A comparative experimental study on the impact of standard and torrefied wood pellets on the drive parameters of a stratified batch gasifier

In these last years gasification studies have mainly involved raw biomasses. Recently, torrefied lignocellulosic materials have become particularly attractive but the majority of the investigations regarding this thermal treatment have been limited to the characterization of the feedstocks submitted to a wide range of working conditions. Only a limited and well documented number of works specifically dedicated to gasification of torrefied biomasses have been till now published. Most of these works, indeed, report results refer to industrial or pilot plants working within limited range conditions. As a consequence, extended investigations of the impact of the guide parameters of this process on a wide working conditions spectrum are not so easy to found. This work presents the results of an extended experimental campaign carried out on a specific small gasifier designed for a batch configuration and using air as gasification agent. The peculiarity of this experimental study consists in an on line monitoring of the biomass loss during the gasification process and in a direct experimental determination of the main parameters of the process as: the productivity of the syngas, its heating value, the amount of the remaining char, the power of the gasifier and the cold efficiency of the process. In particular the role of the air flow rate as critical parameter and its impact on the cited quantities is highlighted. For this investigation the results obtained for gasification tests of both commercial pellet (CP) and torrefied pellet (TP) characterized by a Mass Yield close to 80% are presented. The adopted experimental device allows to select several air flow rate ranging from 15 to 30 Nl·min-1. The L.H.V. of the syngas reaches values in the range 3.51 \u3c L.H.V. \u3c 3.85 and 4.14 \u3c L.H.V. \u3c 4.31 for CP and TP respectively. The maximum power values set at 2.73 kW for CP and 3.53 kW for TP. Interesting results can be deduced by reporting the trend of the cited quantities Vs. the air flow rate. As general result, the use of torrefied material confirms a significant improvement of the performances of the gasification process compared to those involving conventional biomasses. Please click Additional Files below to see the full abstract

Impact of TGA measurements on activation energy (ea) determination: case study applied to biomasses by means of isoconversional methods

This work reports the results of an extended kinetic study involving both experimental measurements and modeling elaborations. It is specifically dedicated to investigate the thermal behavior of selected biomasses undergoing to torrefaction treatment. Three biomasses representative of the hardwood family have been considered: ash-wood, beech-wood and hornbeam. As main purpose, this work is oriented to evaluate the impact of the TGA measurements on the final Activation Energy (Ea) results achieved by the adoption of the so called isoconversional “model free” methods, implemented on both their differential and integral version. Please click Additional Files below to see the full abstract

State-of-the-art of small-scale biomass gasification systems: An extensive and unique monitoring review

Abstract During the last few years, there has been an increasing interest in small-scale biomass gasification in Central and Northern Europe. Since 2011, almost fifty small-scale biomass gasification plants have been authorized and built in the South Tyrolean region (Italy), and most of them are currently operating. Within this framework, an extensive survey was performed by means of questionnaires to the plant owners for assessing the biomass and char flows in the region. Moreover, a comprehensive monitoring campaign was carried out onsite on representative plants of almost all the available operating technologies. For each of the monitored plants, the feedstock and the gasification products were characterized and their fluxes quantified, leading to energy and mass balances. This allowed collecting an extended set of data and drawing up a unique overview of the reference values for the ranges of operation of small-scale biomass gasification systems currently available in the European market, in terms of equivalence ratio, dry gas composition and heating value, specific electricity production, and conversion efficiencies. Moreover, samples of chars were deeply characterized, providing an insight into possible utilization pathways for the valorization of this by-product that is currently disposed of, representing an economical and environmental burden

The EEE Project

The new experiment ``Extreme Energy Events'' (EEE) to detect extensive air showers through muon detection is starting in Italy. The use of particle detectors based on Multigap Resistive Plate Chambers (MRPC) will allow to determine with a very high accuracy the direction of the axis of cosmic ray showers initiated by primaries of ultra-high energy, together with a high temporal resolution. The installation of many of such 'telescopes' in numerous High Schools scattered all over the Italian territory will also allow to investigate coincidences between multiple primaries producing distant showers. Here we present the experimental apparatus and its tasks.Comment: 4 pages, 29th ICRC 2005, Pune, Indi

