13,162 research outputs found

    Hidden Dirac Monopoles

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    Dirac showed that the existence of one magnetic pole in the universe could offer an explanation of the discrete nature of the electric charge. Magnetic poles appear naturally in most grand unified theories. Their discovery would be of greatest importance for particle physics and cosmology. The intense experimental search carried thus far has not met with success. I proposed a universe with magnetic poles which are not observed free because they hide in deeply bound monopole--anti-monopole states named monopolium. I discuss the realization of this proposal and its consistency with known cosmological features. I furthermore analyze its implications and the experimental signatures that confirm the scenario.Comment: Comments: 15 pages, 3 figure

    Infrared spectrum and stability of a π-type hydrogen-bonded complex between the OH and C2H2 reactants

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    A hydrogen-bonded complex between the hydroxyl radical and acetylene has been stabilized in the reactant channel well leading to the addition reaction and characterized by infrared action spectroscopy in the OH overtone region. Analysis of the rotational band structure associated with the a-type transition observed at 6885.53(1) cm−1 (origin) reveals a T-shaped structure with a 3.327(5) Å separation between the centers of mass of the monomer constituents. The OH (v = 1) product states populated following vibrational predissociation show that dissociation proceeds by two mechanisms: intramolecular vibrational to rotational energy transfer and intermolecular vibrational energy transfer. The highest observed OH product state establishes an upper limit of 956 cm−1 for the stability of the π-type hydrogen-bonded complex. The experimental results are in good accord with the intermolecular distance and well depth at the T-shaped minimum energy configuration obtained from complementary ab initio calculations, which were carried out at the restricted coupled cluster singles, doubles, noniterative triples level of theory with extrapolation to the complete basis set limit

    Phase field modeling of electrochemistry II: Kinetics

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    The kinetic behavior of a phase field model of electrochemistry is explored for advancing (electrodeposition) and receding (electrodissolution) conditions in one dimension. We described the equilibrium behavior of this model in [J. E. Guyer, W. J. Boettinger, J.A. Warren, and G. B. McFadden, ``Phase field modeling of electrochemistry I: Equilibrium'', cond-mat/0308173]. We examine the relationship between the parameters of the phase field method and the more typical parameters of electrochemistry. We demonstrate ohmic conduction in the electrode and ionic conduction in the electrolyte. We find that, despite making simple, linear dynamic postulates, we obtain the nonlinear relationship between current and overpotential predicted by the classical ``Butler-Volmer'' equation and observed in electrochemical experiments. The charge distribution in the interfacial double layer changes with the passage of current and, at sufficiently high currents, we find that the diffusion limited deposition of a more noble cation leads to alloy deposition with less noble species.Comment: v3: To be published in Phys. Rev. E v2: Attempt to work around turnpage bug. Replaced color Fig. 4a with grayscale 13 pages, 7 figures in 10 files, REVTeX 4, SIunits.sty, follows cond-mat/030817

    Relative entropy via non-sequential recursive pair substitutions

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    The entropy of an ergodic source is the limit of properly rescaled 1-block entropies of sources obtained applying successive non-sequential recursive pairs substitutions (see P. Grassberger 2002 ArXiv:physics/0207023 and D. Benedetto, E. Caglioti and D. Gabrielli 2006 Jour. Stat. Mech. Theo. Exp. 09 doi:10.1088/1742.-5468/2006/09/P09011). In this paper we prove that the cross entropy and the Kullback-Leibler divergence can be obtained in a similar way.Comment: 13 pages , 2 figure

    Renal fibrosis in feline chronic kidney disease: known mediators and mechanisms of injury

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    Chronic kidney disease (CKD) is a common medical condition of ageing cats. In most cases the underlying aetiology is unknown, but the most frequently reported pathological diagnosis is renal tubulointerstitial fibrosis. Renal fibrosis, characterised by extensive accumulation of extra-cellular matrix within the interstitium, is thought to be the final common pathway for all kidney diseases and is the pathological lesion best correlated with function in both humans and cats. As a convergent pathway, renal fibrosis provides an ideal target for the treatment of CKD and knowledge of the underlying fibrotic process is essential for the future development of novel therapies. There are many mediators and mechanisms of renal fibrosis reported in the literature, of which only a few have been investigated in the cat. This article reviews the process of renal fibrosis and discusses the most commonly cited mediators and mechanisms of progressive renal injury, with particular focus on the potential significance to feline CKD

    Wigner-Yanase skew information as tests for quantum entanglement

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    A Bell-type inequality is proposed in terms of Wigner-Yanase skew information, which is quadratic and involves only one local spin observable at each site. This inequality presents a hierarchic classification of all states of multipartite quantum systems from separable to fully entangled states, which is more powerful than the one presented by quadratic Bell inequalities from two-entangled to fully entangled states. In particular, it is proved that the inequality provides an exact test to distinguish entangled from nonentangled pure states of two qubits. Our inequality sheds considerable light on relationships between quantum entanglement and information theory.Comment: 5 page

    Apparent horizons in simplicial Brill wave initial data

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    We construct initial data for a particular class of Brill wave metrics using Regge calculus, and compare the results to a corresponding continuum solution, finding excellent agreement. We then search for trapped surfaces in both sets of initial data, and provide an independent verification of the existence of an apparent horizon once a critical gravitational wave amplitude is passed. Our estimate of this critical value, using both the Regge and continuum solutions, supports other recent findings.Comment: 7 pages, 6 EPS figures, LaTeX 2e. Submitted to Class. Quant. Gra

    Permeability control on transient slip weakening during gypsum dehydration: Implications for earthquakes in subduction zones

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    © 2016 The Authors.A conflict has emerged from recent laboratory experiments regarding the question of whether or not dehydration reactions can promote unstable slip in subduction zones leading to earthquakes. Although reactions produce mechanical weakening due to pore-fluid pressure increase, this weakening has been associated with both stable and unstable slip. Here, new results monitoring strength, permeability, pore-fluid pressure, reaction progress and microstructural evolution during dehydration reactions are presented to identify the conditions necessary for mechanical instability. Triaxial experiments are conducted using gypsum and a direct shear sample assembly with constant normal stress that allows the measurement of permeability during sliding. Tests are conducted with temperature ramp from 70 to 150 °C and with different effective confining pressures (50, 100 and 150 MPa) and velocities (0.1 and 0.4 μm s-1). Results show that gypsum dehydration to bassanite induces transient stable-slip weakening that is controlled by pore-fluid pressure and permeability evolution. At the onset of dehydration, the low permeability promoted by pore compaction induces pore-fluid pressure build-up and stable slip weakening. The increase of bassanite content during the reaction shows clear evidence of dehydration related with the development of R1 Riedel shears and P foliation planes where bassanite is preferentially localized along these structures. The continued production of bassanite, which is stronger than gypsum, provides a supporting framework for newly formed pores, thus resulting in permeability increase, pore-fluid pressure drop and fault strength increase. After dehydration reaction, deformation is characterized by unstable slip on the fully dehydrated reaction product, controlled by the transition from velocity-strengthening to velocity-weakening behaviour of bassanite at temperature above ~140 °C and the localization of deformation along narrow Y-shear planes. This study highlights the generic conditions required to trigger instabilities during dehydration reactions. It shows that pore-fluid pressure build-up during dehydration reactions associated with the localization of a velocity-weakening reacting or dehydrated phase along shear planes is necessary for earthquake triggering
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