SLOCLIM: a high-resolution daily gridded precipitation and temperature dataset for Slovenia

We present a new publicly available daily gridded dataset of maximum and minimum temperature and precipitation data covering the whole territory of Slovenia from 1950 to 2018. It represents the great variability of climate at the crossroads between the Mediterranean, Alpine and continental climatic regimes with altitudes between 0-2864ma.s.l. We completely reconstructed (quality control and gap filling) the data for the three variables from 174 observatories (climatological, precipitation and automatic stations) with the original records all over the country. A comprehensive quality control process based on the spatial coherence of the data was applied to the original dataset, and the missing values were estimated for each day and location independently. Using the filled data series, a grid of 1 x 1 km spatial resolution with 20 998 points was created by estimating daily temperatures (minimum and maximum) and precipitation, as well as their corresponding uncertainties at each grid point. In order to show the potential applications, four daily temperature indices and two on precipitation were calculated to describe the spatial distribution of (1) the absolute maximum and minimum temperature, (2) the number of frost days, (3) the number of summer days, (4) the intensity of precipitation and (5) the maximum number of consecutive dry days. The use of all the available information, the complete quality control and the high spatial resolution of the grid allowed for an accurate estimate of precipitation and temperature that represents a precise spatial and temporal distribution of daily temperatures and precipitation in Slovenia. The SLOCLIM dataset is publicly available at https://doi.org/10.5281/zenodo.4108543 and http://www.sloclim.eu (last access: 10 June 2021) and can be cited as Skrk et al. (2020)

Current model capabilities for simulating black carbon and sulfate concentrations in the Arctic atmosphere: a multi-model evaluation using a comprehensive measurement data set

The concentrations of sulfate, black carbon (BC) and other aerosols in the Arctic are characterized by high values in late winter and spring (so-called Arctic Haze) and low values in summer. Models have long been struggling to capture this seasonality and especially the high concentrations associated with Arctic Haze. In this study, we evaluate sulfate and BC concentrations from eleven different models driven with the same emission inventory against a comprehensive pan-Arctic measurement data set over a time period of 2 years (2008–2009). The set of models consisted of one Lagrangian particle dispersion model, four chemistry transport models (CTMs), one atmospheric chemistry-weather forecast model and five chemistry climate models (CCMs), of which two were nudged to meteorological analyses and three were running freely. The measurement data set consisted of surface measurements of equivalent BC (eBC) from five stations (Alert, Barrow, Pallas, Tiksi and Zeppelin), elemental carbon (EC) from Station Nord and Alert and aircraft measurements of refractory BC (rBC) from six different campaigns. We find that the models generally captured the measured eBC or rBC and sulfate concentrations quite well, compared to previous comparisons. However, the aerosol seasonality at the surface is still too weak in most models. Concentrations of eBC and sulfate averaged over three surface sites are underestimated in winter/spring in all but one model (model means for January–March underestimated by 59 and 37 % for BC and sulfate, respectively), whereas concentrations in summer are overestimated in the model mean (by 88 and 44 % for July–September), but with overestimates as well as underestimates present in individual models. The most pronounced eBC underestimates, not included in the above multi-site average, are found for the station Tiksi in Siberia where the measured annual mean eBC concentration is 3 times higher than the average annual mean for all other stations. This suggests an underestimate of BC sources in Russia in the emission inventory used. Based on the campaign data, biomass burning was identified as another cause of the modeling problems. For sulfate, very large differences were found in the model ensemble, with an apparent anti-correlation between modeled surface concentrations and total atmospheric columns. There is a strong correlation between observed sulfate and eBC concentrations with consistent sulfate/eBC slopes found for all Arctic stations, indicating that the sources contributing to sulfate and BC are similar throughout the Arctic and that the aerosols are internally mixed and undergo similar removal. However, only three models reproduced this finding, whereas sulfate and BC are weakly correlated in the other models. Overall, no class of models (e.g., CTMs, CCMs) performed better than the others and differences are independent of model resolution

