394 research outputs found

    Casein and Caseinogen.

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    EPR identification of defects responsible for thermoluminescence in Cu-doped lithium tetraborate (Li2B4O7) crystals

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    Electron paramagnetic resonance (EPR) is used to identify the electron and hole traps responsible for thermoluminescence (TL) peaks occurring near 100 and 200 ◦C in copper-doped lithium tetraborate (Li2B4O7) crystals. As-grown crystals have Cu+ and Cu2+ ions substituting for lithium and have Cu+ ions at interstitial sites. All of the substitutional Cu2+ ions in the as-grown crystals have an adjacent lithium vacancy and give rise to a distinct EPR spectrum. Exposure to ionizing radiation at room temperature produces a second and different Cu2+ EPR spectrum when a hole is trapped by substitutional Cu+ ions that have no nearby defects. These two Cu2+ trapped-hole centers are referred to as Cu2+-VLi and Cu2+active, respectively. Also during the irradiation, two trapped-electron centers in the form of interstitial Cu0 atoms are produced when interstitial Cu+ ions trap electrons. They are observed with EPR and are labeled Cu0A and Cu0B. When an irradiated crystal is warmed from 25 to 150 ◦C, the Cu2+active centers have a partial decay step that correlates with the TL peak near 100 ◦C. The concentrations of Cu0A and Cu0B centers, however, increase as the crystal is heated through this range. As the crystal is futher warmed between 150 and 250 ◦C, the EPR signals from the Cu2+active hole centers and Cu0A and Cu0B electron centers decay simultaneously. This decay step correlates with the intense TL peak near 200 ◦C

    Photoconductivity Parameters In Lithium Niobate

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    Measurements on a variety of doped (magnesium and/or iron) and undoped lithium niobate crystals in the oxidized state demonstrate an Arrhenius dependence of dark conductivity on reciprocal temperature between 460 and 590 K. All of the crystals had roughly the same conductivity and activation energy (1.21 eV) over the temperature range, implying that all have about the same free-carrier concentration and mobility. The enhanced photoconductivity of magnesium-doped lithium niobate is attributed to a greatly reduced trapping cross section of Fe3+ for electrons, the smaller cross section being due to a changed substitutional site for Fe3+. The Fe3+ trapping cross section is calculated from photoconductivity data to be of order 10-18 m2 in undoped lithium niobate. This implies a photoelectron lifetime of order 6x10-11 s in a relatively pure (2-ppm Fe) oxidized crystal

    Fast Measurements of Flow Through Mitral Regurgitant Orifices With Magnetic Resonance Phase Velocity Mapping

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    Magnetic-resonance (MR) phase velocity mapping (PVM) shows promise in measuring the mitral regurgitant volume. However, in its conventional nonsegmented form, MR-PVM is slow and impractical for clinical use. The aim of this study was to evaluate the accuracy of rapid, segmented k-spaceMR-PVM in quantifying the mitral regurgitant flow through a control volume (CV) method. Two segmented MR-PVM schemes, one with seven (seg-7) and one with nine (seg-9) lines per segment, were evaluated in acrylic regurgitant mitral valve models under steady and pulsatile flow. A nonsegmented (nonseg) MR-PVM acquisition was also performed for reference. The segmented acquisitions were considerably faster (min) than the nonsegmented (\u3e45 min). The regurgitant flow rates and volumes measured with segmented MR-PVM agreed closely with those measured with nonsegmented MR-PVM (differences 0.05), when the CV was large enough to exclude the region of flow acceleration and aliasing from its boundaries. The regurgitant orifice shape (circular vs. slit-like) and the presence of aortic outflow did not significantly affect the accuracy of the results under both steady and pulsatile flow (p\u3e0.05). This study shows that segmented k-space MR-PVM canaccurately quantify the flow through regurgitant orifices using the CV method and demonstrates great clinical potential

