152 research outputs found
Structure and magnetic order in Fe2+xV1-xAl
We present a detailed structural investigation via neutron diffraction of
differently heat treated samples Fe2VAl and Fe2+xV1-xAl. Moreover, the magnetic
behaviour of these materials is studied by means of mSR and
Mossbauer-experiments. Our structural investigation indicates that quenched
Fe2VAl, exhibiting the previously reported "Kondo insulating like" behaviour,
is off-stoichiometric (6%) in its Al content. Slowly cooled Fe2VAl is
structurally better ordered and stoichiometric, and the microscopic magnetic
probes establish long range ferromagnetic order below TC = 13K, consistent with
results from bulk experiments. The magnetic state can be modelled as being
generated by diluted magnetic ions in a non-magnetic matrix. Quantitatively,
the required number of magnetic ions is too large as to be explained by a model
of Fe/V site exchange. We discuss the implications of our findings for the
ground state properties of Fe2VAl, in particular with respect to the role of
crystallographic disorder.Comment: accepted for publication in J. Phys.: Condens. Matte
Electronic Structure, Local Moments and Transport in Fe_2VAl
Local spin density approximation calculations are used to elucidate
electronic and magnetic properties of Heusler structure Fe_2VAl. The compound
is found to be a low carrier density semimetal. The Fermi surface has small
hole pockets derived from a triply degenerate Fe derived state at Gamma
compensated by an V derived electron pocket at the X point. The ideal compound
is found to be stable against ferromagnetism. Fe impurities on V sites,
however, behave as local moments. Because of the separation of the hole and
electron pockets the RKKY interaction between such local moments should be
rapidly oscillating on the scale of its decay, leading to the likelihood of
spin-glass behavior for moderate concentrations of Fe on V sites. These
features are discussed in relation to experimental observations of an unusual
insulating state in this compound.Comment: 16 pages, RevTeX, 5 figure
Invariant higher-order variational problems II
Motivated by applications in computational anatomy, we consider a
second-order problem in the calculus of variations on object manifolds that are
acted upon by Lie groups of smooth invertible transformations. This problem
leads to solution curves known as Riemannian cubics on object manifolds that
are endowed with normal metrics. The prime examples of such object manifolds
are the symmetric spaces. We characterize the class of cubics on object
manifolds that can be lifted horizontally to cubics on the group of
transformations. Conversely, we show that certain types of non-horizontal
geodesics on the group of transformations project to cubics. Finally, we apply
second-order Lagrange--Poincar\'e reduction to the problem of Riemannian cubics
on the group of transformations. This leads to a reduced form of the equations
that reveals the obstruction for the projection of a cubic on a transformation
group to again be a cubic on its object manifold.Comment: 40 pages, 1 figure. First version -- comments welcome
Integrated modeling and validation for phase change with natural convection
Water-ice systems undergoing melting develop complex spatio-temporal
interface dynamics and a non-trivial temperature field. In this contribution,
we present computational aspects of a recently conducted validation study that
aims at investigating the role of natural convection for cryo-interface
dynamics of water-ice. We will present a fixed grid model known as the enthalpy
porosity method. It is based on introducing a phase field and employs mixture
theory. The resulting PDEs are solved using a finite volume discretization. The
second part is devoted to experiments that have been conducted for model
validation. The evolving water-ice interface is tracked based on optical images
that shows both the water and the ice phase. To segment the phases, we use a
binary Mumford Shah method, which yields a piece-wise constant approximation of
the imaging data. Its jump set is the reconstruction of the measured phase
interface. Our combined simulation and segmentation effort finally enables us
to compare the modeled and measured phase interfaces continuously. We conclude
with a discussion of our findings
Assessing the magnitude and trends in hospital acquired infections in Canadian hospitals through sequential point prevalence surveys
A longitudinal study investigating quality of life and nutritional outcomes in advanced cancer patients receiving home parenteral nutrition
NMR and Mossbauer study of spin dynamics and electronic structure of Fe{2+x}V{1-x}Al and Fe2VGa
In order to assess the magnetic ordering process in Fe2VAl and the related
material Fe2VGa, we have carried out nuclear magnetic resonance (NMR) and
Mossbauer studies. 27Al NMR relaxation measurements covered the temperature
range 4 -- 500 K in Fe(2+x)V(1-x)Al samples. We found a peak in the NMR
spin-lattice relaxation rate, 27T1^-1, corresponding to the magnetic
transitions in each of these samples. These peaks appear at 125 K, 17 K, and
165 K for x = 0.10, 0, and - 0.05 respectively, and we connect these features
with critical slowing down of the localized antisite defects. Mossbauer
measurements for Fe2VAl and Fe2VGa showed lines with no hyperfine splitting,
and isomer shifts nearly identical to those of the corresponding sites in Fe3Al
and Fe3Ga, respectively. We show that a model in which local band filling leads
to magnetic regions in the samples, in addition to the localized antisite
defects, can account for the observed magnetic ordering behavior.Comment: 5 pages, 3 figure
Lack of observational evidence for quantum structure of space-time at Plank scales
It has been noted (Lieu & Hillmann, 2002) that the cumulative affect of
Planck-scale phenomenology, or the structure of space-time at extremely small
scales, can be lead to the loss of phase of radiation emitted at large
distances from the observer. We elaborate on such an approach and demonstrate
that such an effect would lead to an apparent blurring of distant
point-sources. Evidence of the diffraction pattern from the HST observations of
SN 1994D and the unresolved appearance of a Hubble Deep Field galaxy at z=5.34
lead us to put stringent limits on the effects of Planck-scale phenomenology.Comment: 12 pages, 3 figures, accepter for ApJ
Common Features at the Start of the Neurodegeneration Cascade
A single-molecule study reveals that neurotoxic proteins share common structural features that may trigger neurodegeneration, thus identifying new targets for therapy and diagnosis
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