333 research outputs found
Progress in Atomic Fountains at LNE-SYRTE
We give an overview of the work done with the Laboratoire National de
M\'etrologie et d'Essais-Syst\`emes de R\'ef\'erence Temps-Espace (LNE-SYRTE)
fountain ensemble during the last five years. After a description of the clock
ensemble, comprising three fountains, FO1, FO2, and FOM, and the newest
developments, we review recent studies of several systematic frequency shifts.
This includes the distributed cavity phase shift, which we evaluate for the FO1
and FOM fountains, applying the techniques of our recent work on FO2. We also
report calculations of the microwave lensing frequency shift for the three
fountains, review the status of the blackbody radiation shift, and summarize
recent experimental work to control microwave leakage and spurious phase
perturbations. We give current accuracy budgets. We also describe several
applications in time and frequency metrology: fountain comparisons,
calibrations of the international atomic time, secondary representation of the
SI second based on the 87Rb hyperfine frequency, absolute measurements of
optical frequencies, tests of the T2L2 satellite laser link, and review
fundamental physics applications of the LNE-SYRTE fountain ensemble. Finally,
we give a summary of the tests of the PHARAO cold atom space clock performed
using the FOM transportable fountain.Comment: 19 pages, 12 figures, 5 tables, 126 reference
Enzymatic Hydrolysis of Bacterial Cellulose for the Production of Nanocrystals for the Food Packaging Industry
Bacterial cellulose nanocrystals (BCNCs) obtained by enzymatic hydrolysis have been loaded in pullulan biopolymer for use as nanoparticles in the generation of high-oxygen barrier coatings intended for food packaging applications. Bacterial cellulose (BC) produced by Komagataeibacter sucrofermentans was hydrolyzed by two different enzymatic treatments, i.e., using endo-1,4-\u3b2-glucanases (EGs) from Thermobifida halotolerans and cellulase from Trichoderma reesei. The hydrolytic activity was compared by means of turbidity experiments over a period of 145 h, whereas BCNCs in their final state were compared, in terms of size and morphology, by atomic force microscopy (AFM) and dynamic light scattering (DLS). Though both treatments led to particles of similar size, a greater amount of nano-sized particles ( 48250 nm) were observed in the system that also included cellulase enzymes. Unexpectedly, transmission electron microscopy (TEM) revealed that cellulose nanoparticles were round-shaped and made of 4-5 short (150-180 nm) piled whiskers. Pullulan/BCNCs nanocomposite coatings allowed an increase in the overall oxygen barrier performance, of more than two and one orders of magnitude ( 480.7 mL\ub7m-2\ub724 h-1), of pure polyethylene terephthalate (PET) ( 48120 mL\ub7m-2\ub724 h-1) as well as pullulan/coated PET ( 486 mL\ub7m-2\ub724 h-1), with no significant difference between treatments (hydrolysis mediated by EGs or with the addition of cellulase). BCNCs obtained by enzymatic hydrolysis have the potential to generate high oxygen barrier coatings for the food packaging industry
La inclinacion española
Copia digital. Valladolid : Junta de Castilla y León. Consejería de Cultura y Turismo, 2009-2010Contiene, además: El conde las legumbres, del mismo auto
Improved tests of Local Position Invariance using 87Rb and 133Cs fountains
We report tests of local position invariance based on measurements of the
ratio of the ground state hyperfine frequencies of 133Cs and 87Rb in
laser-cooled atomic fountain clocks. Measurements extending over 14 years set a
stringent limit to a possible variation with time of this ratio: d
ln(nu_Rb/nu_Cs)/dt=(-1.39 +/- 0.91)x 10-16 yr-1. This improves by a factor of
7.7 over our previous report (H. Marion et al., Phys. Rev. Lett. 90, 150801
(2003)). Our measurements also set the first limit to a fractional variation of
the Rb/Cs ratio with gravitational potential at the level of c^2 d
ln(nu_Rb/nu_Cs)/dU=(0.11 +/- 1.04)x 10^-6, providing a new stringent
differential redshift test. The above limits equivalently apply to the
fractional variation of the quantity alpha^{-0.49}x(g_Rb/g_Cs), which involves
the fine structure constant alpha and the ratio of the nuclear g-factors of the
two alkalis. The link with variations of the light quark mass is also presented
