Nueva sonda TDR para la medida de la conductividad eléctrica de la solución del suelo

Esta comunicación presenta una sonda TDR (WECP) para la medida de la conductividad eléctrica de la solución del suelo (σw), que consiste en una sonda TDR trifilar (10 cm longitud) insertadas en 14 discos cerámicos. La σw se estima a partir de la humedad y la conductividad eléctrica del conjunto de discos cerámicos. La WECP fue calibrada y testada en laboratorio con suelo franco y en condiciones de campo con diferentes soluciones de KCl. La σw estimada con WECP en laboratorio fue comparada con las obtenidas a partir de la solución de drenaje. El experimento de campo comparó σw estimados con WECP con los medidos con lisímetros de tensión. En ambos experimentos se observó una buena y significativa correlación (R2 ≥ 0,97; P < 0,001; Coeficiente de eficeincia Nash-Sutdiffe > 0,96) entre los valores de σw estimados con WECP y los obtenidos en laboratorio y campo a partir de la solución de drenajeEsta comunicación presenta una sonda TDR (WECP) para la medida de la conductividad eléctrica de la solución del suelo (σw), que consiste en una sonda TDR trifilar (10 cm longitud) insertadas en 14 discos cerámicos. La σw se estima a partir de la humedad y la conductividad eléctrica del conjunto de discos cerámicos. La WECP fue calibrada y testada en laboratorio con suelo franco y en condiciones de campo con diferentes soluciones de KCl. La σw estimada con WECP en laboratorio fue comparada con las obtenidas a partir de la solución de drenaje. El experimento de campo comparó σw estimados con WECP con los medidos con lisímetros de tensión. En ambos experimentos se observó una buena y significativa correlación (R2 ≥ 0,97; P < 0,001; Coeficiente de eficeincia Nash-Sutdiffe > 0,96) entre los valores de σw estimados con WECP y los obtenidos en laboratorio y campo a partir de la solución de drenajePublishe

Effect of the refining process on total hydroxytyrosol, tyrosol, and tocopherol contents of olive oil

The impact of the olive oil refining process on major antioxidant compound levels was evaluated by means of UHPLC analysis of lampante olive oils collected at different stages of the refining procedure (degumming, chemical and physical flash neutralization, bleaching, and deodorization). For this purpose, the evolution of the tocopherol fraction was investigated by means of the UHPLC-FL method, while the influence of the refining process on the total hydrolyzed phenolic content was assessed by measuring hydroxytyrosol and tyrosol levels after acid hydrolysis of the phenolic extracts. Refining was found to have a marked effect on total hydroxytyrosol and tyrosol contents, as they are completely removed in the early steps of the refining procedure. In contrast, the variation trends of tocopherols are not always clear-cut, and significant decreases in content from 7% to 16% were only revealed during refining in four out of nine samples. In addition, five of the nine refined oils showed final tocopherol concentrations higher than 200 mg/kg, the limit imposed by international standards regarding the content of such compounds in commercial olive oils. This study supports the need for a revision of the International Olive Oil Council (IOC) standard relative to the limit established for tocopherol addition to refined oils to avoid possible legal and economic trade issues

VSP Traveltime Inversion: Near-Surface Issues

P-wave velocity information obtained from vertical seismic profiles (VSPs) can be useful in imaging subsurface structure, either by directly detecting changes in the subsurface or as an aid to the interpretation of seismic reflection data. In the shallow subsurface, P-wave velocity can change by nearly an order of magnitude over a short distance, so curved rays are needed to accurately model VSP traveltimes. We used a curved-ray inversion to estimate the velocity profile and the discrepancy principle to estimate the data noise level and to choose the optimum regularization parameter. The curved-ray routine performed better than a straight-ray inversion for synthetic models containing high-velocity contrasts. The application of the inversion to field data produced a velocity model that agreed well with prior information. These results show that curved-ray inversion should be used to obtain velocity information from VSPs in the shallow subsurface

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Enhancement of the Binding Energy of Charged Excitons in Disordered Quantum Wires

