1,975 research outputs found

    Escherichia coli helicase II (UvrD) protein initiates DNA unwinding at nicks and blunt ends.

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    Stability of Relativistic Matter with Magnetic Fields for Nuclear Charges up to the Critical Value

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    We give a proof of stability of relativistic matter with magnetic fields all the way up to the critical value of the nuclear charge Zα=2/πZ\alpha=2/\pi.Comment: LaTeX2e, 12 page

    The in situ synthesis of PbS nanocrystals from lead(II) n -octylxanthate within a 1,3-diisopropenylbenzene–bisphenol A dimethacrylate sulfur copolymer

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    The synthesis of lead sulfide nanocrystals within a solution processable sulfur ‘inverse vulcanization’ polymer thin film matrix was achieved from the in situ thermal decomposition of lead(II) n-octylxanthate, [Pb(S2COOct)2]. The growth of nanocrystals within polymer thin films from single-source precursors offers a faster route to networks of nanocrystals within polymers when compared with ex situ routes. The ‘inverse vulcanization’ sulfur polymer described herein contains a hybrid linker system which demonstrates high solubility in organic solvents, allowing solution processing of the sulfur-based polymer, ideal for the formation of thin films. The process of nanocrystal synthesis within sulfur films was optimized by observing nanocrystal formation by X-ray photoelectron spectroscopy and X-ray diffraction. Examination of the film morphology by scanning electron microscopy showed that beyond a certain precursor concentration the nanocrystals formed were not only within the film but also on the surface suggesting a loading limit within the polymer. We envisage this material could be used as the basis of a new generation of materials where solution processed sulfur polymers act as an alternative to traditional polymers

    Dispersion of imbibition fronts

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    We have studied the dispersive behaviour of imbibition fronts in a porous medium by X-ray tomography. Injection velocities were varied and the porous medium was initially prewetted or not. At low velocity in the prewetted medium, the imbibition profiles are found to be distinctly hyperdispersive. The profiles are anomalously extended when compared to tracer fronts exhibiting conventional (Gaussian) dispersion. We observe a strong velocity dependence of the exponent characterizing the divergence of the dispersion coefficient for low wetting-fluid saturation. Hyperdispersion is absent at high imbibition velocities or when the medium is not prewetted.Comment: 8 pages, 5 figures; submitted to Europhysics Letter

    Spontaneous symmetry breaking in gauge theories via Bose-Einstein condensation

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    We propose a mechanism naturally leading to the spontaneous symmetry breaking in a gauge theory. The Higgs field is assumed to have global and gauged internal symmetries. We associate a non zero chemical potential to one of the globally conserved charges commuting with all of the gauge transformations. This induces a negative mass squared for the Higgs field triggering the spontaneous symmetry breaking of the global and local symmetries. The mechanism is general and we test the idea for the electroweak theory in which the Higgs sector is extended to possess an extra global Abelian symmetry. To this symmetry we associate a non zero chemical potential. The Bose-Einstein condensation of the Higgs leads, at tree level, to modified dispersion relations for the Higgs field while the dispersion relations of the gauge bosons and fermions remain undisturbed. The latter are modified through higher order corrections. We have computed some corrections to the vacuum polarizations of the gauge bosons and fermions. To quantify the corrections to the gauge boson vacuum polarizations with respect to the Standard Model we considered the effects on the T parameter. We finally derive the one loop modified fermion dispersion relations.Comment: RevTeX 4, 13 pages. Added references and corrected typo

    Reconstruction of three-dimensional porous media using generative adversarial neural networks

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    To evaluate the variability of multi-phase flow properties of porous media at the pore scale, it is necessary to acquire a number of representative samples of the void-solid structure. While modern x-ray computer tomography has made it possible to extract three-dimensional images of the pore space, assessment of the variability in the inherent material properties is often experimentally not feasible. We present a novel method to reconstruct the solid-void structure of porous media by applying a generative neural network that allows an implicit description of the probability distribution represented by three-dimensional image datasets. We show, by using an adversarial learning approach for neural networks, that this method of unsupervised learning is able to generate representative samples of porous media that honor their statistics. We successfully compare measures of pore morphology, such as the Euler characteristic, two-point statistics and directional single-phase permeability of synthetic realizations with the calculated properties of a bead pack, Berea sandstone, and Ketton limestone. Results show that GANs can be used to reconstruct high-resolution three-dimensional images of porous media at different scales that are representative of the morphology of the images used to train the neural network. The fully convolutional nature of the trained neural network allows the generation of large samples while maintaining computational efficiency. Compared to classical stochastic methods of image reconstruction, the implicit representation of the learned data distribution can be stored and reused to generate multiple realizations of the pore structure very rapidly.Comment: 21 pages, 20 figure

    Lorentz violating kinematics: Threshold theorems

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    Recent tentative experimental indications, and the subsequent theoretical speculations, regarding possible violations of Lorentz invariance have attracted a vast amount of attention. An important technical issue that considerably complicates detailed calculations in any such scenario, is that once one violates Lorentz invariance the analysis of thresholds in both scattering and decay processes becomes extremely subtle, with many new and naively unexpected effects. In the current article we develop several extremely general threshold theorems that depend only on the existence of some energy momentum relation E(p), eschewing even assumptions of isotropy or monotonicity. We shall argue that there are physically interesting situations where such a level of generality is called for, and that existing (partial) results in the literature make unnecessary technical assumptions. Even in this most general of settings, we show that at threshold all final state particles move with the same 3-velocity, while initial state particles must have 3-velocities parallel/anti-parallel to the final state particles. In contrast the various 3-momenta can behave in a complicated and counter-intuitive manner.Comment: V1: 32 pages, 6 figures, 3 tables. V2: 5 references adde

    Copper-doped CdSe/ZnS quantum dots : controllable photoactivated copper(I) cation storage and release vectors for catalysis

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    The first photoactivated doped quantum dot vector for metal-ion release has been developed. A facile method for doping copper(I) cations within ZnS quantum dot shells was achieved through the use of metal-dithiocarbamates, with Cu(+) ions elucidated by X-ray photoelectron spectroscopy. Photoexcitation of the quantum dots has been shown to release Cu(+) ions, which was employed as an effective catalyst for the Huisgen [3+2] cycloaddition reaction. The relationship between the extent of doping, catalytic activity, and the fluorescence quenching was also explored
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