together with a global analysis combining with other available highly accurate
clock comparisons.Comment: 5 pages, 3 figures, 3 tables, 34 reference
Mechanical behavior of biopolymer composite coatings on plastic films by depth-sensing indentation : a nanoscale study
Fundamental physical behaviors of materials at the nanoscale level are crucial when local aspects govern the macroscale performance of nanocomposites, e.g., interface and surface phenomena. Because of the increasing interest in biopolymer nanocomposite coatings for many different applications (e.g., optical devices, displays/screens, and packaging), this work investigates the potential of nanoindentation as a method for clarifying the interplay between distinct phases (i.e., organic and inorganic) at local level in thin biopolymer films loaded with nanoparticles. The nanomechanical features of pullulan nanocomposite coatings laid on polyethylene terephthalate (PET) were quantified in terms of elastic modulus (E), hardness (H), and creep (C) through an instrumented indentation test composed of a loading-holding-unloading cycle. Colloidal silica (CS) and cellulose nanocrystals (CNCs) were used as spherical and rod-like nanoparticles, respectively. An overall reinforcing effect was shown for all nanocomposite coatings over the pristine (unfilled) pullulan coating. A size effect was also disclosed for the CS-loaded surfaces, with the highest E value recorded for the largest particles (8.19\u202f\ub1\u202f0.35\u202fGPa) and the highest H value belonging to the smallest ones (395.41\u202f\ub1\u202f25.22\u202fMPa). Comparing CS and CNCs, the addition of spherical nanoparticles had a greater effect on the surface hardness than cellulose nanowhiskers (353.50\u202f\ub1\u202f83.52\u202fMPa and 321.36\u202f\ub1\u202f43.26\u202fMPa, respectively). As for the elastic modulus, the addition of CS did not provide any improvement over both the bare and CNC-loaded pullulan coatings, whereas the coating including CNCs exhibited higher E values (p\u202f<\u202f.05). Finally, CS-loaded pullulan coatings were the best performing in terms of C properties, with an average indentation depth of 16.5\u202f\ub1\u202f1.85\u202fnm under a load of 3c190\u202f\u3bcN. These results are discussed in terms of local distribution gradients, surface chemistry of nanoparticles, and how nanoparticle aggregation occurred in the dry nanocomposite coatings
Atomic fountains and optical clocks at SYRTE: status and perspectives
In this article, we report on the work done with the LNE-SYRTE atomic clock
ensemble during the last 10 years. We cover progress made in atomic fountains
and in their application to timekeeping. We also cover the development of
optical lattice clocks based on strontium and on mercury. We report on tests of
fundamental physical laws made with these highly accurate atomic clocks. We
also report on work relevant to a future possible redefinition of the SI
second
An accurate optical lattice clock with 87Sr atoms
We report a frequency measurement of the 1S0-3P0 transition of 87Sr atoms in an optical lattice clock. The frequency is determined to be 429 228 004 229 879 (5) Hz with a fractional uncertainty that is comparable to state-of-the-art optical clocks with neutral atoms in free fall. Two previous measurements of this transition were found to disagree by about 2x10^{-13}, i.e. almost four times the combined error bar, instilling doubt on the potential of optical lattice clocks to perform at a high accuracy level. In perfect agreement with one of these two values, our measurement essentially dissipates this doubt
Accurate spectroscopy of Sr atoms
We report the frequency measurement with an accuracy in the 100 kHz range of
several optical transitions of atomic Sr : at 689 nm, at 688 nm and at 679 nm. Measurements are performed with
a frequency chain based on a femtosecond laser referenced to primary frequency
standards. They allowed the indirect determination with a 70 kHz uncertainty of
the frequency of the doubly forbidden 5s^2^1S_0- 5s5p^3P_0 transition of
Sr at 698 nm and in a second step its direct observation. Frequency
measurements are performed for Sr and Sr, allowing the
determination of , and isotope shifts, as well as the
hyperfine constants.Comment: 12 pages, 16 figure
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