General Cram\'er-Rao bound for parameter estimation using Gaussian multimode quantum resources

Multimode Gaussian quantum light, including multimode squeezed and/or multipartite quadrature entangled light, is a very general and powerful quantum resource with promising applications to quantum information processing and metrology involving continuous variables. In this paper, we determine the ultimate sensitivity in the estimation of any parameter when the information about this parameter is encoded in such Gaussian light, irrespective of the exact information extraction protocol used in the estimation. We then show that, for a given set of available quantum resources, the most economical way to maximize the sensitivity is to put the most squeezed state available in a well-defined light mode. This implies that it is not possible to take advantage of the existence of squeezed fluctuations in other modes, nor of quantum correlations and entanglement between different modes. We show that an appropriate homodyne detection scheme allows us to reach this Cramr-Rao bound. We apply finally these considerations to the problem of optimal phase estimation using interferometric techniques

Synthèse des impacts écologiques des feux et des coupes forestières sur les lacs de l'écozone boréale au Québec

Cet article présente une première synthèse comparative des impacts des feux et des coupes forestières sur la qualité des eaux et les communautés aquatiques des lacs de l'écozone boréale de l'est du Canada. La recherche a été réalisée de 1996 à 1998 dans le cadre d'un projet du Réseau de centre d'excellence sur la gestion durable des forêts (RCE-GDF) et porte sur 38 lacs du Bouclier Canadien du Québec. Les changements dans la qualité de l'eau ainsi que dans la diversité, la biomasse et la structure des communautés de plancton et de poissons ont été suivis pendant trois ans dans 20 lacs dont les bassins versants étaient non perturbés, dans 9 lacs qui avaient subit des coupes forestières et dans 9 lacs qui avaient subit des feux de forêt.Notre étude montre que les feux et les coupes ont des impacts significatifs qui diffèrent selon le type de perturbation. En général, les lacs affectés par les coupes et les feux ont des concentrations de phosphore 2 à 3 fois plus élevées que les lacs de référence. Toutefois, les lacs affectés par les feux montrent des concentrations en nitrates beaucoup plus élevées tandis que les lacs affectés par les coupes sont moins transparents et ont des eaux plus colorées, très riches en carbone organique dissous. Les feux et les coupes affectent aussi de façon différente la minéralisation des eaux et les concentrations des ions majeurs. Les feux et les coupes n'ont pas d'effet sur la biodiversité des communautés planctoniques, sauf dans les lacs ayant un grand bassin versant et plus de 40 % de perturbation. Aucune différence n'a été observée entre les lacs de référence et les lacs perturbés au niveau de l'occurrence, l'abondance et la croissance des espèces de poissons. En revanche, les feux et les coupes affectent la production et la structure des communautés aquatiques. Dans les lacs affectés par les feux, l'enrichissement en azote et phosphore provoque une hausse de la concentration en chlorophylle a, et de la biomasse du phytoplancton et du limnoplancton (seston > 53 µm), en particulier des diatomées, des rotifères et des gros crustacés, pendant deux à trois années après les feux. En revanche, dans les lacs affectés par les coupes, l'enrichissement en phosphore n'entraîne qu'une augmentation très faible et limitée à un an de la biomasse des algues et pas de changement dans les biomasses du limnoplancton, en raison de la forte couleur et de la transparence réduite des eaux, qui limite la production biologique. Les coupes ont un impact négatif sur les copépodes calanoïdes, un groupe de zooplancton caractéristique des lacs oligotrophes et transparents. Une diminution significative de la proportion des individus de petite taille a été observée chez les populations de perchaude et de meunier noir des lacs perturbés (lacs de coupe et de feux formant un seul groupe). Les impacts observés dans la qualité des eaux et la production du plancton augmentent avec l'importance relative des perturbations au niveau du bassin versant. Cependant, la variabilité dans les caractéristiques des bassins versants et des lacs, en particulier le rapport de drainage et le temps de résidence des eaux, a des effets confondants sur les réponses des écosystèmes lacustres aux perturbations par les feux et les coupes.This paper presents a comparative review on ecological impacts of wildfires and harvesting on water quality and aquatic community attributes of boreal lakes in eastern Canada. This project was carried out from 1996 to 1998, as part of the research program of the Sustainable Forest Management Network Centre of Excellence (NCE-SFM), on 38 lakes of the Boreal Canadian Shield (Québec, Canada). Changes in water quality, and in diversity, biomass and community structure of pelagic plankton and fish populations were monitored for 3 years in 20 reference lakes, 9 cut lakes and 9 burnt lakes.Our study shows that wildfires and logging have significant impacts on water quality as well as primary and secondary producers in boreal lakes. However, fire and logging does not have similar impacts. In general, cut and burnt lakes showed higher concentrations of total phosphorus (TP: 2-3 folds) than reference lakes. However nitrates concentrations (NO3-) were higher in burnt lakes than in reference and cut lakes, whereas dissolved organic carbon (DOC), light extinction coefficient (e PAR) and water colour were higher in cut lakes than in reference lakes, burnt lakes showing intermediate values. Wildfire and logging also affect ionic composition of lake water. Both burnt and cut lakes had higher concentrations of potassium (K+), chloride (Cl-) and calcium (Ca2+) than reference lakes, while sulphates (SO42-) and magnesium (Mg2+) increased only in burnt lakes. The observed increases in organic and mineral elements reflect their export from the watershed and were related to the drainage ratio. As mobile ions are rapidly flushed from the perturbed watersheds, ionic water composition returned to normal levels within three years after the perturbation. In contrast, some changes in water quality (P and N enrichment in perturbed lakes; DOC increase in cut lakes) seems to be on longer term and might have a more important effect on limnological features of lakes such as thermal stratification, mixed and euphotic depth, plankton biomass and bioaccumulation of mercury in zooplankton and fish.Wildfires and logging do not have significant impacts on species richness of planktonic communities, except for lakes with large drainage basins and those where the perturbation was higher than 40% of the watershed area. However, wildfires and logging affect biomass of plankton communities. In burnt lakes, the nutrient enrichment induced important increases in Chl. a concentration and phytoplankton biomass, and a small increase in limnoplankton biomass (seston > 53 µm). Diatoms, rotifers and large crustaceans showed significant increases. In burnt lakes, increases in phytoplankton were observed during the three years of the survey and were highest in the first 2 years after fires. Limnoplankton increases lasted only 2 years and were highest the second year after fires. In cut lakes, nutrient enrichment was not reflected in a proportional increase in plankton production due to increase in DOC concentrations and lake water colour that reduced water transparency. Phytoplankton slightly increased only the first year after logging and no increase was observed for limnoplankton and zooplankton. Logging negatively affect calanoids, a zooplankton group characteristic of clear and oligotrophic lakes. No significant differences were observed in the occurrence, abundance and growth of fish populations among reference and perturbed lakes. However, the proportion of small yellow perch and white sucker were significantly lower in populations of impacted lakes (burned and logged lakes pooled). In most cases, impacts on water quality and plankton communities were related to the intensity of fire or logging, when expressed as the percent area of watershed harvested or burnt divided by the lake surface or volume. Simple models may then be developed and help to predict the effect of harvesting practices on lake ecosystems. However, environmental variation in watershed and lakes characteristics, especially drainage ratio and lake water residence time, are important confounding factors in the responses of lakes to watershed perturbations by fire or logging. Lakes with drainage ratio > 4 and with more of 30% of their watershed perturbed are the most sensitive to fire and logging. These factors should be considered when developing lake management models in the boreal forest impacted by fire and logging

