The Effect of Air Bleed on the Heat Transfer and Pressure Distribution on 30 Conical Flares at a Mach Number of 6.8

The effect of a boundary-layer bleed at the start of a 30 deg half-angle flare upon the shape of the flow boundaries, the pressure distribution on the flare, and the heat transfer to the flare was studied at a Mach number of 6.8. The forebody was an ogive cylinder. Test Reynolds numbers, based on forebody length, ranged from 1 x 10(exp 6) to 7.4 x 10(exp 6). Schlieren photographs showed the effect produced upon the flow boundaries by varying the dimensions of the bleed in both the radial and axial directions and by blunting the lip at the leading edge of the flare. The heat transfer and pressure distribution on the flare were correlated with the shape and nature of the flow boundaries

Heat Transfer in Regions of Separated and Reattached Flows

Past experimental work has indicated that separated flow can greatly increase the heat transfer to a surface; whereas, some theoretical studies have indicated a possible decrease. Recent investigations have helped to clarify the effects of separation on heat transfer and have indicated a method of reducing separation. This paper considers the results of some of these investigations and shows the heat transfer in regions of separation and reattachment for a few specific shapes. These results show that the heat transfer in a separated region is strongly affected by the extent of separation, the location of the reattachment point, and the location of transition along the separated boundary

Assessment of upper tropospheric HOx sources over the tropical Pacific based on NASA GTE/PEM data: Net effect on HOx and other photochemical parameters

Data for the tropical upper troposphere (8-12 km, 20° N-20° S) collected during NASA's Pacific Exploratory Missions have been used to carry out a detailed examination of the photochemical processes controlling HOx (OH+HO2). Of particular significance is the availability of measurements of nonmethane hydrocarbons, oxygenated hydrocarbons (i.e., acetone, methanol, and ethanol) and peroxides (i.e., H2O2 and CH3OOH). These observations have provided constraints on model calculations permitting an assessment of the potential impact of these species on the levels of HOx, CH3O2, CH2O, as well as ozone budget parameters. Sensitivity calculations using a time-dependent photochemical box model show that when constrained by measured values of the above oxygenated species, model estimated HOx levels are elevated relative to unconstrained calculations. The impact of constraining these species was found to increase with altitude, reflecting the systematic roll-off in water vapor mixing ratios with altitude. At 11-12 km, overall increases in HOx approached a factor of 2 with somewhat larger increases being found for gross and net photochemical production of ozone. While significant, the impact on HOx due to peroxides appears to be less than previously estimated. In particular, observations of elevated H2O2 levels may be more influenced by local photochemistry than by convective transport. Issues related to the uncertainty in high-altitude water vapor levels and the possibility of other contributing sources of HOx are discussed. Finally, it is noted that the uncertainties in gas kinetic rate coefficients at the low temperatures of the upper troposphere and as well as OH sensor calibrations should be areas of continued investigation. Copyright 1999 by the American Geophysical Union

Evolution and chemical consequences of lightning-produced NOx observed in the North Atlantic upper troposphere

Airborne observations of NO during the Subsonics Assessment Ozone and Nitrogen Oxides Experiment (SONEX) reveal episodes of high NOx in the upper troposphere believed to be associated with lightning. Linkage to specific periods of lightning activity is possible through back trajectories and data from the National Lightning Detection Network. Lagrangian model calculations are used to explore the evolution of these high NOx plumes over the 1-2 days between their introduction and subsequent sampling by NASA's DC-8 aircraft. Simulations include expected changes in HNO3, H2O2, CH3OOH, HO2, and OH. Depending on the time of injection and dilution rate, initial NOx concentrations are estimated to range from 1 to 7 ppbv. Similar to many previous studies, simulated HNO3 concentrations tend to be greater than observations. Several possible explanations for this difference are explored. H2O2 observations are shown to be consistent with removal in convective activity. While it is possible that upper tropospheric CH3OOH is enhanced by convection, simulations show such increases in CH3OOH can be short-lived (e.g., < 12 hours) with no perceptible trace remaining at the time of sampling. High NO levels further prevent elevated levels of CH3OOH from propagating into increases in H2O2. HO2 is suppressed through reaction with NO in all cases. Simulated increases in OH exceeded a factor of 2 for some cases, but for the highest NOx levels, loss of OH via OH+NO2 offset production from HO2+NO. Additional increases in OH of 30-60% could result from convection of CH3OOH. A final point of discussion concerns how the chemistry within these plumes, their long-range transport, and their potential importance in sustaining background NOx far from source regions present a challenge to global and regional model simulations. Copyright 2000 by the American Geophysical Union

An assessment of ozone photochemistry in the extratropical western North Pacific: Impact of continental outflow during the late winter/early spring

