surface passivation, show promising reduction of biexciton auger recombination, as measured by a time correlated single photon counting (TCSPC) microscope. TCSPC methods were used to diagnose and identify QD architectures for LED applications and explore fundamental recombination dynamics using photon antibunching measurements, and statistical analysis of blinking traces.Introducing new surfaces onto graphitic substrates can be a useful for introducing new electronic properties, patterning device-specific geometries, or appending molecular catalysts. Metal nanoparticles were used to act as a catalyst for the gasification and etching of graphite and graphene. Several methods of controlling the initiation, propagation, and density of these trenches were explored. Patterning defects helped control where initiation occurred, while faceting existing defect sites could also enable more facile initiation and control the direction at the beginning of etching, due to the wetting mechanism of particle movement. Patterning the metal also was shown as a promising avenue to limit unwanted gasification and promote etching in specific, patterned regions. Surface functionalization using reactive gases was performed and characterized with outlook for future experiments