Dihydroxyacetone conversion into lactic acid in an aqueous medium in the presence of metal salts: influence of the ionic thermodynamic equilibrium on the reaction performance

International audienceThe catalytic conversion of dihydroxyacetone (DHA) to lactic acid (LA) via pyruvaldehyde (PA) in aqueous media was studied using different homogeneous metal salts. A kinetic model was developed and the parameters corresponding to each reaction steps were estimated. Agreement between experiments and simulated results was excellent and the performance of the different catalysts was consistent with previous studies described in the literature. Aluminium salts, which show the best performance, were tested in a whole range of concentrations and at different pH, in order to identify the catalytically active ionic species. It was confirmed that the DHA to pyruvaldehyde (PA) dehydration step is catalyzed by both Brønsted and Lewis acids whereas the consecutive reaction of PA to LA is solely catalyzed by Lewis acids. Moreover, comparing thermodynamic analysis of the reaction media and kinetic parameters demonstrated that cationic hydroxyl-aluminium complexes [Al(OH)h] (3-h)+ formed in situ by the hydrolysis of the aluminium aqua complexes like [Al(OH2)6] 3+ are the most active Lewis acids

Mapping snow depth in open alpine terrain from stereo satellite imagery

International audienceTo date, there is no definitive approach to map snow depth in mountainous areas from spaceborne sensors. Here, we examine the potential of very-high-resolution (VHR) optical stereo satellites to this purpose. Two triplets of 0.70 m resolution images were acquired by the Pléiades satellite over an open alpine catchment (14.5 km2) under snow-free and snow-covered conditions. The open-source software Ame's Stereo Pipeline (ASP) was used to match the stereo pairs without ground control points to generate raw photogrammetric clouds and to convert them into high-resolution digital elevation models (DEMs) at 1, 2, and 4 m resolutions. The DEM differences (dDEMs) were computed after 3-D coregistration, including a correction of a −0.48 m vertical bias. The bias-corrected dDEM maps were compared to 451 snow-probe measurements. The results show a decimetric accuracy and precision in the Pléiades-derived snow depths. The median of the residuals is −0.16 m, with a standard deviation (SD) of 0.58 m at a pixel size of 2 m. We compared the 2 m Pléiades dDEM to a 2 m dDEM that was based on a winged unmanned aircraft vehicle (UAV) photogrammetric survey that was performed on the same winter date over a portion of the catchment (3.1 km2). The UAV-derived snow depth map exhibits the same patterns as the Pléiades-derived snow map, with a median of −0.11 m and a SD of 0.62 m when compared to the snow-probe measurements. The Pléiades images benefit from a very broad radiometric range (12 bits), allowing a high correlation success rate over the snow-covered areas. This study demonstrates the value of VHR stereo satellite imagery to map snow depth in remote mountainous areas even when no field data are available

Gradient echo quantum memory in warm atomic vapor

Video Article - http://www.jove.com/video/50552Gradient echo memory (GEM) is a protocol for storing optical quantum states of light in atomic ensembles. The primary motivation for such a technology is that quantum key distribution (QKD), which uses Heisenberg uncertainty to guarantee security of cryptographic keys, is limited in transmission distance. The development of a quantum repeater is a possible path to extend QKD range, but a repeater will need a quantum memory. In our experiments we use a gas of rubidium 87 vapor that is contained in a warm gas cell. This makes the scheme particularly simple. It is also a highly versatile scheme that enables in-memory refinement of the stored state, such as frequency shifting and bandwidth manipulation. The basis of the GEM protocol is to absorb the light into an ensemble of atoms that has been prepared in a magnetic field gradient. The reversal of this gradient leads to rephasing of the atomic polarization and thus recall of the stored optical state. We will outline how we prepare the atoms and this gradient and also describe some of the pitfalls that need to be avoided, in particular four-wave mixing, which can give rise to optical gain.Olivier Pinel, Mahdi Hosseini, Ben M. Sparkes, Jesse L. Everett, Daniel Higginbottom, Geoff T. Campbell, Ping Koy Lam, Ben C. Buchle