This study examines the influence of photochemical processes on tropospheric ozone distributions over the extratropical western North Pacific. The analysis presented ere is based on data collected during the Pacific Exploratory Mission-West Phase B (PEM-West B) field study conducted in February-March 1994. Sampling in the study region involved altitudes of 0-12 km and latitudes of 10°S to 50°N. The extratropical component of the data set (i.e., 20-50°N) was defined by markedly different photochemical environments north and south of 30°N. This separation was clearly defined by an abrupt decrease in the tropopause height near 30°N and a concomitant increase in total O3 column density. This shift in overhead O3 led to highly reduced rates of O3 formation and destruction for the 30-50°N latitude regime. Both latitude ranges, however, stili exhibited net O3 production at all altitudes. Of special significance was the finding that net O3 production prevailed even at boundary layer and lower free tropospheric altitudes (e.g., < 4 km), a condition uncommon to Pacific marine environments. These results reflect the strong impact of continental outflow of O3 precursors (e.g., NO and NMHCs) into the northwestern Pacific Basin. Comparisons with PEM-West A, which sampled the same region in a different season (September-October), revealed major differences at altitudes below 4 km, the altitude range most influenced by continental outflow. The resulting net rate of increase in the tropospheric O3 column for PEM-West B was 1-3% per day, while for PEM-West A it was approximately zero. Unique to the PEM-West B study is the finding that even under wintertime conditions substantial column production of tropospheric O3 can occur at subtropical and mid-latitudes. While such impacts may not be totally unexpected at near coast locations, the present study suggests that the impact from continental outflow on the marine BL could extend out to distances of more than 2000 km from the Asian Pacific Rim

The X-ray luminous cluster underlying the z = 1.04 quasar PKS1229-021

We present a 100 ks Chandra observation studying the extended X-ray emission around the powerful z=1.04 quasar PKS1229-021. The diffuse cluster X-ray emission can be traced out to ~15 arcsec (~120 kpc) radius and there is a drop in the calculated hardness ratio inside the central 5 arcsec consistent with the presence of a cool core. Radio observations of the quasar show a strong core and a bright, one-sided jet leading to the SW hot spot and a second hot spot visible on the counter-jet side. Although the wings of the quasar PSF provided a significant contribution to the total X-ray flux at all radii where the extended cluster emission was detected, we were able to accurately subtract off the PSF emission using ChaRT and marx simulations. The resulting steep cluster surface brightness profile for PKS1229-021 appears similar to the profile for the FRII radio galaxy 3C444, which has a similarly rapid surface brightness drop caused by a powerful shock surrounding the radio lobes (Croston et al.). Using a model surface brightness profile based on 3C444, we estimated the total cluster luminosity for PKS1229-021 to be L_X ~ 2 x 10^{44} erg/s. We discuss the difficulty of detecting cool core clusters, which host bright X-ray sources, in high redshift surveys.Comment: 10 pages, 9 figures, accepted by MNRA

Assessment of ozone photochemistry in the western North Pacific as inferred from PEM-West A observations during the fall 1991

This study examines the influence of photochemical processes on ozone distributions in the western North Pacific. The analysis is based on data generated during NASA's western Pacific Exploratory Mission (PEM-West A) during the fall of 1991. Ozone trends were best described in terms of two geographical domains: the western North Pacific rim (WNPR) and the western tropical North Pacific (WTNP). For both geographical regions, ozone photochemical destruction, D(O3), decreased more rapidly with altitude than did photochemical formation, F(O3). Thus the ozone tendency, P(O3), was typically found to be negative for z <6 km and positive for z > 6-8 km. For nearly all altitudes and latitudes, observed nonmethane hydrocarbon (NMHC) levels were shown to be of minor importance as ozone precursor species. Air parcel types producing the largest positive values of P(O3) included fresh continental boundary layer (BL) air and high-altitude (z > 7 km) parcels influenced by deep convection/lightning. Significant negative P(O3) values were found when encountering clean marine BL air or relatively clean lower free-tropospheric air. Photochemical destruction and formation fluxes for the Pacific rim region were found to exceed average values cited for marine dry deposition and stratospheric injection in the northern hemisphere by nearly a factor of 6. This region was also found to be in near balance with respect to column-integrated O3 photochemical production and destruction. By contrast, for the tropical regime column-integrated O3 showed photochemical destruction exceeding production by nearly 80%. Both transport of O3 rich midlatitude air into the tropics as well as very high-altitude (10-17 km) photochemical O3 production were proposed as possible additional sources that might explain this estimated deficit. Results from this study further suggest that during the fall time period, deep convection over Asia and Malaysia/Indonesia provided a significant source of high-altitude NOx to the western Pacific. Given that the high-altitude NOx lifetime is estimated at between 3 and 9 days, one would predict that this source added significantly to high altitude photochemical O3 formation over large areas of the western Pacific. When viewed in terms of strong seasonal westerly flow, its influence would potentially span a large part of the Pacific. Copyright 1996 by the American Geophysical Union