Pt-Sn/C as a possible methanol-tolerant cathode catalyst for DMFC

An effective method was developed for preparing highly dispersed nano-sized Pt–Sn/C electrocatalyst synthesised by a modified polyol reduction method. From XRD patterns, the Pt–Sn/C peaks shifted slightly to lower 2θ angles when compared with commercial Pt/C catalyst, suggesting that Sn formed alloy with Pt. Based on HR-TEM images, the Pt–Sn/C nanoparticles showed small particle sizes and well dispersed onto the carbon support with a narrow particle distribution. The methanol oxidation reaction on the as-prepared Pt–Sn/C catalyst appeared at lower currents (+7.08 mA at +480 mV vs. Ag/AgCl) compared to the commercial Pt/C (+8.25 mA at +480 mV vs. Ag/AgCl) suggesting that the Pt–Sn/C catalyst has ‘methanol tolerance capabilities’. Pt–Sn/C HA Slurry pH3 catalysts showed better activity towards the oxygen-reduction reaction (ORR) than commercial Pt/C which could be attributed to smaller particle sizes. In our study, the Pt–Sn/C catalyst appears to be a promising methanol-tolerant catalyst with activity towards the ORR in the DMFC.Web of Scienc

Search for Slowly Moving Magnetic Monopoles with the MACRO Detector

A search for slowly moving magnetic monopoles in the cosmic radiation was conducted from October 1989 to November 1991 using the large liquid scintillator detector subsystem of the first supermodule of the MACRO detector at the Gran Sasso underground laboratory. The absence of candidates established an upper limit on the monopole flux of 5.6 × 10^(−15) cm^(−2) sr^(−1) s^(−1) at 90% confidence level in the velocity range of 10^(−4)≲β<4×10^(−3). This result places a new constraint on the abundance of monopoles trapped in our solar system

Gold nanoparticle-polymer nanocomposites synthesized by room temperature atmospheric pressure plasma and their potential for fuel cell electrocatalytic application

Conductive polymers have been increasingly used as fuel cell catalyst support due to their electrical conductivity, large surface areas and stability. The incorporation of metal nanoparticles into a polymer matrix can effectively increase the specific surface area of these materials and hence improve the catalytic efficiency. In this work, a nanoparticle loaded conductive polymer nanocomposite was obtained by a one-step synthesis approach based on room temperature direct current plasmaliquid interaction. Gold nanoparticles were directly synthesized from HAuCl4 precursor in poly(3,4-ethylenedioxythiophene) polystyrene sulfonate (PEDOT: PSS). The resulting AuNPs/PEDOT: PSS nanocomposites were subsequently characterized under a practical alkaline direct ethanol fuel cell operation condition for its potential application as an electrocatalyst. Results show that AuNPs sizes within the PEDOT: PSS matrix are dependent on the plasma treatment time and precursor concentration, which in turn affect the nanocomposites electrical conductivity and their catalytic performance. Under certain synthesis conditions, unique nanoscale AuNPs/PEDOT: PSS core-shell structures could also be produced, indicating the interaction at the AuNPs/polymer interface. The enhanced catalytic activity shown by AuNPs/PEDOT: PSS has been attributed to the effective electron transfer and reactive species diffusion through the porous polymer network, as well as the synergistic interfacial interaction at the metal/polymer and metal/metal interfaces.Funding Agencies|UK EPSRC [EP/K022237/1, EP/M024938/1, EP/P00394X/1, EP/I013229/1]; National Natural Science Foundation of China [51203135]; InvestNI [PoC-325]; Department of Employment Learning; EU-COST Action [TD1208]</p

Pseudo-single crystal electrochemistry on polycrystalline electrodes : visualizing activity at grains and grain boundaries on platinum for the Fe2+/Fe3+ redox reaction

The influence of electrode surface structure on electrochemical reaction rates and mechanisms is a major theme in electrochemical research, especially as electrodes with inherent structural heterogeneities are used ubiquitously. Yet, probing local electrochemistry and surface structure at complex surfaces is challenging. In this paper, high spatial resolution scanning electrochemical cell microscopy (SECCM) complemented with electron backscatter diffraction (EBSD) is demonstrated as a means of performing ‘pseudo-single-crystal’ electrochemical measurements at individual grains of a polycrystalline platinum electrode, while also allowing grain boundaries to be probed. Using the Fe2+/3+ couple as an illustrative case, a strong correlation is found between local surface structure and electrochemical activity. Variations in electrochemical activity for individual high index grains, visualized in a weakly adsorbing perchlorate medium, show that there is higher activity on grains with a significant (101) orientation contribution, compared to those with (001) and (111) contribution, consistent with findings on single-crystal electrodes. Interestingly, for Fe2+ oxidation in a sulfate medium a different pattern of activity emerges. Here, SECCM reveals only minor variations in activity between individual grains, again consistent with single-crystal studies, with a greatly enhanced activity at grain boundaries. This suggests that these sites may contribute significantly to the overall electrochemical behavior measured on the macroscale