Variations à court terme des compartiments planctoniques d'un lac humique du Bouclier canadien

Les variations spatio-temporelles à court terme des compartiments planctoniques ont été étudiées simultanément du 30 juillet au 5 août 1986 dans un lac humique du Bouclier canadien. L'abondance du bactérioplancton fluctue de 1,4 à 1,7.106 cell. ml.-1 (coloration DAPI) ou de 2,7 à 7,7.106 cell. ml-1; (coloration Acridine Orange). La production du bactérioplancton estimée par incorporation de 3H méthyl thimidine, varie de 4 à 24.106 cell. l-1 h-1. Les valeurs d'activité hétérotrophe potentielle bactérienne estimée par assimilation de 14C glucose, s'échelonnent de 0,007 à 0,065 µg C.l-1. h-1. La biomasse pigmentaire (chlore. a et pheopigments) varie de 6,8 à 21,7 mg.m-3 . La production primaire est très faible (max. : 10 mg C. m-3 .h-1; 20 mg C.m-2 .h-1 ) et décroît très rapidement avec la profondeur (25 % à 82 % dans le premier mètre). Le microzooplancton (Rotifères, Bosmina, nauplies) représente plus de 90 % du peuplement zooplanctonique et les taux de broutage global du macrozooplancton sont faibles (25 % j-1). Les compartiments hétérotrophes prédominent dans le métabolisme du lac par rapport au compartiment autotrophe. Les patrons de variation spatiale reflètent la stratification verticale des compartiments et des processus autotrophes et hétérotrophes. Les maxima de photosynthèse, d'ATP et de production bactérienne se situent dans les eaux épilimnétiques tandis que les maxima d'abondance du bactérioptancton et des pigments se rencontrent dans l'hypolimnion. Le zooplancton est plus dense et broute d'avantage dans la strate 1-3 m. Ces variations spatiales semblent influencer l'activité hétérotrophe potentielle du bactérioptancton. Nos résultats montrent aussi des variations temporelles à court terme de la production primaire, de l'assimilation hétérotrophe et du broutage du macrozooplancton. Cette étude préliminaire met en lumière la nécessité de tenir compte des variations à court terme lors des études des relations trophodynamiques dans les écosystèmes planctoniques.Short term spatial and temporal variations in planktonic compartments were studied simultaneously, from July 30th to August 5th, 1986, in a humic lake on the Canadian Shield. Abundance of bacterioplankton ranged from 1,4 to 1,7 106 cell. ml-1 (DAP1) or from 2,7 to 7,7 106 cell. ml-1 (Acridine Orange). Bacterial production, as measured by incorporation of 3H methyl-thimidine, was estimated at 4-24 106 cells. l-1. h-1 and potential heterotrophic bacterial activity ranged from 0,007 to 0,065 µg C.l-1. h-1, as estimated by 14C glucose incorporation. Pigments biomass (chloro. a and phaeopigments) varied from 6,8 to 21,7 mg m-3. Primary production was low (max. : 10 mg C.m-3. h-1; 20 mg C.m-2. h-1) and decreased rapidly with depth (25-82 % in 1 m depth). Microzooplankton (rotifera, Bosmina, nauplii) accounted for more than 90 % of total numbers and macrozooplankton global grazing rates were low (25 % d-1). The heterotrophic compartments play a greater rate in the lake metabolism than the autotrophic compartment. Spatial variations reflect the stratification of the heterotrophic and autotrophic organisms and processes with depth. Maximum levels in primary production, ATP and bacterial production occur in epilimnetic waters, while maxima in bacterial numbers and algal pigments occur in the hypolimnion. Zooplancton density and macrozooplankton grazing rates were higher in the 1-3 m strata. These spatial patterns seem to influence the vertical profiles of the bacterial potential heterotrophic activity. Our results also show short term temporal variations in primary production, potential heterotrophic activity of bacterioplankton and macrozooplankton grazing rates. This preliminary study stresses the importance of short term variations in the assessment of the trophodynamics of the planktonic food wed