Separation of Fischer-Tropsch Wax Products from Ultrafine Iron Catalyst Particles

The morphological and chemical nature of ultrafine iron catalyst particles (3-5 nm diameters) during activation/FTS was studied by HRTEM, EELS, and Moessbauer spectroscopy. With the progress of FTS, the carbide re-oxidized to magnetite and catalyst activity gradually decreased. The growth of oxide phase continued and average particle size also increased simultaneously. The phase transformation occurred in a ''growing oxide core'' manner with different nano-zones. The nano-range carbide particles did not show fragmentation or attrition as generally observed in micrometer range particles. Nevertheless, when the dimension of particles reached the micrometer range, the crystalline carbide phase appeared to be sprouted on the surface of magnetite single crystal. In the previous reporting period, a design and operating philosophy was developed for an integrated wax filtration system for a 4 liter slurry bubble column reactor to be used in Phase II of this research program. During the current reporting period, we have started construction of the new filtration system and began modifications to the 4 liter slurry bubble column reactor (SBCR) reactor. The system will utilize a primary wax separation device followed by a Pall Accusep or Membralox ceramic cross-flow membrane. As of this writing, the unit is nearly complete except for the modification of a moyno-type pump; the pump was shipped to the manufacturer to install a special leak-free, high pressure seal

An overview of ISCAT 2000

The Investigation of Sulfur Chemistry in the Antarctic Troposphere (ISCAT) took place over the timer period of 15 November to 31 December in the year 2000. The study location was the Amundsen Scott Station in Antarctica. ISCAT 2000 defines the second phase of a program designed to explore tropospheric chemistry in Antarctica. As in 1998, the 2000 ISCAT study revealed a strong oxidizing environment at South Pole (SP). During the 2000 investigation, however, the suite of measurements was greatly expanded. These new measurements established the recycling of reactive nitrogen as a critical component of this unique environment. This paper first presents the historical background leading up to the ISCAT 2000 observations; then it focuses on providing a summary of the year 2000 results and contrasts these with those recorded during 1998. Important developments made during the 2000 study included the recording of SP data for several species being emitted from the snowpack. These included NO, H 2O2 and CH2O. In this context, eddy-diffusion flux measurements provided the first quantitative estimates of the SP NO and NOx snow-to-atmosphere fluxes. This study also revealed that HNO 3 and HO2NO2 were major sink species for HOx and NOx radicals. And, it identified the critical factors responsible for SP NO levels exceeding those at other polar sites by nearly an order of magnitude. Finally, it reports on the levels of gas phase sulfur species and provides evidence indicating that the absence of DMS at SP is most likely due to its greatly shorten chemical lifetime in the near vicinity of the plateau. It is proposed that this is due to the influence of NO on the distribution of OH in the lower free troposphere over a region that extends well beyond the plateau itself. Details related to each of the above findings plus others can be found in the 11 accompanying Special Issue papers. © 2004 Elsevier Ltd. All rights reserved

The X-ray luminous cluster underlying the bright radio-quiet quasar H1821+643

We present a Chandra observation of the only low redshift, z=0.299, galaxy cluster to contain a highly luminous radio-quiet quasar, H1821+643. By simulating the quasar PSF, we subtract the quasar contribution from the cluster core and determine the physical properties of the cluster gas down to 3 arcsec (15 kpc) from the point source. The temperature of the cluster gas decreases from 9.0\pm0.5 keV down to 1.3\pm0.2 keV in the centre, with a short central radiative cooling time of 1.0\pm0.1 Gyr, typical of a strong cool-core cluster. The X-ray morphology in the central 100 kpc shows extended spurs of emission from the core, a small radio cavity and a weak shock or cold front forming a semi-circular edge at 15 arcsec radius. The quasar bolometric luminosity was estimated to be 2 x 10^{47} erg per sec, requiring a mass accretion rate of 40 Msolar per yr, which corresponds to half the Eddington accretion rate. We explore possible accretion mechanisms for this object and determine that Bondi accretion, when boosted by Compton cooling of the accretion material, could provide a significant source of the fuel for this outburst. We consider H1821+643 in the context of a unified AGN accretion model and, by comparing H1821+643 with a sample of galaxy clusters, we show that the quasar has not significantly affected the large-scale cluster gas properties.Comment: 20 pages, 19 figures, accepted by MNRA