Current model capabilities for simulating black carbon and sulfate concentrations in the Arctic atmosphere: a multi-model evaluation using a comprehensive measurement data set

The concentrations of sulfate, black carbon (BC) and other aerosols in the Arctic are characterized by high values in late winter and spring (so-called Arctic Haze) and low values in summer. Models have long been struggling to capture this seasonality and especially the high concentrations associated with Arctic Haze. In this study, we evaluate sulfate and BC concentrations from eleven different models driven with the same emission inventory against a comprehensive pan-Arctic measurement data set over a time period of 2 years (2008–2009). The set of models consisted of one Lagrangian particle dispersion model, four chemistry transport models (CTMs), one atmospheric chemistry-weather forecast model and five chemistry climate models (CCMs), of which two were nudged to meteorological analyses and three were running freely. The measurement data set consisted of surface measurements of equivalent BC (eBC) from five stations (Alert, Barrow, Pallas, Tiksi and Zeppelin), elemental carbon (EC) from Station Nord and Alert and aircraft measurements of refractory BC (rBC) from six different campaigns. We find that the models generally captured the measured eBC or rBC and sulfate concentrations quite well, compared to previous comparisons. However, the aerosol seasonality at the surface is still too weak in most models. Concentrations of eBC and sulfate averaged over three surface sites are underestimated in winter/spring in all but one model (model means for January–March underestimated by 59 and 37% for BC and sulfate, respectively), whereas concentrations in summer are overestimated in the model mean (by 88 and 44% for July–September), but with overestimates as well as underestimates present in individual models. The most pronounced eBC underestimates, not included in the above multi-site average, are found for the station Tiksi in Siberia where the measured annual mean eBC concentration is 3 times higher than the average annual mean for all other stations. This suggests an underestimate of BC sources in Russia in the emission inventory used. Based on the campaign data, biomass burning was identified as another cause of the modeling problems. For sulfate, very large differences were found in the model ensemble, with an apparent anticorrelation between modeled surface concentrations and total atmospheric columns. There is a strong correlation between observed sulfate and eBC concentrations with consistent sulfate/eBC slopes found for all Arctic stations, indicating that the sources contributing to sulfate and BC are similar throughout the Arctic and that the aerosols are internally mixed and undergo similar removal. However, only three models reproduced this finding, whereas sulfate and BC are weakly correlated in the other models. Overall, no class of models (e.g., CTMs, CCMs) performed better than the others and differences are independent of model resolution

Numerická simulace přenosu hmoty mezi amoniakem a vodou v absorpčním chilleru

Článek popisuje absorpční proces plynného amoniaku do kapalné vody v deskovém tepelném výměníku, který je považován za kritickou část absorpčního chladicího systému. Jsou aplikovány dva přístupy pro numerickou simulaci absorpce. První přístup spočívá v simulaci jak vlastního rozpouštění atomů plynného amoniaku v kapalné vodě, tak i jejich následné chemické reakci s molekulami vody za vzniku hydroxidu. Ve druhém, zjednodušeném, přístupu je simulována pouze první část absorpce, tedy jen rozpouštění molekul bez jejich následné reakce.This paper describes the absorption process of gaseous ammonia into liquid water in the plate heat exchanger, which is considered to be the crucial part of an absorption cooling system. Two approaches are utilized to numerically simulate this absorption process. In the first approach, the dissolution of gaseous ammonia into liquid water, as well as the following chemical reaction between the dissolved liquid ammonia and liquid water, are modeled. In the second approach, only the dissolution of ammonia into water is considered. The Henry’s Law with Van’t Hoff correlation is used for the simulation of the ammonia absorption process, namely the calculation of the concentration of ammonia in gas and in liquid. The Henry’s law is utilized since its line has the best correlation with the ammonia-water equilibrium line for the concentrations, which is taken into account in the numerical simulations. The ammonia mass flux from gas to liquid phase and its concentration at the outlet of the computational domain is determined as a result of the simulations