Correction of interferometric and vegetation biases in the SRTMGL1 spaceborne DEM with hydrological conditioning towards improved hydrodynamics modeling in the Amazon Basin

In the Amazon basin, the recently released SRTM Global 1 arc-second (SRTMGL1) remains the best topographic information for hydrological and hydrodynamic modeling purposes. However, its accuracy is hindered by errors, partly due to vegetation, leading to erroneous simulations. Previous efforts to remove the vegetation signal either did not account for its spatial variability or relied on a single assumed percentage of penetration of the SRTM signal. Here, we propose a systematic approach over an Amazonian floodplain to remove the vegetation signal, addressing its heterogeneity by combining estimates of vegetation height and a land cover map. We improve this approach by interpolating the first results with drainage network, field and altimetry data to obtain a hydrological conditioned DEM. The averaged interferometric and vegetation biases over the forest zone were found to be -2.0 m and 7.4 m, respectively. Comparing the original and corrected DEM, vertical validation against Ground Control Points shows a RMSE reduction of 64%. Flood extent accuracy, controlled against Landsat and JERS-1 images, stresses improvements in low and high water periods (+24% and +18%, respectively). This study also highlights that a ground truth drainage network, as a unique input during the interpolation, achieves reasonable results in terms of flood extent and hydrological characteristics

Exposure to Household Air Pollution from Biomass Cookstoves and Blood Pressure Among Women in Rural Honduras: A Cross‐Sectional Study

Growing evidence links household air pollution exposure from biomass cookstoves with elevated blood pressure. We assessed cross‐sectional associations of 24‐hour mean concentrations of personal and kitchen fine particulate matter (PM2.5), black carbon (BC), and stove type with blood pressure, adjusting for confounders, among 147 women using traditional or cleaner‐burning Justa stoves in Honduras. We investigated effect modification by age and body mass index. Traditional stove users had mean (standard deviation) personal and kitchen 24‐hour PM2.5 concentrations of 126 μg/m3 (77) and 360 μg/m3 (374), while Justa stove users’ exposures were 66 μg/m3 (38) and 137 μg/m3(194), respectively. BC concentrations were similarly lower among Justa stove users. Adjusted mean systolic blood pressure was 2.5 mm Hg higher (95% CI, 0.7‐4.3) per unit increase in natural log‐transformed kitchen PM2.5 concentration; results were stronger among women of 40 years or older (5.2 mm Hg increase, 95% CI, 2.3‐8.1). Adjusted odds of borderline high and high blood pressure (categorized) were also elevated (odds ratio = 1.5, 95% CI, 1.0‐2.3). Some results included null values and are suggestive. Results suggest that reduced household air pollution, even when concentrations exceed air quality guidelines, may help lower cardiovascular disease risk, particularly among older subgroups