Negatively and positively charged excitons are identified in the spatially-resolved photoluminescence spectra of quantum wires. We demonstrate that charged excitons are weakly localized in disordered quantum wires. As a consequence, the enhancement of the "binding energy" of a charged exciton is caused, for a significant part, by the recoil energy transferred to the remaining charged carrier during its radiative recombination. We discover that the Coulomb correlation energy is not the sole origin of the "binding energy", in contrast to charged excitons confined in quantum dots.Comment: 4 Fig

Applicability of the photogrammetry technique to determine the volume and the bulk density of small soil aggregates

Aggregate density (¿) is defined as the relationship between the mass and the volume occupied by an aggregate. Previous studies have characterised ¿ on large to medium-sized soil aggregates (>4mm diameter); however, little information is available for smaller aggregates (0.99, P<0.0001) between the volumes estimated on rough stones with the PHM and Archimedes methods demonstrates that this technique can be satisfactorily used to estimate the volume and, consequently, the ¿ of small soil aggregates. The results showed an increase in ¿ with decreasing aggregate size. A general trend of increasing ¿ with the degree of soil disturbance by tillage was also observed

CT angiography, MR angiography and rotational digital subtraction angiography for volumetric assessment of intracranial aneurysms. An experimental study

The purpose of our experimental study was to assess the accuracy and precision of CT angiography (CTA), MR angiography (MRA) and rotational digital subtraction angiography (DSA) for measuring the volume of an in vitro aneurysm model. A rigid model of the anterior cerebral circulation harbouring an anterior communicating aneurysm was connected to a pulsatile circuit. It was studied using unenhanced 3D time-of-flight MRA, contrast-enhanced CTA and rotational DSA angiography. The source images were then postprocessed on dedicated workstations to calculate the volume of the aneurysm. CTA was more accurate than MRA (P=0.0019). Rotational DSA was more accurate than CTA, although the difference did not reach statistical significance (P=0.1605), and significantly more accurate than MRA (P<0.00001). CTA was more precise than MRA (P=0.12), although this did not reach statistical significance. Rotational DSA can be part of the diagnosis, treatment planning and support endovascular treatment of intracranial aneurysms. The emerging endovascular treatment techniques which consist of using liquid polymers as implants to exclude aneurysms from arterial circulation would certainly benefit from this precise measurement of the volume of aneurysm

Two-Stage Rotational Disordering of a Molecular Crystal Surface: C60

We propose a two-stage mechanism for the rotational surface disordering phase transition of a molecular crystal, as realized in C$_{60}$ fullerite. Our study, based on Monte Carlo simulations, uncovers the existence of a new intermediate regime, between a low temperature ordered $(2 \times 2)$ state, and a high temperature $(1 \times 1)$ disordered phase. In the intermediate regime there is partial disorder, strongest for a subset of particularly frustrated surface molecules. These concepts and calculations provide a coherent understanding of experimental observations, with possible extension to other molecular crystal surfaces.Comment: 4 pages, 2 figure

Molecularly imprinted polymer as selective sorbent for the extraction of zearalenone in edible vegetable oils

A method based on the selective extraction of zearalenone (ZON) from edible vegetable oils using molecularly imprinted polymer (MIP) has been developed and validated. Ultra-high-pressure liquid chromatography coupled with a fluorescence detection system was employed for the detection of zearalenone. The method was applied to the analysis of zearalenone in maize oil samples spiked at four concentration levels within the maximum permitted amount specified by the European Commission Regulation (EC) No. 1126/2007. As a result, the proposed methodology provided high recoveries (>72%) with good linearity (R2 > 0.999) in the range of 10-2000 \u3bcg/kg and a repeatability relative standard deviation below 1.8%. These findings meet the analytical performance criteria specified by the European Commission Regulation No. 401/2006 and reveal that the proposed methodology can be successfully applied for monitoring zearalenone at trace levels in di_erent edible vegetable oils. Acomparison of MIP behavior with the ones of QuEChERS and liquid-liquid extraction was also performed, showing higher extraction rates and precision of MIP. Finally, the evolution of ZON contamination during the maize oil refining process was also investigated, demonstrating how the process is unable to completely remove (60%) ZON from oil samples