Thermodynamics of micellization of oppositely charged polymers

The complexation of oppositely charged colloidal objects is considered in this paper as a thermodynamic micellization process where each kind of object needs the others to micellize. This requirement gives rise to quantitatively different behaviors than the so-called mixed-micellization where each specie can micellize separately. A simple model of the grand potential for micelles is proposed to corroborate the predictions of this general approach.Comment: 7 pages, 2 figures. Accepted for publication in Europhysics Letter

Multi-PLC Exercise Environments for Training ICS First Responders

When systems are targeted by cyber attacks, cyber first responders must be able to react effectively, especially when dealing with critical infrastructure. Training for cyber first responders is lacking and most existing exercise platforms are expensive, inaccessible or ineffective. This paper presents a mobile training platform which incorporates a variety of programmable logic controllers into a single system which facilitates the development of the unique skills required of cyber first responders operating in the realm of industrial control systems. The platform is modeled after a jail in the northeastern United States and was developed to maximize realism. Example training scenarios are provided to address specific skills and techniques. Results show that the platform is robust enough to conduct sustained training exercises that address a curriculum that has been proposed for cyber first responders

Phase operators, phase states and vector phase states for SU(3) and SU(2,1)

This paper focuses on phase operators, phase states and vector phase states for the sl(3) Lie algebra. We introduce a one-parameter generalized oscillator algebra A(k,2) which provides a unified scheme for dealing with su(3) (for k < 0), su(2,1) (for k > 0) and h(4) x h(4) (for k = 0) symmetries. Finite- and infinite-dimensional representations of A(k,2) are constructed for k < 0 and k > 0 or = 0, respectively. Phase operators associated with A(k,2) are defined and temporally stable phase states (as well as vector phase states) are constructed as eigenstates of these operators. Finally, we discuss a relation between quantized phase states and a quadratic discrete Fourier transform and show how to use these states for constructing mutually unbiased bases

Origin and stability of the dipolar response in a family of tetragonal tungsten bronze relaxors

A new family of relaxor dielectrics with the tetragonal tungsten bronze structure (nominal composition Ba6M3+Nb9O30, M3+ = Ga, Sc or In) were studied using dielectric spectroscopy to probe the dynamic dipole response and correlate this with the crystal structure as determined from powder neutron diffraction. Independent analyses of real and imaginary parts of the complex dielectric function were used to determine characteristic temperature parameters, TVF, and TUDR, respectively. In each composition both these temperatures correlated with the temperature of maximum crystallographic strain, Tc/a determined from diffraction data. The overall behaviour is consistent with dipole freezing and the data indicate that the dipole stability increases with increasing M3+ cation size as a result of increased tetragonality of the unit cell. Crystallographic data suggests that these materials are uniaxial relaxors with the dipole moment predominantly restricted to the B1 cation site in the structure. Possible origins of the relaxor behaviour are discussed.Comment: Main article 32 pages, 8 figures; Supplementary data 24 pages, 4 figure

Aggregation number distributions and mesoglobules in dilute solutions of diblock and triblock copolymers

We investigate the aggregation number and size distributions for inter-molecular clusters of amphiphilic diblock and triblock copolymers in poor solvent at very low concentrations. Diblocks and triblocks with hydrophilic ends are shown to possess narrow distributions corresponding to formation of monodispersed mesoglobules. Diblocks with hydrophobic ends are found to produce inter-cluster multimers due to bridging by the hydrophilic middle blocks, resulting in polydisperse distributions. Implications of these observations for preparation of monodispersed nanoparticles and, potentially, understanding of the quaternary structure of proteins are discussed.Comment: 4 pages, 4 PS figures. Accepted for publication in EP

Coupling the image analysis and the artificial neural networks to predict a mixing time of a pharmaceutical powder

In recent years, different laboratories were interested in predicting the mixing time of a pharmaceutical powder. In fact, a nonhomogeneous mixture may lead to under dose and/or overdose of the active ingredient in the drug product. Our study is aimed toward using a new and revolutionary approach in the field of the processes “The Artificial Neural Networks” (ANN) by using the Neural Networks ToolboxTM derived from Matlab® software. The validation of the neural network was assumed by studying others mixing powder s and then we compared the experimental results to the data obtained by the neural network calculations. Experimental results were obtained from a non-destructive method (Image Analysis) which was used in order to characterize the homogeneity of powder mixture in a V-Blender as well as a Cubic Blender which are most used in the pharmaceutical industry.Keywords: ANN; Image analysis; Homogeneity; Back-propagation algorithm; multi-layer perceptro

Multi Matrix Vector Coherent States

A class of vector coherent states is derived with multiple of matrices as vectors in a Hilbert space, where the Hilbert space is taken to be the tensor product of several other Hilbert spaces. As examples vector coherent states with multiple of quaternions and octonions are given. The resulting generalized oscillator algebra is briefly discussed. Further, vector coherent states for a tensored Hamiltonian system are obtained by the same method. As particular cases, coherent states are obtained for tensored Jaynes-Cummings type Hamiltonians and for a two-level two-mode generalization of the Jaynes-Cummings model.Comment: 24 page

Behavior of Droplets in Microfluidic System with T-Junction

Micro droplet formation is considered as a growing emerging area of research due to its wide-range application in chemistry as well as biology. The mechanism of micro droplet formation using two immiscible liquids running through a T-junction has been widely studied. We believe that the flow of these two immiscible phases can be of greater important factor that could have an impact on out-flow hydrodynamic behavior, the droplets generated and the size of the droplets. In this study, the type of the capillary tubes used also represents another important factor that can have an impact on the generation of micro droplets. The tygon capillary tubing with hydrophilic inner surface doesn't allow regular out-flows due to the fact that the continuous phase doesn't adhere to the wall of the capillary inner surface. Teflon capillary tubing, presents better wettability than tygon tubing, and allows to obtain steady and regular regimes of out-flow, and the micro droplets are homogeneoussize. The size of the droplets is directly dependent on the flows of the continuous and dispersed phases. Thus, as increasing the flow of the continuous phase, to flow of the dispersed phase stationary, the size of the drops decreases. Inversely, while increasing the flow of the dispersed phase, to flow of the continuous phase stationary, the size of the droplet increases

On supersymmetric quantum mechanics

This paper constitutes a review on N=2 fractional supersymmetric Quantum Mechanics of order k. The presentation is based on the introduction of a generalized Weyl-Heisenberg algebra W_k. It is shown how a general Hamiltonian can be associated with the algebra W_k. This general Hamiltonian covers various supersymmetrical versions of dynamical systems (Morse system, Poschl-Teller system, fractional supersymmetric oscillator of order k, etc.). The case of ordinary supersymmetric Quantum Mechanics corresponds to k=2. A connection between fractional supersymmetric Quantum Mechanics and ordinary supersymmetric Quantum Mechanics is briefly described. A realization of the algebra W_k, of the N=2 supercharges and of the corresponding Hamiltonian is given in terms of deformed-bosons and k-fermions as well as in terms of differential operators.Comment: Review paper (31 pages) to be published in: Fundamental World of Quantum Chemistry, A Tribute to the Memory of Per-Olov Lowdin, Volume 3, E. Brandas and E.S. Kryachko (Eds.), Springer-Verlag, Berlin, 200