    Sandstone matrix acidizing knowledge and future development

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    To meet rising global demands for energy, the oil and gas industry continuously strives to develop innovative oilfield technologies. With the development of new enhanced oil recovery techniques, sandstone acidizing has been significantly developed to contribute to the petroleum industry. Different acid combinations have been applied to the formation, which result in minimizing the near wellbore damage and improving the well productivity. A combination of hydrofluoric acid and hydrochloric acid (HF:HCl) known as mud acid has gained attractiveness in improving the porosity and permeability of the reservoir formation. However, high-temperature matrix acidizing is now growing since most of the wells nowadays become deeper and hotter temperature reservoirs, with a temperature higher than 200 °F. As a result, mud acid becomes corrosive, forms precipitates and reacts rapidly, which causes early consumption of acid, hence becoming less efficient due to high pH value. However, different acids have been developed to combat these problems where studies on retarded mud acids, organic-HF acids, emulsified acids, chelating agents have shown their effectiveness at different conditions. These acids proved to be alternative to mud acid in sandstone acidizing, but the reaction mechanism and experimental analysis have not yet been investigated. The paper critically reviews the sandstone acidizing mechanism with different acids, problems occurred during the application of different acids and explores the reasons when matrix stimulation is successful over fracturing. This paper also explores the future developing requirement for matrix acidizing treatments and new experimental techniques that can be useful for further development, particularly in developing new acids and acidizing techniques, which would provide better results and information of topology, morphology and mineral dissolution and the challenges associated with implementing these “new” technologies

    Observation Of Singly Ionized Selenium Vacancies In Znse Grown By Molecular Beam Epitaxy

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    Electron paramagnetic resonance(EPR) has been used to investigate singly ionized selenium vacancy V Se + centers in ZnSe epilayers grown by molecular beam epitaxy(MBE). The study included undoped and nitrogen-doped films. Spectra taken at 8 K and 9.45 GHz, as the magnetic field was rotated in the plane from [100] to [010], showed an isotropic signal at g =2.0027±0.0004 with a linewidth of 5.8 G. In the two samples where this signal was observed, estimates of concentration were approximately 1.1×10 17 and 6.3×10 17 cm −3 . The appearance of the EPR signal correlated with an increase in the Zn/Se beam equivalent pressure ratio (during growth) in undoped films and with an increase in the nitrogen concentration in doped films. We conclude that the singly ionized selenium vacancy may be a dominant point defect in many MBE-grown ZnSe layers and that these defects may play a role in the compensation mechanisms in heavily nitrogen-doped ZnSe thin films

    Noninvasive Quantification of Fluid Mechanical Energy Losses in the Total Cavopulmonary Connection with Magnetic Resonance Phase Velocity Mapping

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    A major determinant of the success of surgical vascular modifications, such as the total cavopulmonary connection (TCPC), is the energetic efficiency that is assessed by calculating the mechanical energy loss of blood flow through the new connection. Currently, however, to determine the energy loss, invasive pressure measurements are necessary. Therefore, this study evaluated the feasibility of the viscous dissipation (VD) method, which has the potential to provide the energy loss without the need for invasive pressure measurements. Two experimental phantoms, a U-shaped tube and a glass TCPC, were scanned in a magnetic resonance (MR) imaging scanner and the images were used to construct computational models of both geometries. MR phase velocity mapping (PVM) acquisitions of all three spatial components of the fluid velocity were made in both phantoms and the VD was calculated. VD results from MR PVM experiments were compared with VD results from computational fluid dynamics (CFD) simulations on the image-based computational models. The results showed an overall agreement between MR PVM and CFD. There was a similar ascending tendency in the VD values as the image spatial resolution increased. The most accurate computations of the energy loss were achieved for a CFD grid density that was too high for MR to achieve under current MR system capabilities (in-plane pixel size of less than 0.4 mm). Nevertheless, the agreement between the MR PVM and the CFD VD results under the same resolution settings suggests that the VD method implemented with a clinical imaging modality such as MR has good potential to quantify the energy loss in vascular geometries such as the TCPC

    Transition-metal ions in β-Ga\u3csub\u3e2\u3c/sub\u3eO\u3csub\u3e3\u3c/sub\u3e crystals: Identification of Ni acceptors

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    Excerpt: Transition-metal ions (Ni, Cu, and Zn) in β-Ga2O3 crystals form deep acceptor levels in the lower half of the bandgap. In the present study, we characterize the Ni acceptors in a Czochralski-grown crystal and find that their (0/−) level is approximately 1.40 eV above the maximum of the valence band
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