Synthesis of sub-5 nm Co-doped SnO2_2 nanoparticles and their structural, microstructural, optical and photocatalytic properties

A swift chemical route to synthesize Co-doped SnO$_2$ nanopowders is described. Pure and highly stable Sn$_{1-x}$Co$_x$O$_{2-\delta}$ (0 $\le$ x $\le$ 0.15) crystalline nanoparticles were synthesized, with mean grain sizes < 5 nm and the dopant element homogeneously distributed in substitutional sites of the SnO$_2$ matrix. The UV-visible diffuse reflectance spectra of the Sn$_{1-x}$Co$_x$O$_{2-\delta}$ samples reveal red shifts, the optical bandgap energies decreasing with increasing Co concentration. The Urbach energies of the samples were calculated and correlated with their bandgap energies. The photocatalytic activity of the Sn$_{1-x}$Co$_x$O$_{2-\delta}$ samples was investigated for the 4-hydroxylbenzoic acid (4-HBA) degradation process. A complete photodegradation of a 10 ppm 4-HBA solution was achieved using 0.02% (w/w) of Sn$_{0.95}$Co$_{0.05}$O$_{2-\delta}$ nanoparticles in 60 min of irradiation.Comment: 29 pages, 2 tables, 10 figure

Pulmonary function in young females of Kolkata, India – Revisited

Rapid economic and industrial growths imposed significant impact on human health including the pulmonary health. Questions were raised regarding the validity of the existing prediction norms of pulmonary function tests (PFTs) in a particular population. The present study was conducted to investigate the applicability of the existing norms for PFTs in young healthy non-smoking female university students of Kolkata, India. Significant difference was noted in vital capacity (VC), forced vital capacity (FVC), and forced expiratory volume in 1 s (FEV1) when the present data were compared with the earlier study in similar population. Correlation statistic revealed significant relationship of age and body height with all the PFT parameters. Body mass had significant correlation with VC, FVC, FEV1 as a percentage of FVC (FEV1%), and peak expiratory flow rate (PEFR). Regression equations have been computed for predicting PFTs from age and body height. There has been a change of PFTs in the studied population for the last couple of decades due to increased environmental pollution in the course of economical and industrial developments. Regression equations computed in this study are not only recommended to predict PFT parameters in the studied population, but they are also considered more reliable owing to their substantially smaller standard error of estimate than those proposed in the previous study

ANTHROPOMETRIC PROFILE, BODY COMPOSITION AND VERTICAL JUMP SCORE IN BOXERS AND SWIMMERS

Background. Vertical jump test (VJT) is used in some sport disciplines to evaluate an individual’s lower extremity power. However, VJT data is unavailable in young Indian boxers and swimmers.Objective. The given study was aimed to evaluate the VJT, anthropometric profile and body composition in young male Indian swimmers and boxers and compare the data with sedentary control group. The study also explored the relationship of VJT with anthropometric parameters and different components of body composition in the studied groups.Methods. Male boxers (n=40), swimmers (n=40) and sedentary subjects (n=40) with similar socio-economic background with age ranging between 21 and 25 years were sampled for the study from Kolkata, India. Body composition was determined by skinfold measurements and VJT was evaluated by Sargent Jump Test.Results. One way ANOVA shows significant (p&lt;0.001) difference in body mass, %fat, total body fat (TF), lean body mass (LBM) and VJT score in boxers, swimmers and sedentary groups. Significant positive correlation of LBM with VJT score was associated with a greater jumping height in swimmers. On the other hand, VJT had significant negative (p&lt;0.05) correlation with sum of all the skinfolds, individual skinfold and total fat in both athlete group as well as in the sedentary group.Conclusion. Significant intergroup difference was found in the studied parameters. VJT scores obtained in all the groups were well comparable. Higher value of body %fat imposed the unfavourable effect towards achieving higher jumping height mainly in sedentary group.KEY WORDS: VJT, boxers, swimmers, %fat, LBM

