1,083 research outputs found

    Acylation and alkylation of 1, 3-dimethoxybenzene in polyphosphoric acid

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    Products of the reaction of 3-halo- and 3-ethoxypropionic acids with 1,3-dimethoxybenzene (4) in polyphosphoric acid have been shown to be 2',4'-dimethoxy-3-(2,4-dimethoxyphenyl)-propiophenone (6) and 1,5-bis[3-(2,4-dimethoxyphenyl)-3-keto-propyl]-2,4-dimethoxybenzene (15) and these have been prepared by unambiguous syntheses. 2',4'-Dimethoxy-3-ethoxypropiophenone (3a) and 2',3,4'- trimethoxypropiophenone (3d) have been synthesized by the reaction of 3-chloro-2',4'-dimethoxypropiophenone (3c) with ethanol and methanol respectively

    Analytical and Experimental Investigation of Flow Through a Turbine Vane Cascade .

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    Present day military aero-gas turbines demand higher stage loadings for turbines so as to meet the growing for higher thrust/power with fuel consumption. This calls for improved methods of blade element profiles. Details of a computer code developed for the design of blade elements for the prescribed distribution of surface velocity (Mach number) based on Stanitz's inverse methods are presented in this paper. Effects of boundary layer growth on the blade surface has also been incorporated in this code. Turbine vane was designed making use of this program and a four-bladed cascade was fabricated. It was tested in a blow down wind tunnel for different blowing pressures and stagger angles. Mach number distribution was determined from measured static pressure on the suction and pressure surfaces of the blade. Based on stream filament technique a computer code was developed to predict the characteristics of flow thorough a blade cascade. Results of this study show reasonable agreement between experimentally obtained Mach number distribution and the initially prescribed as well as analytically predicted Mach number distributions

    Free energy analysis of binary alloys at phase transition

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    Order-disorder transformation in alloys is a fascinating and extensively studied problem for many years. This transformation has been studied widely using the two state Ising model. But vacancies are not considered in two state Ising model, which may play an important rule in determining the composition of stable configuration. So we used three state Ising model which takes vacancies also at lattice sites. To make a realistic study we haveincluded kinetic energy of the particles in the total Hamiltonian

    Electron beam induced deposition of silacyclohexane and dichlorosilacyclohexane: the role of dissociative ionization and dissociative electron attachment in the deposition process

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    We present first experiments on electron beam induced deposition of silacyclohexane (SCH) and dichlorosilacyclohexane (DCSCH) under a focused high-energy electron beam (FEBID). We compare the deposition dynamics observed when growing pillars of high aspect ratio from these compounds and we compare the proximity effect observed for these compounds. The two precursors show similar behaviour with regards to fragmentation through dissociative ionization in the gas phase under single-collision conditions. However, while DCSCH shows appreciable cross sections with regards to dissociative electron attachment, SCH is inert with respect to this process. We discuss our deposition experiments in context of the efficiency of these different electron-induced fragmentation processes. With regards to the deposition dynamics, we observe a substantially faster growth from DCSCH and a higher saturation diameter when growing pillars with high aspect ratio. However, both compounds show similar behaviour with regards to the proximity effect. With regards to the composition of the deposits, we observe that the C/Si ratio is similar for both compounds and in both cases close to the initial molecular stoichiometry. The oxygen content in the DCSCH deposits is about double that of the SCH deposits. Only marginal chlorine is observed in the deposits of from DCSCH. We discuss these observations in context of potential approaches for Si deposition.CWH likes to thank Luc van Kessel, Kerim Arat and Sebastiaan Lokhorst for their assistance with the Monte Carlo simulations of Figure 10. OI acknowledges supported from the Icelandic Center of Research (RANNIS) Grant No. 13049305(1-3) and the University of Iceland Research Fund. RKTP acknowledges a doctoral grant from the University of Iceland Research Fund and financial support from the COST Action CM1301; CELINA, for short term scientific missions (STSMs)Peer Reviewe

    Spectrophotometric determination of trace amounts of cadmium with iodide and methyl violet

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    445-446A selective spectrophotometric method based on the interaction of an anionic iodo complex of cadmium with methyl violet has been described for the determination of trace amounts of cadmium. The developed method is precise, accurate and has been applied to determination of cadmium at trace levels (25 ppb) in sea water and high purity samples of indium and zinc materials

    Biochemical characterization and 16s rRNA sequencing of different bacteria from textile dye effluents

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    Environmental pollution has been identified as a major problem in the modern world. Dyeing effluents have become a vital source of water pollution. Release of coloured textile effluents is undesirable in the aquatic environment as they reduce light penetration, thereby affecting aquatic life and limits utilization of the water media. In Tirupur, the textile factories discharge millions of litres of untreated effluents into the drains that eventually empty into river, Noyyal. The release of coloured compound into water bodies is undesirable not only because of their impact on photosynthesis of aquatic plants but also due to the carcinogenic nature of these dyes and their breakdown products. The ability of bacterial strains isolated from the dye effluent of textile mill sites. Morphological and biochemical characterization was done to identify isolates and was found to be Pseudomonas spp, Bacillus spp and Serattia spp. The isolated strains were finally identified by 16S rRNA sequence analysis. Bacteria are generally identified by 16S rRNA sequencing. The rRNA is the most conserved (least variable) gene in all cells. They were identified as Pseudomonas aeruginosa, Bacillus amyloliquefaciens and Serattia liquefaciens. The sequences were deposited in GENBANK. The accession numbers were KU041528, KU041530 and KU041531 respectively. The identification was conformed by 16S rRNA sequencing. Keywords: Textile Dye Effluents, Bacteria, 16S rRNA, NCBI
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