Characterization of the ultrafine and fine particles formed during laser cladding with the Inconel 718 metal powder by means of X-ray spectroscopic techniques

Additive manufacturing is a rapidly growing industrial technology. Still, there is a lack of knowledge regarding the fine particle emission and new particle formation during the processes and their consequences on the performance of the operation and the operator's health as well. Therefore, we studied the properties of the emitted particles during the 3D printing process using the Inconel 718 (Ni-based) superalloy. The number and the mass concentrations were measured with a Scanning Mobility Particle Counter and Sizer. Size-fractionated samples were collected by a cascade impactor, and the elemental composition of the particles was determined by total-reflection X-ray fluorescence analysis, Scanning Electron Microscopy, Energy Dispersive Spectroscopy, and microscopic X-ray fluorescence analysis in the different size fractions. The oxidation states of the metals (Cr, Mn, Fe, Ni) in the samples were determined with the X-ray absorption near-edge structure (XANES) method. Most of the particles were found in the ultrafine region with a size below 100 nm, and the mass size distribution had the maximum at 85 nm. In the original powder, Ni was dominating with appr. 52 wt%, and the proportion of Cr was around 20 wt%, and Mn was below 1 wt%. In the released particles, the Ni content decreased to appr. 26 wt%, the Cr content increased to appr. 47 wt% and Mn increased to around 10 wt% for particles with a size between 0.07 and 10 μm. According to the XANES results, Cr, Mn and Fe were found to be oxidized significantly, whereas Ni remained in the metallic form in the total emitted aerosol containing mostly ultrafine particles. The enrichment and oxidation of metals were correlated with each other

Comparative analysis of SERS substrates of different morphology

In this work the surface enhanced Raman scattering (SERS) performance of gold coated patterned silicon surfaces of different morphology and period was investigated. Arrays of inverse pyramids, spheres and rounded pyramids of different sizes were fabricated by photolithography and selective etching. Thin layer of gold was sputtered onto the surface of the samples. The SERS performance of the substrates was tested using a highly dissolved organic solution

CODEX-B4C Experiment: Cored Degradation Test With Boron Carbide Control Rod KFKI-2003-01/G (2003)

The CODEX-B4C bundle test has been successfully performed on 25th May 2001 in the framework of the COLOSS project of the EU 5th FWP. The high temperature degradation of a VVER-1000 type bundle with B4C control rod was investigated with electrically heated fuel rods. The experiment was carried out according to a scenario selected in favour of methane formation. Degradation of control rod and fuel bundle took place at temperatures ~2000 oC, cooling down of the bundle was performed in steam atmosphere. The gas composition measurement indicated no methane production during the experiment. High release of aerosols was detected in the high temperature oxidation phase. The on-line measured data are collected into a database and are available for code validation and development

Pre-Excitation Studies for Rubidium-Plasma Generation

The key element in the Proton-Driven-Plasma-Wake-Field-Accelerator (AWAKE) project is the generation of highly uniform plasma from Rubidium vapor. The standard way to achieve full ionization is to use high power laser which can assure the over-barrier-ionization (OBI) along the 10 meters long active region. The Wigner-team in Budapest is investigating an alternative way of uniform plasma generation. The proposed Resonance Enhanced Multi Photon Ionization (REMPI) scheme probably can be realized by much less laser power. In the following the resonant pre-excitations of the Rb atoms are investigated, theoretically and the status report about the preparatory work on the experiment are presented.Comment: 8 pages, 6 figures, submitted to Nucl. Inst. and Meth. in Phys. Res.

Measuring Measurement: Theory and Practice

Recent efforts have applied quantum tomography techniques to the calibration and characterization of complex quantum detectors using minimal assumptions. In this work we provide detail and insight concerning the formalism, the experimental and theoretical challenges and the scope of these tomographical tools. Our focus is on the detection of photons with avalanche photodiodes and photon number resolving detectors and our approach is to fully characterize the quantum operators describing these detectors with a minimal set of well specified assumptions. The formalism is completely general and can be applied to a wide range of detectorsComment: 22 pages, 27 figure

Investigation of Aerosols Released at High Temperature from Nuclear Reactor Core Models.

Abstract not availableJRC.(EI)-Environment Institut