Mass selection in laser-plasma ion accelerator on nanostructured surfaces

When an intense laser pulse interacts with a solid surface, ions get accelerated in the laser-plasma due to the formation of transient longitudinal electric field along the target normal direction. However, the acceleration is not mass-selective. The possibility of manipulating such ion acceleration scheme to enhance the energy of one ionic species (either proton or carbon) selectively over the other species is investigated experimentally using nanopore targets. For an incident laser intensity of approximately 5×1017 W/cm2, we show that the acceleration is optimal for protons when the pore diameter is about 15-20 nm, while carbon ions are optimally accelerated when the pore diameter is close to 40-50 nm. The observed effect is due to tailoring targetry by the pulse pedestal of the laser prior to the arrival of the main pulse

Mechanical characteristics of microwave sintered silicon carbide

The present work deals with the sintering of SIC with a low melting additive by microwave technique, The mechanical characteristics of the products were compared with that of conventionally sintered products. The failure stress of the microwave sintered products, in biaxial flexure, was superior to that of the products made by conventional sintering route in ambient condition. In firing of products by conventionally sintered process, SiC grain gets oxidized producing SiO2 (-32 wt%) and deteriorates the quality of the product substantially. Partially sintered silicon carbide by such a method is a useful material for a varieties of applications ranging from kiln furniture to membrane material

Mental health status and perceived burden in caregiving spouses of persons with psychotic illness (a study from India)

Mental illness poses a great deal of burden on other family members, particularly the primary caregiver. In the Indian context for a married person with mental illness, the caregiving burden is usually experienced by the spouse, who is considered to be the ‘natural’ option. This quantitative study used survey methodology to assess caregiving burden in fifty spouses of persons diagnosed with a psychotic illness. Data was collected at a neuro-psychiatric facility in Tiruchirappalli, India. The Depression, Anxiety and Stress Scale and the Burden Assessment Schedule were the instruments administered to assess the mental health status of the spouse and their perceived burden. Findings revealed that the majority of spouses were classified as experiencing ‘severe’ and ‘extremely severe’ in terms of their depression, anxiety and stress levels and ‘high’ in terms of perceived burden. The specific ‘type’ of clinical diagnosis, however, did not differentiate the spouses on the key variables studied. The correlation of these key variables with other background variables has also been examined. The implications of the results of this study for psychosocial intervention have also been discussed in this article

Efficient transport of femtosecond laser-generated fast electrons in a millimeter thick graphite

We demonstrate efficient transport of fast electrons generated by ∼1018 W/cm2, 30 fs, 800 nm laser pulses through a millimeter thick polycrystalline graphite. Measurements of hot electron spectra at the front side of the graphite target show enhancement in terms of the electron flux and temperature, while the spectra at the rear confirm the ability of the graphite to transport large electron currents over a macroscopic distance of a millimeter. In addition, protons of keV energies are observed at the rear side of such a macroscopically thick target and attributed to the target-normal-sheath-acceleration mechanism

Mechanical characterization of microwave sintered zinc oxide

The mechanical characterization of microwave sintered zinc oxide disks is reported. The microwave sintering was done with a specially designed applicator placed in a domestic microwave oven operating at a frequency of 2.45 GHz to a maximum power output of 800 Watt, These samples with a wide variation of density and hence, of open pore volume percentage, were characterized in terms of its elastic modulus determination by ultrasonic time of flight measurement using a 15 MHz transducer, In addition, the load dependence of the microhardness was examined for the range of loads 0.1-20 N, Finally, the fracture toughness data (K-IC) was obtained using the indentation techniqu

Luminous, relativistic, directional electron bunches from an intense laser driven grating plasma

Bright, energetic, and directional electron bunches are generated through efficient energy transfer of relativistic intense (~ 1019 W/cm2), 30 femtosecond, 800 nm high contrast laser pulses to grating targets (500 lines/mm and 1000 lines/mm), under surface plasmon resonance (SPR) conditions. Bi-directional relativistic electron bunches (at 40° and 150°) are observed exiting from the 500 lines/mm grating target at the SPR conditions. The surface plasmon excited grating target enhances the electron flux and temperature by factor of 6.0 and 3.6, respectively, compared to that of the plane substrate. Particle-in-Cell simulations indicate that fast electrons are emitted in different directions at different stages of the laser interaction, which are related to the resultant surface magnetic field evolution. This study suggests that the SPR mechanism can be used to generate multiple, bright, ultrafast relativistic electron bunches for a variety of applications